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51.
目的 探讨喉癌的CT分型和转移相关因子CD44V6表达的意义。方法 对39例喉鳞癌行术前常规CT检查,其术后标本进行CD44V6的表达检测,与术前CT片作对照分析。结果39例喉鳞癌CT检查;声门型24例,声门上型14例,跨声门型1例,声门下型0例;T1-2级22例,T3-4级17例;淋巴结转移组13例,非转移组26例,CD44V6总的阳性表达率为61.5%,对各组均采用秩次检验分析,CD44V6在喉癌的CT的T分级和淋巴结分组中存在显著性差异(P<0.01)。而部位分区无明显差异。结论 喉癌的CT分型中的T分级、淋巴结分组与CD44V6的阳性表达密切相关。 相似文献
52.
53.
简述了瑞士ARL 9400型X荧光光谱仪探测器高压部分的故障现象、分析与处理及维修方法,并给出了维修实例。 相似文献
54.
应用AFS 820型双道原子荧光仪测定芦荟中砷和硒,方法检出限分别为As0.51μg/L;Se0.42μg/L。经国家一级植物标准物质分析验证,结果与标准值相符。5次测定相对标准偏差As<2.3%;Se<3.1%。 相似文献
55.
原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰 总被引:1,自引:0,他引:1
通过研究黑龙江省森林沼泽景观区有机水系沉积物(泥炭)、土壤中As,Sb,Bi的测定结果,发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰,提出采用低温(<450℃)灰化处理可完全消除干扰。对比研究还发现,过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题,应专门对其进行评价研究。 相似文献
56.
Depth profiles of fluorescence at several excitation and emission wavelengths were measured along with CTD data during the
cruise So119 of RV Sonne in the Arabian Sea from 12 May to 10 June 1997. In addition to chlorophyll fluorescence from phytoplankton in the near-surface
layer, the profiles in the oxygen minimum region well below the euphotic zone show enhanced red fluorescence. Red fluorescence
intensity is inversely related to the oxygen concentration in intermediate and deep waters. A relationship to characteristic
water masses of the region cannot be found in the data, and this holds also with chemical data such as DOC. Absorbance spectra
of water samples taken in the oxygen minimum zone show an absorption band at 420 nm wavelength with about 50 nm bandwidth,
much weaker than gelbstoff absorbance in the same wavelength range. The absorption band remains stable after sample filtration
with 0.45 μm glass fibre filters. Hence, the size of the absorbing matter is in the range of dissolved molecules or particles
much smaller than 1 μm. Fluorescence spectra of unfiltered samples with 420 nm excitation show a weak emission band at 600
nm and a more pronounced one at 660 nm wavelength. The trailing edge of the 660 nm band falls into the range of chlorophyll
emission, thus giving rise to the observed depth profiles of red fluorescence in the oxygen minimum zone. Red fluorescence
measured on samples remain stable during a few hours after sampling even in the presence of oxygen. It is not detectable after
several weeks of sample storage in the dark and cannot be reproduced even after depletion of dissolved oxygen.
Received: 22 May 2002 / Accepted: 18 February 2003
Responsible Editor: Andreas Oschlies
Acknowledgements. This work was supported by a grant from the Federal Minister of Education and Technology, Bonn, within the frame work of
the JGOFS Arabian Sea program. We are grateful to the captain and the crew of RV Sonne for their support. We are indebted to Mrs. Kirsten Neumann from the Institute of Marine Chemistry and Biogeochemistry of
the University of Hamburg for providing the oxygen data, and to Mr. Nikolai Delling from the same institute for making the
DOC and chlorophyll data available to us. 相似文献
57.
S. K. Deb M. H. Manghnani K. Ross R. A. Livingston P. J. M. Monteiro 《Physics and Chemistry of Minerals》2003,30(1):31-38
A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal
is presented. Raman spectra, recorded with increasing temperature, indicate that the thermal decomposition begins at ≈55 °C,
accompanied by dehydration of water molecules from the mineral. This is in contrast to previous studies that reported higher
temperature breakdown of ettringite. The dehydration is completed by 175 °C and this results in total collapse of the crystalline
structure and the material becomes amorphous. The Raman scattering results are supported by X-ray diffraction results obtained
at increasing temperatures.
Received: 9 July 2001 / Accepted: 14 August 2002 相似文献
58.
Advances in energy-dispersive X-ray fluorescence 总被引:1,自引:0,他引:1
Utz Kramar 《Journal of Geochemical Exploration》1997,58(1):73-80
Recently, two new instruments for X-ray fluorescence analysis (XRF) with interesting features for geochemical applications came to the market. Both instruments were designed to improve the peak to background ratio, the principal factor limiting the sensitivity of XRF. Total reflection XRF (TXRF) was designed to analyse extremely small sample amounts. An instrument, using polarised X-rays (P-XRF) for excitation, is designed to reduce scattered background in spectra of bulk samples. The performance of both instruments was compared with conventional XRF-methods and ICP/MS. Results for GXR-1, GXR-2, GXR-3, GXR-4 and GXR-6 obtained with TXRF and P-XRF are in good agreement with literature data. The effective amount of sample, analysed by TXRF was 200 μg only and detection limits of ~ l μg/g were achieved. P-XRF shows considerable improved detection limits (0.25–0.5 μg/g) for bulk samples for elements with atomic numbers 42–51 (Mo-Sb) compared with conventional XRF-methods. 相似文献
59.
X射线荧光测井中 ,井液位于井下探管与井壁之间 ,它的影响不但表现在对特征X射线的吸收 ,而且表现在对源初级射线和特征 X射线的散射。井液的校正采用硬件与软件相结合的方法 ,在硬件上 ,使含有探测器的部分制成单独的短臂 ,有效地保证了探测窗与井壁的良好接触 ;在软件上 ,提出的双散射峰法和散射峰 -逃逸峰法 ,能够校正 0 - 10 mm厚的井液对 X射线荧光测井结果的影响 相似文献
60.
The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface. 相似文献