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11.
The evolution of volcanic landscapes and their landslide potential are both dependent upon the weathering of layered volcanic rock sequences. We characterize critical zone structure using shallow seismic Vp and Vs profiles and vertical exposures of rock across a basaltic climosequence on Kohala peninsula, Hawai’i, and exploit the dramatic gradient in mean annual precipitation (MAP) across the peninsula as a proxy for weathering intensity. Seismic velocity increases rapidly with depth and the velocity–depth gradient is uniform across three sites with 500–600 mm/yr MAP, where the transition to unaltered bedrock occurs at a depth of 4 to 10 m. In contrast, velocity increases with depth less rapidly at wetter sites, but this gradient remains constant across increasing MAP from 1000 to 3000 mm/yr and the transition to unaltered bedrock is near the maximum depth of investigation (15–25 m). In detail, the profiles of seismic velocity and of weathering at wet sites are nowhere monotonic functions of depth. The uniform average velocity gradient and the greater depths of low velocities may be explained by the averaging of velocities over intercalated highly weathered sites with less weathered layers at sites where MAP > 1000 mm/yr. Hence, the main effect of climate is not the progressive deepening of a near‐surface altered layer, but rather the rapid weathering of high permeability zones within rock subjected to precipitation greater than ~1000 mm/yr. Although weathering suggests mechanical weakening, the nearly horizontal orientation of alternating weathered and unweathered horizons with respect to topography also plays a role in the slope stability of these heterogeneous rock masses. We speculate that where steep, rapidly evolving hillslopes exist, the sub‐horizontal orientation of weak/strong horizons allows such sites to remain nearly as strong as their less weathered counterparts at drier sites, as is exemplified by the 50°–60° slopes maintained in the amphitheater canyons on the northwest flank of the island. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
12.
To better understand the mechanisms relating to hydrological regulations of chemical weathering processes and dissolved inorganic carbon (DIC) behaviours, high-frequency sampling campaigns and associated analyses were conducted in the Yu River, South China. Hydrological variability modifies the biogeochemical processes of dissolved solutes, so major ions display different behaviours in response to discharge change. Most ions become diluted with increasing discharge because of the shortened reactive time between rock and water under high-flow conditions. Carbonate weathering is the main source of major ions, which shows strong chemostatic behaviour in response to changes in discharge. Ions from silicate weathering exhibit a significant dilution effect relative to the carbonate-sourced ions. Under high temperatures, the increased soil CO2 influx from the mineralisation of organic material shifts the negative carbon isotope ratios of DIC (δ13CDIC) during the high-flow season. The δ13CDIC values show a higher sensitivity than DIC contents in response to various hydrological conditions. Results from a modified isotope-mixing model (IsoSource) demonstrate that biological carbon is a dominant source of DIC and plays an important role in temporal carbon dynamics. Furthermore, this study provides insights into chemical weathering processes and carbon dynamics, highlighting the significant influence of hydrological variability to aid understanding of the global carbon cycle.  相似文献   
13.
Lateritic weathering profiles (LWPs) are widespread in the tropics and comprise an important component of the Critical Zone (CZ). The Hawaiian Islands make an excellent natural laboratory for examining the tropical CZ, where the bedrock composition (basalt) is nearly uniform and rainfall varies greatly. This natural laboratory is employed to assess the utility of the HVSR (horizontal/vertical spectral ratio) method to characterize the shear-wave velocity (Vs) structure of LWPs, particularly the depth to the contact between saprolite and basalt bedrock. LWP thicknesses determined from HVSR provide good agreement with multi-channel analysis of surface waves (MASW) profiles, well logs and outcrop. LWP thicknesses may be estimated from the fundamental mode equation or through forward models. Prior knowledge about the subsurface from well, outcrop, and MASW profiles may greatly aid modeling in some cases. For the 3.2 to 1.8 Ma Koolau Volcano on Oahu, the downward rate of advance of the weathering front varies from 0.004 to 0.041 m/ka. For the 0.44 to 0.10 Ma Kohala Volcano (Big Island of Hawaii) rates vary from 0.013 to 0.047 m/ka. Simple H/V spectra develop in areas where the combined effects of time and elevated rainfall produce thick LWPs with a flat base and a general absence of core stones with an ideal layered geometry. Abundant buried core stones violate the assumption of simple layered geometries and scatter acoustic energy, leading to uninterpretable results. This is common where low rainfall and a young basaltic substrate leave abundant core stones as well as an undulating contact between saprolite and bedrock. Velocity inversions (high Vs intervals within low Vs saprolite) may also be present and originate from relatively intact bedrock horizons or mineralogical changes within saprolite. At Kohala, a gibbsite-rich horizon produces such a velocity inversion due to enhanced weathering and subsequent collapse of saprolite in a discrete horizon. © 2019 John Wiley & Sons, Ltd.  相似文献   
14.
利用化学蚀变指数法恢复物源区的风化历史及沉积物通量是一种经济实用、行之有效的方法。前人对珠江口盆地荔湾凹陷对应物源区的研究相对薄弱。本文通过对区内岩心测试数据进行化学蚀变指数分析,恢复晚渐新世—早中新世物源区的风化历史,并进行沉积物通量的估算,在此基础上探讨物源特征对研究区内沉积充填的控制作用。研究表明,晚渐新世研究区对应物源区经历了强烈风化阶段,该阶段产生的丰富的沉积物供给是研究区西北部快速进积、规模壮观的陆架边缘三角洲及斜坡重力流沉积体系发育的重要控制因素之一;早中新世,西北物源区风化减弱,沉积供给减少,但研究区东部沉积物供应较西部要充分得多,表明早中新世,研究区南部除了来自西北部的主要物源外,局部物源对该时期的沉积具有重要影响;推测东部物源(东部古隆起、兴宁古隆起)的突然复活是促进研究区东部早中新世沟槽形成发育的重要原因之一。在超深水区进行沉积物源区的研究中,这种半定量的方法对盆内局部物源的确定具有重要的指示意义。  相似文献   
15.
碳酸盐岩风化作用(即岩溶作用)能够吸收大气二氧化碳(CO_2),形成溶解无机碳(DIC,dissolved inorganic carbon),被认为是一种重要的陆地碳汇,其在全球碳收支平衡和未来陆地增汇中可能会有重要贡献。然而,目前对岩溶碳汇的稳定性还存在争议,一些学者认为岩溶地下水出露地表后会发生CO_2脱气,对岩溶碳汇通量估算带来不确定性。本文以广西桂林长流水表层岩溶泉补给的溪流(约2.7km长)为例,利用水化学和同位素质谱仪测试技术,研究了溪水水化学指标和溶解无机碳同位素(δ~(13)C_(DIC))沿流程变化,探讨了溪流CO_2脱气过程、通量及其影响因素,以更好地了解岩溶碳汇的稳定性。结果表明:从泉口向下游,在陡坡地段(C1~C14段,长约270m,坡度约10°),溪水pH值、方解石饱和指数和δ~(13)C_(DIC)沿流程分别升高了0.9、0.9和1.8‰,而CO_2分压、电导率、Ca~(2+)浓度和DIC浓度分别下降了85%、34μS/cm、0.2mmol/L和0.7mmol/L,说明溪水发生了显著的CO_2脱气,并伴随碳酸钙沉淀。而在平缓地段(C18~C26段,长约2.1km,坡度1°),溪水各水化学指标和δ~(13)C_(DIC)变化较小,指示CO_2脱气作用较弱。这些发现表明溪流CO_2脱气受到了地形决定的水动力条件控制。另外,在下游渠段,受支流汇入影响,溪水pH值和方解石饱和指数有所降低,在一定程度上抑制了CO_2脱气。溪流CO_2脱气能够抵消部分岩溶作用固定的大气CO_2量,但是在长流水这一高地势、低流量且有碳酸钙沉积的环境下,其抵消的量也仅占29%。对于在低缓地区受流量很大的岩溶泉/地下河补给的河流,其CO_2脱气作用对岩溶碳汇的影响有限,加之受可能增强的水生光合生物固碳效应影响,岩溶碳汇应具有很高的稳定性。  相似文献   
16.
Due to its structure,rock and mineral composition,fluid and other factors,the granite Buried Hill Reservoir is highly heterogeneous with a complex longitudinal structure and a reservoir space made up of a combination of dissolution pores and fractures.This paper is based on current understanding of tectonic evolution in the northern part of the South China Sea,in conjunction with the seismic phase characteristics.It is determined that the meshed fault system was formed by three stages of movement-tectonic compression orogeny during the Indochinese epoch,strike-slip compression-tension during the Yanshanian Period,early fracture extension activation during the Himalayan-which controlled the distribution of the Buried Hill Reservoir.Drilling revealed two types of buried hills,faulted anticline and fault horst,their longitudinal structure and the reservoir space type being significantly different.The mineral composition,reservoir space and diagenetic characteristics of the reservoir rocks and minerals were analyzed by lithogeochemistry,micro section and logging etc.,it thus being determined that the Mesozoic rocks of the Songnan Low Uplift in the Qiongdongnan Basin are mainly composed of syenogranite,granodiorite,monzogranite,which is the material basis for the development of the Buried Hill Reservoir.The content of felsic and other brittle minerals is more than 70%,making it easy for it to be transformed into fractures.At the same time,the weathering resistance of granodiorite and monzogranite is weaker than that of syenogranite,which is easily weathered and destroyed,forming a thick sand gravel weathering zone.With increasing depth of burial,weathering and dissolution gradually weaken,the deep acidic fluid improving the reservoir property of internal fractures and expanding the vertical distribution range of the reservoirs.The research results lay a foundation for the exploration of Buried Hill in the deep-water area of the Qiongdongnan Basin.  相似文献   
17.
地球化学基因是近两年提出的一种新的地球化学示踪技术,本文选择北京怀柔云蒙山地区两个邻近的花岗岩风化剖面(编号为B和C)来分析岩性地球化学基因和金矿化地球化学基因的属性特征。剖面B样品的化学蚀变指数CIA变化为51.3~58.9,WIG的范围为89.4~68.6,属于初始风化程度;剖面C样品的CIA变化为52.4~78.4,WIG的范围为84.8~25.3,属于中等风化程度。这种邻近剖面风化程度的明显差异表明微环境对岩石风化产物的影响是显著的。相对于剖面底部新鲜花岗岩而言,岩性地球化学基因相似度在剖面B和C中的范围分别为85%~100%和90%~100%,金矿化地球化学基因相似度范围分别为85%~100%和80%~100%。当相对于剖面顶部土壤样品时,岩性地球化学基因相似度在剖面B和C中的范围分别为80%~100%和90%~100%,金矿化地球化学基因相似度范围分别为85%~100%和80%~100%。依据≥80%的基因相似度标准(区分基因是否相似),尽管两个剖面在风化程度上存在明显差异,但岩性地球化学基因和金矿化地球化学基因在两个剖面内部均表现出良好的遗传性和继承性,且在两个剖面之间体现出同源风化产物之间具有良好的相似性。相对于理想金矿石(其金矿化基因为12020202020)而言,金矿化相似度在剖面B和C中的范围分别为25%~50%和30%~50%。依据≥40%的金矿化相似度(即样品与理想金矿石的金矿化相似度)作为存在金矿化异常的标准,在两个剖面中均可识别出厚度约1 m左右的矿化异常层位。因此,金矿化基因除了具有地球化学基因的属性(遗传性、继承性、相似性)外,其金矿化相似度(即相对于理想金矿石的相似度)也有可能作为金矿勘查中的一个地球化学综合指标。  相似文献   
18.
本文首先提出了河流泥沙输移过程中泥沙中的钙镁矿物溶蚀消耗水体中的CO2并具有碳汇功能的观点。基于前人长江干流从源头到入海口和支流2003~2007年期间4次河流悬移质泥沙的化学元素组成和矿物组成资料,分析悬移质中CaO、MgO含量和方解石、白云石含量变化特征,定量计算了这些取样点悬移质泥沙的CO2总碳汇能力和非永久性、永久性碳汇能力,分析了不同碳汇能力沿程变化规律及其原因。碳汇计算结果表明:寸滩—大通河段1956~2000年期间泥沙输移过程中钙镁矿物溶蚀产生的总碳汇量、非永久性和永久性碳汇量分别为2572万t/a、1700万t/a和872万t/a。由于输沙量减少,寸滩站—大通站河段的总碳汇量、非永久性和永久性碳汇量2006~2019年期间较1956~2000年期间相应分别减少了1852万t、1224万t和872万t。三峡水库年均淤积量1. 145亿t,损失总碳汇量675. 6万t,相当于三峡电站减排二氧化碳8580万t的7. 9%。全球河流入海年输沙量126. 1亿t,以寸滩- 吴淞口河段碳汇功能0. 060 t/t计,总碳汇量7. 57亿t相当于全球岩石风化碳汇总量10. 56亿t CO2的71. 6%。河流泥沙输移过程中钙镁矿物溶蚀的碳汇量具有重要的作用,其溶蚀速率大于原地风化。  相似文献   
19.
王增涛 《陕西地质》2011,29(2):41-46
文中探讨了寨上地区古风化壳形成机理和演化过程,认为在寨上矿区第三系地层以下存在古风化壳,寨上矿区王足路一带16、29、23号矿体头部的风化壳内的氧化铁帽型金矿为风化壳型金矿床(类红土型金矿)。  相似文献   
20.
南水北调中线水源地河水地球化学特征与流域侵蚀   总被引:1,自引:0,他引:1  
丹江口水库及其上游流域是南水北调中线工程的水源地,本文讨论了水源地河流水化学与锶同位素(87Sr/86Sr)组成变化特征,目的在于了解水源地流域河流地表水溶质的物质来源以及岩石风化侵蚀过程和人为活动的影响。流域内河流水化学组成以Ca2+、HCO3-为主,Mg2+和SO42-次之,反映了碳酸盐岩风化溶解起控制作用的典型特征。水化学分析表明水源地河水受到工农业活动等人为因素的影响;河流87Sr/86Sr同位素地球化学研究表明,流域岩石风化输入至少存在三个不同端员(硅酸岩、石灰岩和白云岩)之间的混合。水源地流域内硅酸岩和碳酸岩的风化侵蚀速率分别为38.6和4.4 t/km2.a,总岩石风化侵蚀速率高于全球河流平均值。  相似文献   
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