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71.
青海省东昆仑祁漫塔格地区肯德可克矿区外围东部发育一正长花岗岩体,主要矿物组合为正长石(50%~60%)+石英(20%~30%)+斜长石(10%~20%)+黑云母(1%~5%)。其LA-ICP-MS锆石U-Pb加权平均年龄为217.9±1.7 Ma(MSWD=0.74,n=20),形成时代为晚三叠世,与祁漫塔格地区铁多金属矿床基本同时形成。岩石地球化学组成具有高硅(Si O2=74.53%~75.28%)、富碱(K2O+Na2O=8.81%~8.95%)、富铁贫镁(Fe OT/Mg O=18.02~31.48)的特征,并具强烈的负Eu异常(δEu=0.04~0.05),富集Rb、Th、U、K、Ga,亏损Sr、Ba、Ta、P、Ti,显示其为准铝质A型花岗岩。正长花岗岩锆石εHf(t)为2.0~12.4,平均6.4,显示其源区具有壳幔混合作用的特征,壳幔物质交换为区内铁多金属矿化提供了大量成矿物质。该正长花岗岩属A2型花岗岩,暗示其形成于造山后的伸展构造体制,反映了祁漫塔格地区晚华力西-印支期造山旋回于晚三叠世由造山后期转为伸展阶段。  相似文献   
72.
位于长江中下游的宣城水东地区发育一套酸性火山岩,主要由流纹质角砾岩、流纹岩和珍珠岩组成。本文对该套火山岩进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Nd-Hf同位素研究。LA-ICP MS锆石U-Pb定年结果显示3种岩性的火山岩年龄分别为133.2±0.8、133.4±0.8和131.5±0.9 Ma。主量元素组成上,这套酸性火山岩具高硅(72.51%~81.79%)、富钾(K_2O/Na_2O=2.04~14.93,平均6.72)、贫钙镁(Ca O=0.19%~1.57%,Mg O=0.06%~0.29%)的特征,属于弱过铝质(A/CNK=1.02~1.24)的高钾钙碱性-钾玄岩系列岩石。微量元素方面,轻重稀土元素分馏明显[(La/Yb)_N=5.43~9.17],具明显的负铕异常(Eu/Eu~*=0.44~0.60),富集大离子亲石元素(LILE)Rb、Th、K和Pb等,亏损Ba、Sr、Nb、P和Ti等元素,表现出壳源的特征。全岩Sr-Nd和锆石Hf同位素组成变化范围相对较小,(~(87)Sr/~(86)Sr)_i为0.707 3~0.708 8,εNd(t)值为-7.05~-5.56,εHf(t)为-8.6~-1.3。结合区域地质研究成果,认为宣城水东地区酸性火山岩可能是在约135 Ma古太平洋板块俯冲作用之后的伸展-拉伸环境下,由新元古代早期新生地壳重熔而成。  相似文献   
73.
北阿尔金蛇绿岩带是分布在阿尔金山北缘的一条蛇绿混杂岩带,超基性蛇纹岩岩块、基性岩墙、辉长岩块及基性熔岩组合是该带东段阿克塞蛇绿岩的典型组合形式。地球化学研究结果显示,阿克塞蛇绿岩超基性蛇纹岩以富MgO、贫Al_2O_3、P_2O_5、CaO和K_2O为特征,球粒陨石标准化稀土元素配分曲线表现较平缓,比值接近于1;基性熔岩类中TiO_2为0.86%~1.80%,Al_2O_3为12.00%~14.85%,CaO介于4.89%~19.23%之间,球粒陨石标准化稀土元素配分型式表现为右倾;基性岩墙中TiO_2介于1.08%~2.44%之间,Al_2O_3含量为11.07%~13.26%,Na_2O(1.20%~2.28%)K_2O(0.80%~1.38%),稀土元素总量介于48.65×10~(-6)~124.04×10~(-6)之间,平均92.95×10~(-6);轻、重稀土元素比值介于2.22~4.45之间,总体表现为大洋中脊环境,LA-ICP-MS锆石U-Pb年龄显示,阿克塞蛇绿岩形成于514.6±8.8Ma,为寒武纪,表明在早古生代北阿尔金洋已完全打开,并连通了红柳沟—阿克塞。  相似文献   
74.
Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm3). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS 187Os/189Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM 187Os/189Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.  相似文献   
75.
A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.  相似文献   
76.
扎兰屯地区位于二连 贺根山 黑河构造带中段,区内发育韧性变形叠加的晚古生代早期花岗岩类。本文在详尽的野外地质调查基础上,对该套花岗岩类的锆石U- Pb年代学和地球化学进行系统分析,研究其成岩年代序列,探讨岩石成因及构造背景,厘定韧性构造叠加的时限,进一步揭示扎兰屯地区额尔古纳 兴安地块和松嫩地块的拼合过程,为兴蒙造山带的区域构造演化研究提供新材料。大量年代学研究显示,扎兰屯地区晚古生代早期花岗质岩浆作用发生于405~325Ma之间,该作用可进一步细化为早中泥盆世(Ⅰ期、405~380Ma)、晚泥盆世—早石炭世初(Ⅱ期、365~350Ma)和早石炭世晚期(Ⅲ期335~325Ma)等3期。其中Ⅰ期和Ⅱ期花岗岩类属高钾—钾玄质钙碱性、准铝质—弱过铝质花岗岩类,可能为俯冲背景下岛弧岩浆活动形成的I型 分异I型花岗岩;Ⅲ期花岗岩类属中—高钾钙碱性、准铝质—弱过铝质花岗岩类,可能为后碰撞背景下岩浆活动形成的分异I型- A型花岗岩。该套花岗岩类普遍叠加韧性变形,可能为碰撞后侧向逃逸作用的产物,变形时限为晚石炭世末—早二叠世(308~290Ma)。大兴安岭北段晚古生代早期花岗质岩浆作用与额尔古纳 兴安地块和松嫩地块的碰撞拼合作用有关,扎兰屯地区二者的碰撞拼合时限可能为早石炭世中期。  相似文献   
77.
This study presents new zircon U–Pb geochronology, geochemistry, and zircon Hf isotopic data of volcanic and subvolcanic rocks that crop out in the Bayanhushuo area of the southern Great Xing’an Range (GXR) of NE China. These data provide insights into the tectonic evolution of this area during the late Mesozoic and constrain the evolution of the Mongol–Okhotsk Ocean. Combining these new ages with previously published data suggests that the late Mesozoic volcanism occurred in two distinct episodes: Early–Middle Jurassic (176–173 Ma) and Late Jurassic–Early Cretaceous (151–138 Ma). The Early–Middle Jurassic dacite porphyry belongs to high-K calc-alkaline series, showing the features of I-type igneous rock. This unit has zircon εHf(t) values from +4.06 to +11.62 that yield two-stage model ages (TDM2) from 959 to 481 Ma. The geochemistry of the dacite porphyry is indicative of formation in a volcanic arc tectonic setting, and it is derived from a primary magma generated by the partial melting of juvenile mafic crustal material. The Late Jurassic–Early Cretaceous volcanic rocks belong to high-K calc-alkaline or shoshonite series and have A2-type affinities. These volcanics have εHf(t) and TDM2 values from +5.00 to +8.93 and from 879 to 627 Ma, respectively. The geochemistry of these Late Jurassic–Early Cretaceous volcanic rocks is indicative of formation in a post-collisional extensional environment, and they formed from primary magmas generated by the partial melting of juvenile mafic lower crust. The discovery of late Mesozoic volcanic and subvolcanic rocks within the southern GXR indicates that this region was in volcanic arc and extensional tectonic settings during the Early–Middle Jurassic and the Late Jurassic–Early Cretaceous, respectively. This indicates that the Mongol–Okhotsk oceanic plate was undergoing subduction during the Early–Middle Jurassic, and this ocean adjacent to the GXR may have closed by the Late Middle Jurassic–Early Late Jurassic.  相似文献   
78.
The Olympic iron oxide–copper–gold province in South Australia contains numerous deposits and prospects, including the Olympic Dam Cu–U–Au–Ag deposit and the Acropolis prospect. The Acropolis prospect comprises massive, coarse-grained magnetite–apatite veins partly replaced by a hematite-stable assemblage. The apatite grains in the veins contain zones with abundant inclusions of other minerals (including monazite and xenotime) and low trace-element concentrations relative to the inclusion-free zones. The inclusion-rich apatite zones are interpreted to be formed from the recrystallisation of the inclusion-free apatite and remobilisation of U, Th and rare earth element (REE) from apatite into monazite and xenotime. Apatite, monazite and xenotime are all established U–Th–Pb geochronometers and offer the potential to constrain the alteration history of the Acropolis prospect. The LA-ICPMS U–Pb age of inclusion-free apatite is within error of the age of the host volcanic units (ca 1.59 Ga). Inclusion-rich apatite yields both near-concordant analyses that are within error of the inclusion-free apatite as well as highly disturbed (discordant) analyses. The most concordant analyses of monazite (Th–Pb) inclusions and xenotime (U–Pb) inclusions and rim grains indicate an alteration event occurred at ca 1.37 Ga and possibly also at ca 500 Ma. The disparity in age of the inclusion-rich apatite and the REE-phosphate inclusions (and rim grains) is suggested to be owing to the apatite being initially recrystallised at ca 1.59 Ga and modified again by a later event that also formed (or coarsened) most of the inclusions. Partial resetting of the majority of the monazite inclusions as well as the presence of significant amounts of common Pb has complicated the interpretation of the monazite results. In contrast, xenotime is a more robust geochronometer in this setting. The ages of the two post-1.59 Ga events that appear to have affected the Acropolis prospect do not correspond to any events known to have occurred in the Gawler Craton. The earlier (ca 1.37 Ga) age instead corresponds best with metamorphic–magmatic–hydrothermal activity in Laurentia, consistent with the proximity of Laurentia and the Gawler Craton inferred from palaeogeographic reconstructions. The later (ca 500 Ma) event corresponds to the Delamerian Orogeny and has been shown by prior studies to have also affected the Olympic Dam deposit.  相似文献   
79.
Loess is a main archive of Pleistocene landscapes and environments and therefore has an important connection to the preservation and interpretation of Paleolithic sites. In Europe, anthropogenic sites have been found in loess because of past local occupation. At one extreme, sites are well preserved with minimal disturbance often accompanied by embedded proxies to estimate ecological parameters. On the other hand, loess deposits have undergone post-depositional alterations such as weathering, pedogenesis or bioturbation due to changing environmental conditions or other disturbances that obscure anthropogenic sites. We outline the current state of research and connections between Paleolithic archeology and loess research while introducing a series of subsequent regional case studies as part of a special issue. We also make recommendations for future work to incorporate a wider variety of methods to create more robust inferences on hominin and environmental evolution and their connections.  相似文献   
80.
早三叠世时期频繁的火山事件是导致全球性气候和海洋环境异常的主要原因,前人对早三叠世重要界线时期的火山事件地层开展了大量研究,但对典型界线时期以外的其他火山事件地层却鲜有报道。本文以上扬子西南普宜地区嘉陵江组两件沉凝灰岩为研究对象开展了岩石学、岩相学、锆石年代学及微量元素组合特征等方面的研究。沉凝灰岩样品具有典型岩浆锆石的内部结构和微量元素组合特征,两组沉凝灰岩锆石谐和年龄分别为250.6±0.6 Ma和249.1±0.8 Ma,代表了母岩岩浆中新生锆石的结晶年龄。沉凝灰岩母岩主要以酸性花岗岩类为主,次为中性正长岩类和少量基性岩类。嘉陵江组沉凝灰岩与二叠系—三叠系界线(PTB)凝灰岩及Olenekian—Anisian界线(OAB)绿豆岩具有同源性,形成于活动大陆边缘的碰撞造山环境,源区很可能位于中越边境地区长山构造岩浆带—十万大山火山带,且在陆壳碰撞过程中源区地壳处于持续的增厚阶段,下地壳增厚部位的部分熔融形成补给岩浆上涌并使早期结晶矿物发生了部分熔蚀。本文嘉陵江组沉凝灰岩样品250.6±0.6 Ma年龄对应着Smithian—Spathian界线时期的全球性降温及短期生物复苏事件;249.1±0.8 Ma年龄的样品对应Spathian亚阶中期极端高温气候和生物再次灭绝事件,再次证明了早三叠世时期频繁的火山活动是导致气候改变和生物周而复始新生和灭绝的重要因素。其原因可能是阳伞效应和温室效应等因素综合反馈的结果,但具体证据仍需要将来更多学科综合研究成果的约束。  相似文献   
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