国内外CO₂地质封存潜力评价方法研究现状     

刘廷  马鑫  刁玉杰  金晓琳  付杰  张成龙 《中国地质调查》2021,8(4):101-108

碳捕集与封存(Carbon Capture and Storage,CCS)技术作为缓解全球气候变暖、减少CO₂排放的有效路径之一,其潜力评估至关重要。目前CCS技术主要包括CO₂强化石油(天然气)开采封存技术、CO₂驱替煤层气封存技术以及咸水层CO₂封存技术3类。各类封存技术利用了不同的封存机制,其潜力评估方法也略有差别。油气藏封存和咸水层封存主要利用了构造圈闭储存、束缚空间储存、溶解储存、矿化储存等封存机制,煤层气封存主要利用了吸附封存机制。国内外学者和机构针对各类封存技术提出了相应的计算方法,依据其计算原理可归纳为4类: 物质平衡封存量计算法、有效容积封存量计算法、溶解机制封存量计算法以及考虑多种捕获机制的综合封存量计算法。通过对各类经典方法及其计算原理进行综述,剖析潜力封存量计算方法的内涵原理和应用场景,分析了CO₂地质封存潜力评价方法在实际应用中面临的问题,有助于提升我国的CCS潜力评价质量。  相似文献   

Arsenic contamination caused by roxarsone transformation with spatiotemporal variation of microbial community structure in a column experiment          下载免费PDF全文

Liu Ya-ci  Zhang Zhao-ji  Zhao Xin-yi  Wen Meng-tuo  Cao Sheng-wei  Li Ya-song 《地下水科学与工程》2021,9(4):304-316

Arsenic contamination from roxarsone in livestock manure is common, and livestock manure continuously accumulates in the open environment. Evaluations of the environmental processes of As mobilization and transformation are critical for predicting the fate of As compounds after roxarsone degradation. In this study, spatiotemporal variations in As species and microbial community structure were characterized using laboratory column experiments with background soil collected from Yanggu County (northern Shandong Plain, China), a region of intense poultry production. Organic and inorganic arsenic were detected by high-performance liquid chromatography (HPLC) and HPLC with hydride generation atomic fluorescence spectrometry (HPLC-HG-AFS), respectively. High-throughput sequencing technology was used to describe microbial diversity. Results showed that roxarsone was transformed completely within 7 days, and As(Ⅲ) and As(Ⅴ) were the major degradation products. The concentration of As(Ⅲ) was much lower than that of As(Ⅴ). The As(Ⅲ) concentration increased significantly after Day 14, whereas the As(Ⅴ) concentration increased significantly after Day 84, indicating that As(Ⅲ) was initially produced. The microbial community structure changed significantly as roxarsone transformed into various As compounds. A critical and dominant bacterial strain, norank_f__Family_XVⅢ, was found to be related to the degradation of roxarsone into As(Ⅲ). This study improves our understanding of the fate of As species released from poultry litter to soil and groundwater, which is a threat to human health and environment.  相似文献   

Dispersion performance of nanoparticles in water          下载免费PDF全文

MA Li-sha  HAN Zhan-tao  WANG Yan-yan 《地下水科学与工程》2021,9(1):37-44

Engineering Nanoparticles(ENPs)’superior characteristics of adsorption depends on their dispersion in the medium.In this study,multi-walled carbon nanotubes(nonmetal),iron nanoparticles and silver nanoparticles(metallic simple substance),and Nano-TiO2,Nano-Fe2O3 and Nano-ZnO(metal oxide)were selected and respectively added into pure water and aqueous solution with 1%Sodium dodecyl benzene sulfonate(SDBS)surfactant.The dispersion effects were compared by leaving the solutions standing at room temperature under ultrasound.The results show that the dispersion of iron nanoparticles is the lowestamong the six ENPs,and that of multi-walled carbon nanotubes(MWCTS)is the highest.Adding anionic surfactants(SDBS)can obviously improve the dispersion performance of ENPs.The concentration of solution decreases by only 5%in 10 daysafter adding 1%SDBS for ultrasonic dispersion.  相似文献   

一次层状云降雨过程多源遥感特征参量演变分析     

杨文霞  范皓  杨洋  赵利伟 《气象》2019,45(9):1278-1287

利用河北省邢台市皇寺国家观测站布设的Ka波段云雷达、微波辐射计和微雨雷达以及地面雨量计等观测资料,对2017年5月3日一次西南涡天气过程的降水云系进行了综合分析,结果表明:本次降水过程为稳定性层状云过程,云内粒子下落速度由高空向地面逐渐增大,第一轮降水出现在云的发展阶段,第二轮降水出现在云的成熟阶段,每次降水开始前云内的相对湿度、水汽含量、液态水含量和温度曲线同时出现跃增和峰值,各指标在降水结束后出现较明显下降,之后得到恢复,出现第二三次峰值并产生降水;利用微波辐射计资料在时间和空间上连续反演计算云中水汽压和冰面饱和水汽压差值场("e—E_i"差值场),当云中过冷水和过冷水汽大值区与"e—E_i"差值场的正值区重合时,冷云中贝吉龙过程较强,有利于精细化定量判断强降水出现和人工增雨潜力区位置,综合以上遥感探测资料分析结果,可以认为本次天气过程有利的人工增雨作业时机出现两次,第一次在13:45降水刚刚开始至云顶下降到6 km前;第二次时间较长,云层条件更为有利,即17:40—21:15云顶高度维持在8~10 km的时段;作业适宜高度为4~8 km(-20~0℃)。  相似文献   

京津冀区域龙卷风灾害特征分析   总被引：1，自引：0，他引：1  

杜康云  顾光芹  许启慧  杨铭  刘金平  白璐瑶 《气象科技》2019,47(1):140-146

基于气象报表、中国气象灾害大典、气象灾情数据库以及档案馆地方志等历史资料,查阅1956—2016年京津冀区域的龙卷风个例,按照"增强藤田级别"龙卷风强度等级分类标准,采用专家评定法对龙卷风个例进行定级,并运用时间序列、趋势分析和空间分析方法,对龙卷风的时空分布、灾害特征进行了统计分析。主要结论如下:①1956—2016年,京津冀区域共确认龙卷风个例188个,空间分布上,龙卷风发生最多的区域有2个,一是张家口坝上4县:张北、尚义、沽源、康保,二是京津冀东部地区,特别是沧州、天津、唐山、秦皇岛沿海地区是龙卷风高发区;②时间分布上,1985—1993年龙卷风发生次数最多,90年代以后呈下降趋势;③龙卷风在夏季发生次数占总数的81.9%,龙卷风主要发生时段为11:00—20:00;④对有灾情记录的122个龙卷风个例,经专家评定,EF4和EF3级各1例,EF2级14例,EF1级52例,EF0级54例。  相似文献   

基于WACCM+DART的临近空间SABER和MLS臭氧观测同化试验研究   总被引：1，自引：0，他引：1  

敬文琪  王业桂  崔园园  蔡其发  兰伟仁 《大气科学》2019,43(2):233-250

本研究在WACCM+DART（Whole Atmosphere Community Climate Model,Data Assimilation Research Test-Bed）临近空间资料同化预报系统中加入SABER（Sounding of the Atmosphere using Broadband Emission Radiometry）和MLS（Microwave Limb Sounder）臭氧观测同化接口,并以2016年2月一次平流层爆发性增温（SSW）过程为模拟个例进行了SABER和MLS臭氧观测同化试验,得出以下结论:同化SABER和MLS臭氧体积浓度观测得出的WACCM+DART臭氧分析场能够较真实反映SSW期间北极上空平流层臭氧廓线随时间的演变特征,且与ERA5（Fifth Generation of ECMWF Reanalyses）再分析资料描述的臭氧变化特征具有很好的一致性;基于SABER和MLS臭氧观测的WACCM臭氧6 h预报检验表明同化臭氧观测对臭氧分析和预报误差的改善效果主要体现在南半球高纬平流层和北半球中高纬平流层中上层-中间层底部;基于ERA5再分析资料的WACCM+DART分析场检验表明同化SABER和MLS臭氧体积浓度资料可在提高北半球高纬地区上平流层-中间层底部臭氧场分析质量的同时减小该地区上平流层-中间层底部温度场和中间层底部纬向风场的分析误差;基于MLS臭氧资料的臭氧中期预报检验表明相对控制试验同化SABER和MLS臭氧体积浓度资料能更好改善0~5 d下平流层和中间层底部臭氧的预报效果。  相似文献   

承德市臭氧污染气象条件预报方法研究   总被引：1，自引：0，他引：1  

陆倩  王国辉  付娇  周士茹 《气象与环境学报》2019,35(6):67-76

利用2014-2016年承德市环境监测站和气象站的数据,分析了气象条件对承德市O₃-8h浓度的影响,探讨了臭氧污染气象条件的预报方法。结果表明：4-7月是承德市O₃-8h浓度较高的月份,O₃浓度的日变化特征为午后浓度高而夜间浓度低;O₃污染的天气形势为500 hPa受高压脊和偏西气流影响,850 hPa有强暖平流和20℃以上的高温,地面受低压前部和高压后部之间的偏南气流影响;有利于O₃-8h出现高浓度的气象因子为日平均气温大于23℃、日最高气温大于28℃、日平均海平面气压995-1007 hPa、日平均水汽压18-28 hPa、偏南风大于1 m·s^-1。利用气象因子综合评分建立臭氧污染指数,与O₃-8h浓度的相关系数高达0.7553,说明臭氧污染指数能较好地预报臭氧污染天气。  相似文献   

一次浓雾过程的观测分析     

甄晓菊  吴国明  杨晓亮 《黑龙江气象》2019,36(2):6-8,22

利用DMTFM120雾滴谱仪(2-50μm)、VAISALAPWD22能见度仪和六要素自动气象站对2016年11月3日河北省中南部平原地区的一次浓雾天气进行了观测分析。这次浓雾过程主要由于夜间辐射降温形成,晴夜风速较弱,低空存在较强逆温,属于典型的辐射雾。观测表明,由于夜间长波辐射冷却作用的增强,温度迅速下降,雾滴浓度突增,导致能见度突降,出现了浓雾的爆发。这次浓雾过程的能见度最低为71m,相对湿度93%-99%;雾滴的平均浓度为89cm^-3,最小2cm^-3,最大403cm^-3;平均直径为3.9μm,最大直径13.5μm;平均含水量为0.0033gm^-3,最小含水量0.00002g·m^-3,最大含水量0.038g·m^-3。总体而言,这次过程雾滴浓度不高、含水量较低,各阶段的雾滴谱分布都偏向小滴一端,谱宽较窄,缺乏大滴,不利于向强浓雾发展。  相似文献   

江陵凹陷古新统光卤石的发现及其钾盐找矿意义   总被引：5，自引：0，他引：5  

王春连  刘成林  刘宝坤  沈立建  蔡晓琳  余小灿  谢腾骁  王立成  赵艳军  宣之强 《地质学报》2015,89(1):129-136

通过薄片鉴定和XRD等分析,在江陵凹陷古新统发现光卤石矿物,单层厚度达23cm,经化学分析该层含光卤石石盐岩中光卤石含量为1.6%。光卤石在江陵凹陷古新统有两种产出状态:一种是被包裹在石盐岩内,呈颗粒状分布,粒度大小0.1~0.5mm;另一种是充填硬石膏孔隙中,粒度大小0.1~0.2mm。经石盐包裹体测温、碳氧同位素和元素地球化学研究,确定了江陵凹陷古新统时期的古气候属于"暖旱"型。江陵凹陷古近纪时期属于裂谷型小盆地,构造期沉降较大,盆地封闭性良好,同时期火山活动频繁,为凹陷带来丰富的成矿物质,火山期后的温热泉水补给同样也为凹陷带来丰富的成矿物质;裂谷的某些部分与大洋沟通,接受海水补给。这样的构造条件、物质条件与古近纪时期的干旱气候相互耦合,出现光卤石沉积。江陵凹陷古新统光卤石发现,说明在该时期江陵凹陷卤水已演化到析出钾盐阶段,具有重要找钾指示意义。  相似文献   

The Paleoproterozoic Montviel carbonatite-hosted REE–Nb deposit,Abitibi, Canada: Geology,mineralogy, geochemistry and genesis     

《Ore Geology Reviews》2015

The Montviel 250 Mt carbonatite-hosted REE–Nb deposit is hosted in a Paleoproterozoic alkaline suite located in the Sub-Province of Abitibi, in the Archean Province of the Superior. The alkaline intrusion consists of biotite clinopyroxenites, melano- to leucosyenites, a melteigite–ijolite–urtite series, riebeckite granite, a series of carbonatites and a carbonatite polygenic breccia. The carbonatite series includes silicocarbonatites, calciocarbonatites, rare magnesiocarbonatites, ferrocarbonatites and mixed carbonatites and are cut by a late, high-energy carbonatite polygenic breccia. Diamond drill hole assays and microscope observations indicate that Nb is hosted in pyrochlore from silicocarbonatite whereas the REE mineralization is mainly hosted in ferrocarbonatite, late mixed carbonatites and polygenic breccia, in REE-bearing carbonates and fluorocarbonate minerals. Diamond drill hole underground mapping and systematic assays have shed light on zones enriched in Nd and LREE with preferential Ba and Sr hydrothermal precipitation and zones enriched in Dy, Y and HREE displaying preferential F and P bearing hydrothermal precipitation. Petrographic observations, electron microprobe analyses, LA-ICPMS and X-ray diffraction were used to study the mineralization processes and to identify and quantify the REE-bearing burbankite–(Ce), carbocernaite–(Ce), ewaldite–(Y), huanghoite–(Nd), cordylite–(Ce), cordylite–(Nd), kukharenkoite–(Ce) and synchysite–(Ce). Most minerals are enriched in total LREE with values around 19.3 wt.%, have total MREE values around 2.2 wt.% and extremely variable total HREE values, with very high contents of Dy and Y averaging around 0.3 wt.% and 1.0 wt.%, respectively, and with total HREE reaching up to 10.0 wt.%. A paragenetic sequence is proposed that consists of: (1) a silicocarbonatite Nb stage, and (2) a calciocarbonatite stage, dominated by magmatism but accompanied by hydrothermal fluids, (3) a main ferrocarbonatite stage, dominated by episodes of Ba- and Sr-hydrothermalism and LREE mineralization, F- and P-hydrothermalism and HREE mineralization and evolved ferrocarbonatitic magmatism, (4) a renewed, mixed carbonatite magmatic stage with minor but increasing hydrothermalism, and (5) a terminal stage of fluid pressure buildup and explosion, leading to the creation of a HREE-enriched polygenic breccia. Globular melt inclusions of Ba–Cl–F (± Si–O) may indicate the presence and contribution of barium-bearing chlorofluoride melts during hydrothermal activity and mineralization of the carbonatite.  相似文献