红透山矿床变质岩系褶皱构造特征浅析   总被引：1，自引：0，他引：1  

王锡华  李伟 《矿产与地质》2004,18(3):245-248

红透山式铜-锌矿床形成于太古代克拉通裂谷槽盆中海底火山喷发-沉积环境。因此，矿床的空间展布严格受特定的含矿岩系所控制。槽盆构造中的岩层褶皱构造最发育，矿床赋存在具多期褶皱构造叠加的大型同倾向形褶皱内，褶皱的层间虚脱是控矿有利构造空间，可以借此预测矿体侧伏方向及赋存部位。  相似文献   

热液中铅、锌、银共生分异的热力学探讨   总被引：4，自引：0，他引：4  

尚林波  樊文苓  胡瑞忠  邓海琳 《矿物学报》2004,24(1):81-86

通过元素基本性质的对比以及热力学计算分析，探讨了热液中银、铅、锌的共生分异机制。在酸性至近中性条件下，氯配合物是它们在热液中的存在形式，其中锌氯配合物最稳定；在近中性到碱性条件下，硫氢配合物占主导地位，此时，银硫氢配合物相对最稳定。温度下降、[Cr]降低、pH升高及f(O2)降低，引起银、铅、锌配合物溶解度减小，发生沉淀分离；对于硫氢配合物，其稳定性主要受pH及还原硫浓度的影响。因此，配合物的不同存在形式以及配合物稳定性之间的差异，使得它们对热液条件的改变做出不同的响应，从而导致了热液中银、铅、锌在成矿过程中的共生分异。  相似文献   

The mechanisms of paragenesis and separation of silver, lead and zinc in hydrothermal solutions     

尚林波胡瑞忠  樊文苓 《中国地球化学学报》2005,24(1):82-89

On the basis of an experimental study and thermodynamic calculation, the mechanisms of paragenesis and separation of silver, lead and zinc in the hydrothermal system have been studied. At acidic to nearly neutral pH, their chloride complexes are stable, and among them the chloride complexes of zinc are most stable. And the sulfide complexes are the dominant species at nearly neutral to alkaline pH,while the sulfide complexes of silver are most stable. With decreasing temperature, [ Cl^-] ,fO2, and increasing pH, the solubilities of silver, lead and zinc will decrease, leading to their deposition and separation. For sulfide complexes, the concentrations of reduced sulfur and pH are two important factors affecting their stabilities. Complexes of different forms and stabilities respond to the variation of conditions to different extents, which gave rise to the paragenesis and separation of silver, lead and zinc in the whole ore-forming process of dissolution, transport and deposition.  相似文献   

SPATIAL VARIATION OF Zn GEOCHEMICAL FRACTIONS IN THE SURFACE SEDIMENTS OF THE STRAITS OF MALACCA: NATURAL OR ANTHROPOGENIC?     

CheeKongYap AhmadIsmail SoonGuanTan 《湿地科学》2005,3(2):94-103

1INTRODUCTION Studiesonheavymetalcontaminationinsedi mentshavealwaysbeenfocusedonthecoastalandin tertidalareas(Sivalingam,etal.,1980;Ismail,1993;Ismail,etal.,1993;IsmailandRosniza,1997;Yap,etal.,2002a,2002b).Theheavymet alconcentrationsfoundinthesediments…  相似文献   

西藏玛圭铅锌多金属矿成矿地质特征及找矿远景     

姚胜  李鹏  郭雪峰  路晓君  张雪婷 《地质通报》2016,35(9):1529-1535

西藏玛圭铅锌多金属矿在冈底斯铅锌银成矿带已发现的矽卡岩型多金属矿床中处于最西段。通过目前的预查工作,在矿区内共发现有14条矿体,初步预测可达到中-大型矿床规模。冈底斯中东段目前研究程度已较高,而西段与之具有相同的良好的矽卡岩型多金属矿成矿地质条件,但发现的矿床却很少。玛圭矿床的发现为该成矿带向西延伸和扩大规模提供了依据,并增加了进一步向西寻找同类型矿床的信心。  相似文献   

Metallogeny of the Baiyangping Lead‐Zinc Polymetallic Ore Concentration Area,Northern Lanping Basin of Yunnan Province,China     

WANG Xiaohu  SONG Yucai  ZHANG Hongrui  LIU Yingchao  PAN Xiaofei  GUO Tao 《《地质学报》英文版》2018,92(4):1486-1507

The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.  相似文献   

内蒙古核桃坝地区铅锌与铀矿的期次关系探讨     

蒋孝君 《地质论评》2021,67(Z1):67z1097-67z1098

正核桃坝地区位于华北板块北缘多金属成矿带和沽源—红山子铀成矿带的交汇部位,具有优越的铀多金属成矿地质条件。近年来,核工业二〇八大队在核桃坝地区取得铀矿勘查突破,落实了铀矿产地。铀矿勘查中不仅发现了多个具有工业价值的铀矿体,还发现了许多较好的铅、锌、钼、铜、  相似文献   

Geodynamic modelling of the Century deposit,Mt Isa Province,Queensland     

A. Ord  B. E. Hobbs  Y. Zhang  G. C. Broadbent  M. Brown  G. Willetts 《Australian Journal of Earth Sciences》2013,60(6):1011-1039

This paper is concerned with an example of quantitative modelling of orebody formation as a guide to reducing the risk for future mineral exploration. Specifically, the paper presents a detailed 3–D numerical model for the formation of the Century zinc deposit in northern Queensland. The model couples fluid flow with deformation, thermal transport and chemical reactions. The emphasis of the study is a systems approach where the holistic mineralising system is considered rather than concentrating solely on the mineral deposit. In so doing the complete plumbing system for mineralisation is considered with a view to specifying the critical conditions responsible for the ore deposit occurring where it does and having the size and metal grades that are observed. The numerical model is based on detailed geological, tectonic, isotopic and mineralogical data collected over the past 20 years. The conclusions are that the Century zinc deposit is located where it is because of the following factors: (i) a thermal anomaly is associated with the Termite Range Fault due to advection of heat from depth by fluid flow up the Termite Range Fault; (ii) bedding‐plane fissility in the shale rocks hosting the Century zinc deposit has controlled the wavelength and nature of D₁ folding in the vicinity of the deposit and has also controlled increases in permeability due to hydrofracture of the shales; such hydrofracture is also associated with the production of hydrocarbons as these shales passed through the ‘oil‐window’; (iii) Pb–Zn leached from crustal rocks in the stratigraphic column migrated up along faults normal to the Termite Range Fault driven by topographic relief associated with inversion at the end of the Isan Orogeny; these fluids mixed with H₂S derived at depth moving up the Termite Range Fault to mix with the crustal fluids to precipitate Pb–Zn in a plume downstream from the point of mixing. Critical factors to be used as exploration guides are high temperatures, carbonaceous fissile shales now folded into relatively tight D₁ folds, fault‐controlled plumbing systems that enable fluid mixing, depletion of metals upstream of the deposit and,in particular,a very wide Fe‐depletion halo upstream of the deposit.  相似文献   

秦岭泥盆系层控铅锌矿床成因模式探讨     

黄书俊  曾永超 《矿产与地质》1991,(3)

在论述秦岭泥盆系层控铅锌矿床的黄铁矿微量元素,硫、铅、氢、氧同位素,矿物气液包裹体均一温度及成分.区域地层元素丰度等方面特征的基础上,提出了该类型属海底含矿热泉溢出沉积和隐伏含矿热泉贯入沉淀的成因模式.  相似文献   

Crystal structure refinement of hendricksite,A Zn- and Mn-rich trioctahedral potassium mica: A contribution to the crystal chemistry of zinc-bearing minerals     

Dr. J. -L. Robert  Dr. M. Gaspérin 《Mineralogy and Petrology》1985,34(1):1-14

Summary The crystal structure of hendricksite, a trioctahedral mica of biotite type, characterized by high Zn²⁺ and Mn²⁺ contents has been refined by least square methods. The structural formula is: (K_0.89Na_0.10Ba_0.04)(Mg_1.57Zn_0.54Mn _0.40 ²⁺ Fe _0.25 ²⁺ Al_0.07Ti_0.07Cr_0.01)(Si_2.92Al_1.08)O₁₀ (OH)₂. The space group isC2/m and the cell parameters are:a=5.340(2) Å,b=9.524(2) Å,c=10.235(3) Å, =100.07(2)^o, the cell volume isV=497.98 ų. The final unweightedR=0.072. Average cation-anion distances in polyhedra are: T–O=1.659 Å, M(1)–O=2.093 Å, M(2)–O=2.088 Å, A–O_long=3.316 Å and A–O_short=3.004 Å; A is the alkaline cation. The rotation angle of tetrahedra is =6.7°. The analysis of electron densities, of the dimensions and distorsions of polyhedra shows that Zn²⁺ is exclusively in octahedral sites; there is no order between six-fold coordinated cations. A comparison between the structural features of hendricksite and those of the two main end-members of biotites, phlogopite and annite, is presented.The effect of the strong covalence of Zn–O bonds is particularly visible on the dimensions and orientations of the thermal ellipsoids of octahedral sites M(1) and M(2) which contain zinc. In all the published structures of trioctahedral micas, the ellipsoids of cationic sites are uniaxial positive, elongated parallel toc ^*. In hendricksite, this is observed only for the two zinc-free sites (T and A; in the octahedra M(1) and M(2), which contain zinc, the ellipsoids are approximately uniaxial negative, flattened parallel toa, which is a unique situation.Zinc which habitually favours the tetrahedral coordinations with oxygen, enters the octahedra only, i.e. the chemically anisotropic sites, in hendricksite. The strong polarizability of Zn²⁺ is proposed to explain this behaviour.An examination of the behaviour of Zn²⁺ in other compounds shows that this situation is general, zinc favours chemically anisotropic sites and specially those adjacent to OH or H₂O.

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Affinement de la structure cristalline de la hendricksite, mica trioctaédrique potassique riche en Zn et Mn; une contribution à la connaissance cristallochimique des minéraux zincifères

Résumé On a affiné par moindres carrés la structure de la hendricksite, mica trioctaédrique de type biotite, caractérisé par une teneur élevée en Zn²⁺ et Mn²⁺. La formule structurale de ce mica est: (K_0m89Na_0,10Ba_0,04)(Mg_1,57Zn_0,54Mn _0,40 ²⁺ Fe _0,25 ²⁺ Al_0,07Ti_0,07Cr_0,01)(Si_2,92Al_1,08)O₁₀(OH)₂. Le groupe spatial estC2/m et les paramètres de la maille:a=5,340(2) Å,b=9,254(2) Å,c=10,235(3) Å, =100,07(2)°; le volume de la maille estV=497,98 ų. Le résidu final non-pondéré estR=0,072. Les distances cation-anion moyennes dans les polyèdres sont les suivantes: T–O=1,659 Å, M(1)–O=2,093 Å, M(2)–O=2,088 Å, A–O_long=3,316 Å et A–O_court=3,004 Å où A désigne le cation alcalin. L'angle de rotation tétraédrique, =6,7°, est très semblable à celui de la phlogopite. L'analyse des densités électroniques, des dimensions et distorsions des polyèdres montre que Zn²⁺ est exclusivement en coordinance octaédrique et qu'il n'y a pas d'ordre entre les cations hexacoordonnés. On présente une comparaison des caractères structuraux de la hendricksite avec ceux des deux principaux pôles des biotites, la phlogopite et l'annite.L'effet de la forte covalence de la liaison Zn–O est particulièrement visible sur les dimensions et orientations des ellipsoides d'agitation thermique des deux sites octaédriques, sites zincifères. Dans toutes les structures de micas trioctaédriques publiées, les ellipsoides des sites cationiques sont uniaxes positifs, allongés parallèlement àc ^*, ce qui s' observe effectivement dans les deux sites non-zincifères (T et A) de la hendricksite, par contre, dans les octaèdres M(1) et M(2), qui contiennent le zinc, les ellipsoides sont approximativement uniaxes négatifs, applatis parallèlement àa, ce qui est une situation unique.Le zinc, qui se fixe généralement en sites tétraédriques dans les structures de type oxyde, occupe les sites octaédriques, c'est-à-dire les sites chimiquement anisotropes dans la hendricksite. La forte polarisabilité de Zn²⁺ est proposée pour expliquer ce comportement.Un examen du comportement de Zn²⁺ dans d'autres phases montre que cette situation est tout à fait générale, le zinc privilégiant les sites chimiquement anisotropes et en particulier ceux adjacents à OH où H₂O.

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