Radon-222 as a tracer for mixing in the water column and benthic exchange in the southern California borderland     

W.M. Berelson  D.E. Hammond  C. Fuller 《Earth and Planetary Science Letters》1982,61(1):41-54

The concentrations of²²²Rn and²²⁶Ra in the water column and in the sediments of Santa Barbara and San Nicolas Basins have been measured semi-annually over the last four years. Approximately one-third of excess radon profiles obtained in the water column in these basins can be adequately fit with a one-dimensional eddy diffusion-decay model. Exponential profiles in the center of San Nicolas Basin yield a vertical eddy diffusivity of 26±16 cm²/s and 3.4±1.0 cm²/s for Santa Barbara Basin. The application of a two-dimensional eddy diffusion-decay model to profiles obtained in the center and on the margins of San Nicolas Basin produces a better fit than is found using a one-dimensional vertical eddy diffusivity. The two-dimensional model for San Nicolas Basin predicts a vertical eddy diffusivity of 17 cm²/s and a horizontal eddy diffusivity of 10⁵ cm²/s. These values are in reasonable agreement with those predicted from the vertical buoyancy gradient and the horizontal length scale.The vertically integrated radon excess (standing crop) in the water column of Santa Barbara Basin averages 53±23 atoms/m² s. This is in good agreement with the flux across the sediment-water interface of 60±15 atoms/m² s, calculated by measuring radon emanation in the sediments as a function of depth and applying a molecular diffusion-reaction model. Hence, one-dimensional molecular diffusion accurately predicts the flux of radon from the laminated Santa Barbara Basin sediments. In San Nicolas Basin the integrated radon excess in the water column is 376±143 atoms/m² s, but the diffusive randon flux from San Nicolas Basin sediments averages only 190±53 atoms/m² s. This descrepancy indicates that a non-diffusive process, probably macrofaunal irrigation, supplies much of the flux of radon from San Nicolas Basin sediments.  相似文献   

The ilmenite/titano-magnetite assemblage: kinetics of re-equilibration     

Patrick A. Hammond  Lawrence A. Taylor 《Earth and Planetary Science Letters》1982,61(1):143-150

Compositions of coexisting ilmenite and titano-magnetite commonly have been used to establish the conditions of formation for igneous and metamorphic rocks (Buddington-Lindsley geothermometer/oxybarometer). Temperatures so determined for some rocks are lower than might be expected for magmatic crystallization. These low temperatures are the result of re-equilibration of the Fe-Ti oxides during slow cooling. This process is one in which titano-magnetites are oxidized and ilmenites are reduced upon cooling along a buffer curve or in the presence of a fluid of constant composition. Textural studies indicate that the reduction of the ilmenite-hematite phase may be the slower reaction consequently, the rate-controlling step of the re-equilibration.The kinetics of the reduction reactions in the two-phase region between the joins for the ilmenite-hematite and magnetite-ulvöspinel solid solution series were studied by thermogravimetric analysis at controlledf_O2. With experiments conducted near the Ni/NiO and QFM buffers, annealed ilmenite(ss) synthetic charges were reduced isothermally. The temperature range for the experiments was 900–1250°C, with total gas-flow rates of 0.35 and 1.0 cm/s. Kinetic data were collected by measuring the weight change during each experiment as a function of time. Additionally, a cooling-rate (0.5°C/hr) experiment was conducted near the QFM buffer from 1150 to 985°C starting with an ilmenite-saturated spinel phase.At 1200°C and 0.35 cm/s flow rate, the reaction mechanism is an interfacial process where mass transport of the reacting gases is the rate-controlling step. In isothermal experiments at 1100°C and lower, diffusion of reactants through a solid product layer was the controlling mechanism. The activation energy for this diffusion process is 59±6 kcal/mole. Significant enhancement of diffusion occurs along grain boundaries.Although the individual phases may re-equilibrate internally upon cooling, the Fe-Ti contents must remain unchanged for proper use of this mineral indicator-i.e. no external re-equilibration. It is imperative that the kinetics of the situation be appreciated. These preliminary kinetic experiments indicate that extreme caution must be exercised when applying this ilmenite/titano-magnetite geothermometer/oxybarometer. These phases may only truly “quench” in the parameters of formation in the case of certain hypabyssal and extrusive occurrences  相似文献   

Characterizing groundwater flow in a faulted karst system using optical brighteners from septic systems as tracers     

K. E. Murray  D. R. Straud  W. W. Hammond 《Environmental Geology》2007,53(4):769-776

This study used optical brighteners (OB) released from septic systems to show that groundwater flow direction is largely controlled by the structural framework in a faulted karst groundwater system. Effective protection of groundwater resources requires that groundwater systems are adequately characterized and source water protection areas (SWPA) are developed for drinking water wells. Karst aquifers are among the most sensitive to contamination due to high recharge rates, and among the most difficult aquifers to characterize due to heterogeneity, and anisotropy. Because septic systems may be used to treat wastewater within SWPAs for karst aquifers there is a need to characterize these groundwater systems using tracers. The objective of this study was to characterize groundwater flow in a faulted portion of the Edwards aquifer in Bexar County, Texas using OB that are released as incidental tracers from septic systems. This study included measurement of water levels, sampling of groundwater and surface water, analysis for OB, and spatial analysis in a GIS. Results show that OB intensities were highest to the southwest of the septic area, a direction that is sub-parallel to the fault and fracture orientation and nearly perpendicular to the hydraulic gradient. This indicates that movement of OB, solutes, or non-aqueous liquids/solids in a faulted karst system can be largely controlled by fault/fracture orientation and structural relay ramps.  相似文献   

Late Holocene lake level dynamics inferred from magnetic susceptibility and stable oxygen isotope data: Lake Elsinore, southern California (USA)     

Matthew E. Kirby  Christopher J. Poulsen  Steve P. Lund  William P. Patterson  Liam Reidy  Douglas E. Hammond 《Journal of Paleolimnology》2004,31(3):275-293

Southern California faces an imminent freshwater shortage. To better assess the future impact of this water crisis, it is essential that we develop continental archives of past hydrological variability. Using four sediment cores from Lake Elsinore in Southern California, we reconstruct late Holocene (3800 calendar years B.P.) hydrological change using a twentieth-century calibrated, proxy methodology. We compared magnetic susceptibility from Lake Elsinore deep basin sediments, lake level from Lake Elsinore, and regional winter precipitation data over the twentieth century to calibrate the late Holocene lake sediment record. The comparison revealed a strong positive, first-order relationship between the three variables. As a working hypothesis, we suggest that periods of greater precipitation produce higher lake levels. Greater precipitation also increases the supply of detritus (i.e., magnetic-rich minerals) from the lake's surrounding drainage basin into the lake environment. As a result, magnetic susceptibility values increase during periods of high lake level. We apply this modern calibration to late Holocene sediments from the lake's littoral zone. As an independent verification of this hypothesis, we analyzed ¹⁸O_(calcite), interpreted as a proxy for variations in the precipitation:evaporation ratio, which reflect first order hydrological variability. The results of this verification support our hypothesis that magnetic susceptibility records regional hydrological change as related to precipitation and lake level. Using both proxy data, we analyzed the past 3800 calendar years of hydrological variability. Our analyses indicate a long period of dry, less variable climate between 3800 and 2000 calendar years B.P. followed by a wet, more variable climate to the present. These results suggest that droughts of greater magnitude and duration than those observed in the modern record have occurred in the recent geological past. This conclusion presents insight to the potential impact of future droughts on the over-populated, water-poor region of Southern California.  相似文献   

From hazard to impact: flood damage assessment tools for mega cities     

Albert S. Chen  Michael J. Hammond  Slobodan Djordjević  David Butler  David M. Khan  William Veerbeek 《Natural Hazards》2016,82(2):857-890

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River management response to multi-decade changes in timing of reservoir inflows,Columbia River Basin,USA     

Julia A. Jones  John C. Hammond 《水文研究》2020,34(25):4814-4830

Around the world, long-term changes in the timing and magnitude of streamflow are testing the ability of large managed water resource systems constructed in the 20th century to continue to meet objectives in the 21st century. Streamflow records for unregulated rivers upstream of reservoirs can be combined with records downstream of reservoirs using a paired-watershed framework and concepts of water resource system performance to assess how reservoir management has responded to long-term change. Using publicly available data, this study quantified how the intra-annual timing of inflows and outflows of 25 major reservoirs has shifted, how management has responded, and how this has influenced reliability and vulnerability of the water resource system in the 668,000 km² Columbia River basin from 1950 to 2012. Reservoir inflows increased slightly in early spring and declined in late spring to early fall, but reservoir outflows increased in late summer from 1950 to 2012. Average inflows to reservoirs in the low flow period exceeded outflows in the1950s, but inflows are now less than outflows. Reservoirs have increased hedging, that is, they have stored more water during the spring, in order to meet the widening gap between inflows and outflows during the summer low flow period. For a given level of reliability (the fraction of time flow targets were met), vulnerability (the maximum departure from the flow target) was greater during periods with lower than average inflows. Thus, the water management system in this large river basin has adjusted to multi-decade trends of declining inflows, but vulnerability, that is, the potential for excess releases in spring and shortfalls in summer, has increased. This study demonstrates the value of combining publicly available historical data on streamflow with concepts from paired-watershed analyses and metrics of water resource performance to detect, evaluate, and manage water resource systems in large river basins.  相似文献   

The mineralogy,petrology, and composition of anomalous eucrite Emmaville          下载免费PDF全文

T. J. Barrett  D. W. Mittlefehldt  R. C. Greenwood  B. L. A. Charlier  S. J. Hammond  D. K. Ross  M. Anand  I. A. Franchi  F. A. J. Abernethy  M. M. Grady 《Meteoritics & planetary science》2017,52(4):656-668

The Emmaville eucrite is a relatively poorly studied basaltic achondrite with an anomalous oxygen isotope signature. In this study, we report comprehensive mineralogical, petrographic, and geochemical data from Emmaville in order to understand its petrogenesis and relationship with the basaltic eucrites. Emmaville is an unusually fine‐grained, hornfelsic‐textured metabasalt with pervasive impact melt veins and mineral compositions similar to those of typical basaltic eucrites. The major and trace element bulk composition of Emmaville is also typical of a basaltic eucrite. Three separated individual lithologies were also analyzed for O isotopes; a dark gray fraction (E1), a shocked lithology (E2), and a lighter gray portion (E3). Fractions E1 and E2 shared similar O isotope compositions to the bulk sample (E‐B), whereas the lighter gray portion (E3) is slightly elevated in Δ¹⁷O and significantly elevated in δ¹⁸O compared to bulk. No evidence for any exogenous material is observed in the thin sections, coupled with the striking compositional similarity to typical basaltic eucrites, appears to preclude a simple impact‐mixing hypothesis. The O‐isotopes of Emmaville are similar to those of Bunburra Rockhole, A‐881394, and EET 92023, and thus distinct from the majority of the HEDs, despite having similarities in petrology, mineral, and bulk compositions. It would, therefore, seem plausible that all four of these samples are derived from a single HED‐like parent body that is isotopically distinct from that of the HEDs (Vesta) but similar in composition.  相似文献   

Historical Gorda Ridge t-phase swarms: relationships to ridge structure and the tectonic and volcanic state of the ridge during 1964–1966     

Daniel A. Walker  Stephen R. Hammond 《Deep Sea Research Part II: Topical Studies in Oceanography》1998,45(12):2531-2545

The U.S. Navy’s Sound Surveillance System (SOSUS) hydrophone arrays are extemely efficient receptors of a high-frequency earthquake energy phase known as the t(ertiary)-wave, or t-phase (Fox et al., 1994). After a nearly 30-year hiatus in such studies, SOSUS arrays are again being utilized to detect t-phases and to locate seismic and volcanic events occurring along the Gorda seafloor spreading center (Fox et al., 1995; Fox and Dziak, 1998). Earlier, Northrop et al. (1968) also used other military arrays to infer tectonic structure along the Gorda Ridge. From October 1964 through December 1966, over 600 low-magnitude earthquakes occurred along the Gorda Ridge. Nearly all of these events had magnitudes below the detection thresholds of land-based seismic networks. Northrop et al. (1968) interpreted the geographic distribution of these events as evidence for a nascent fracture zone near the midpoint of the ridge. In the present study, the spatial distributions of these older data and, for the first time, their temporal distributions as well, were examined with respect to detailed bathymetry of the ridge that was acquired in the early 1980s. This analysis, of 570 on-axis and 74 off-axis events, led to the following observations: (1) nearly all of the Gorda Ridge t-phase events occurred in discreet swarms centered about the ridge axis, (2) most of the events within each of 8 (of 9) observed swarms occurred mainly along single ridge segments, and, (3) reconfirming the earlier Northrop et al. (1968) conclusion, most of the events originated in the region of a major change in the strike of the ridge axis. During the 27-month interval that the ridge was observed, relatively few t-phase events took place along the northernmost segment of the Gorda Ridge where the 1996 eruption occurred. However, a unique sequence of small events which visually resemble the events associated with a Juan de Fuca Ridge eruption in 1993 (Fox et al., 1995) and a Gorda Ridge eruption in 1996 (Fox and Dziak, 1998) may have been associated with an eruption on the ridge during 1965.  相似文献   

GAUGE: the GrAnd Unification and Gravity Explorer     

G. Amelino-Camelia  K. Aplin  M. Arndt  J. D. Barrow  R. J. Bingham  C. Borde  P. Bouyer  M. Caldwell  A. M. Cruise  T. Damour  P. D’Arrigo  H. Dittus  W. Ertmer  B. Foulon  P. Gill  G. D. Hammond  J. Hough  C. Jentsch  U. Johann  P. Jetzer  H. Klein  A. Lambrecht  B. Lamine  C. Lämmerzahl  N. Lockerbie  F. Loeffler  J. T. Mendonca  J. Mester  W.-T. Ni  C. Pegrum  A. Peters  E. Rasel  S. Reynaud  D. Shaul  T. J. Sumner  S. Theil  C. Torrie  P. Touboul  C. Trenkel  S. Vitale  W. Vodel  C. Wang  H. Ward  A. Woodgate 《Experimental Astronomy》2009,23(2):549-572

The GAUGE (GrAnd Unification and Gravity Explorer) mission proposes to use a drag-free spacecraft platform onto which a number of experiments are attached. They are designed to address a number of key issues at the interface between gravity and unification with the other forces of nature. The equivalence principle is to be probed with both a high-precision test using classical macroscopic test bodies, and, to lower precision, using microscopic test bodies via cold-atom interferometry. These two equivalence principle tests will explore string-dilaton theories and the effect of space–time fluctuations respectively. The macroscopic test bodies will also be used for intermediate-range inverse-square law and an axion-like spin-coupling search. The microscopic test bodies offer the prospect of extending the range of tests to also include short-range inverse-square law and spin-coupling measurements as well as looking for evidence of quantum decoherence due to space–time fluctuations at the Planck scale.  相似文献   

Constraining pathways of microbial mediation for carbonate concretions of the Miocene Monterey Formation using carbonate-associated sulfate     

Sean J. Loyd  William M. Berelson  Timothy W. Lyons  Douglas E. Hammond  Frank A. Corsetti 《Geochimica et cosmochimica acta》2012

Carbonate concretions can form as a result of organic matter degradation within sediments. However, the ability to determine specific processes and timing relationships to particular concretions has remained elusive. Previously employed proxies (e.g., carbon and oxygen isotopes) cannot uniquely distinguish among diagenetic alkalinity sources generated by microbial oxidation of organic matter using oxygen, nitrate, metal oxides, and sulfate as electron acceptors, in addition to degradation by thermal decarboxylation. Here, we employ concentrations of carbonate-associated sulfate (CAS) and δ³⁴S_CAS (along with more traditional approaches) to determine the specific nature of concretion authigenesis within the Miocene Monterey Formation.Integrated geochemical analyses reveal that at least three specific organo-diagenetic reaction pathways can be tied to concretion formation and that these reactions are largely sample-site specific. One calcitic concretion from the Phosphatic Shale Member at Naples Beach yields δ³⁴S_CAS values near Miocene seawater sulfate (～+22‰ VCDT), abundant CAS (ca. 1000 ppm), depleted δ¹³C_carb (～?11‰ VPDB), and very low concentrations of Fe (ca. 700 ppm) and Mn (ca. 15 ppm)—characteristics most consistent with shallow formation in association with organic matter degradation by nitrate, iron-oxides and/or minor sulfate reduction. Cemented concretionary layers of the Phosphatic Shale Member at Shell Beach display elevated δ³⁴S_CAS (up to ～+37‰), CAS concentrations of ～600 ppm, mildly depleted δ¹³C_carb (～?6‰), moderate amounts of Mn (ca. 250 ppm), and relatively low Fe (ca. 1700 ppm), indicative of formation in sediments dominated by sulfate reduction. Finally, concretions within a siliceous host at Montaña de Oro and Naples Beach show minimal CAS concentrations, positive δ¹³C values, and the highest concentrations of Fe (ca. 11,300 ppm) and Mn (ca. 440 ppm), consistent with formation in sediments experiencing methanogenesis in a highly reducing environment. This study highlights the promise in combining CAS analysis with more traditional techniques to differentiate among diagenetic reactions as preserved in the geologic record and shows potential for unraveling subsurface biospheric processes in ancient samples with a high degree of specificity.  相似文献