安徽向山地区火山岩层中硬石膏的沉积成因特征及其与硫铁矿的关系   总被引：8，自引：0，他引：8  

胡文xuan  赵玉琛 《现代地质》1991,5(2):164-173

本文从赋矿地层,含矿层序、容矿岩性、矿石结构构造、矿物组合、生成顺序、地球化学特征以及区域对比等方面,论证了向山地区的硬石膏矿床是在蒸发环境条件下,主要由火山喷气作用提供物质来源,通过沉积作用所形成的特殊膏盐建造,并受到后期岩浆热液的叠加改造。文章还分析了硬石膏形成的地质环境条件。最后阐述了该区硫铁矿与硬石膏的两种成因关系。  相似文献   

湖南金矿床中黄铁矿和毒砂的含金性探讨   总被引：5，自引：0，他引：5  

鲍振襄 《矿产与地质》1991,5(5):368-374

(?)南的共生与(?)生金矿庆中的金,大部分为次显微金和(?)显微金.(?)中的黄铁矿和毒砂是金的主要载(?)矿物.金主要以机械混合物或微包体形式赋存,主要形成于硫(?)化物矿化(?)或晚期.矿石合金量的高低与载金矿物的晶形,(?)度,生成期及碎裂程度等有关.(?)黄铁矿、毒砂是金矿床的主要标型矿物.As是标型指示元素.  相似文献   

Gold and antimony metallogenic relations and ore-forming process of Qinglong Sb(Au) deposit in Youjiang basin,SW China: Sulfide trace elements and sulfur isotopes     

Jun Chen  Zhi-Long Huang  Rui-Dong Yang  Li-Juan Du  Ming-Yang Liao 《地学前缘(英文版)》2021,12(2):605-623

In the northwestern margin of the Youjiang basin(NWYB)in SW China,many Carlin-like gold deposits are highly antimony(Sb)-rich,and many vein-type Sb deposits contain much Au.These deposits have similar ages,host rocks,ore-forming temperatures,ore-related alterations and ore mineral assemblages,but the Au and Sb metallogenic relations and their ore-forming process remain enigmatic.Here we investigate the large Qinglong Sb deposit in the NWYB,which has extensive sub-economic Au mineralization,and present a new metallogenic model based on in-situ trace elements(EPMA and LA-ICP-MS)and sulfur isotopes(NanoSIMS and fs-LA-MC-ICPMS)of the ore sulfides.At Qinglong,economic Sb ores contain coarse-grained stibnite,jasperoid quartz and fluorite,whilst the sub-economic Au–Sb ores comprise dominantly veined quartz,arsenian pyrite and fine-grained stibnite.Three generations of ore-related pyrite(Py1,Py2 and Py3)and two generations of stibnite(Stb1 and Stb2)are identified based on their texture,chemistry,and sulfur isotopes.The pre-ore Py1 is characterized by the lower ore element(Au,As,Sb,Cu and Ag)contents(mostly below the LA-ICP-MS detection limit)and Co/Ni ratios(average 0.31)than the ore-stage pyrites(Py2 and Py3),implying a sedimentary/diagenetic origin.The Py2 and Py3 have elevated ore element abundance(maximum As=6500 ppm,Au=22 ppm,Sb=6300 ppm,Cu=951 ppm,Ag=77 ppm)and Co/Ni ratios(average 1.84),and have positive As vs.Au–Sb–Cu–Ag correlations.Early-ore Stb1 has lower As(0.12–0.30 wt.%)than late-ore Stb2(0.91–1.20 wt.%).These features show that the progressive As enrichment in ore sulfides is accompanied by increasing Au,Sb,Cu and Ag with the hydrothermal evolution,thereby making As a good proxy for Au.As-rich,As-poor and As-free zones are identified via NanoSIMS mapping of the Au-bearing pyrite.The As-rich zones in the Qinglong Au-bearing pyrites(Py2 and Py3)and ore stibnites(Stb1 and Stb2)have narrowδ³⁴SH₂S ranges(-8.9‰to +4.1‰,average-3.1‰)and-2.9‰to +6.9‰,average + 1.3‰),respectively,indicating that the Au-rich and Sb-rich fluids may have had the same sulfur source.Published in-situ sulfur isotopic data of pyrite As-rich zones from other Carlin-like Au deposits(Shuiyindong,Taipingdong,Nayang,Getang and Lianhuashan)in the NWYB have similar ore-fluidδSH₂S values(-4.5‰to +6.7‰,average-0.6‰)to those of Qinglong.Therefore,we infer that the sulfur of both Au and Sb mineralization was derived from the same magmatic-related source(0±5‰)in the NWYB.Moreover,the core of pyrites(Py1)has variable S isotope fractionation(-18.9‰to +18.1‰,mostly +3‰to +12‰),suggesting that the higher-³⁴S H₂S was produced by bacterial sulfate reduction(BSR).The hydrothermal pyrite(Py2 and Py3)δ³⁴S values gradually decrease with increasing As concentrations,and ultimately,within the restricted range(-5‰to +5‰)in As-rich zones.This variation implies that the As-rich pyrite was formed through ongoing interactions of the magmatic-hydrothermal fluid with pre-existing sedimentary pyrites,causing the progressive decreasing δ³⁴S values with As content increase,Hence,the fluid/mineral interaction may have generated the observed variation in δ³⁴S and As contents.Overall,comparing the Au and Sb deposits in the NWYB,we favor a magmatic-related source for the Au–Sb–As-rich fluids,but the Au-and Sb-ore fluids were likely evolved at separate stages in the ore-forming system.  相似文献   

赵家堡子金矿床黄铁矿矿物学研究   总被引：1，自引：0，他引：1       下载免费PDF全文

李忠满  刘娟  李士江 《地质找矿论丛》2003,18(Z1):11-15,42

赵家堡子金矿床金属矿物以黄铁矿为主,黄铁矿分为自形立方体,自形-半自形、半自形-他形立方体和五角十二面体及它们的聚形几种形态.不同形态的黄铁矿与金矿化关系不同,从围岩-矿体黄铁矿的形态特征、热电性、主要成分和微量元素、稀土元素、同位素及包体几方面进行对比研究的结果表明,黄铁矿标型特征不但指示矿床成因,而且是重要的找矿标志.  相似文献   

Genetic implications of pyrite chemistry from the Palaeoproterozoic Olary Domain and overlying Neoproterozoic Adelaidean sequences, northeastern South Australia   总被引：4，自引：0，他引：4  

Chris Clark  Ben Grguric  Andreas Schmidt Mumm 《Ore Geology Reviews》2004,25(3-4):237-257

Sulphide mineralisation associated with rocks from the Palaeoproterozoic Olary Domain (OD) and overlying Neoproterozoic Adelaidean sequences has undergone a complex history of metamorphism and remobilisation. In this study, new trace element and sulphur isotopic analyses of pyrites from a large number of deposits and paragenetic generations are combined with an existing data set to build up a sequence of mineralising events linked to the tectonometamorphic evolution of the region. The typically high Co/Ni ratios (>10) indicate that early strata-bound pyrite precipitated from a volcanic-related fluid, which had fluctuating activities of the two metals during the early stages of the evolution of the Willyama basin. This period of mineralisation was followed by a diagenetic concentration of sulphide mineralisation at the horizon known as the Bimba Formation, which occurred as a result of the differing redox conditions between the upper and lower sequences in the Willyama Supergroup. During the Mesoproterozoic (1600 to 1500 Ma) Olarian Orogeny, metamorphic remobilisation of strata-bound pyrite resulted in an epigenetic signature; the trace element concentrations of this generation were controlled primarily by the proximity of mineralisation to the mafic intrusive bodies found throughout the terrane. Further reworking of existing sulphides during the Delamerian Orogeny and associated granitoid-intrusive rocks led to the formation of a new generation of epigenetic pyrite that occurs in quartz veins in the Adelaidean sequences and veins that crosscut Olarian fabrics in the Olary Domain. δ³⁴S results range from 16‰ to 11‰, but most data fall between 2‰ and 4‰. This association is suggestive of an initial uniform deep-seated crustal reservoir of sulphur, which has been repeatedly tapped throughout the metallogenic history of the region. The isotopic outliers can be explained by the input of biogenic sulphur or sulphur derived from oxidised, possibly evaporitic, sediments, respectively. Previous workers have invoked the Kupferschiefer and the Zambian Copperbelt as analogues to mineralisation processes in the Olary Domain. This study shows that δ³⁴S and trace element data are suggestive of some affinities with the aforementioned analogues, but a more likely link can be made between epigenetic remobilisation in the Olary region and the iron oxide copper gold (IOCG) style of mineralisation found at the nearby Olympic Dam deposit.  相似文献   

Ab initio elasticity of FeS2 pyrite from 0 to 135 GPa     

Y. Le Page  J. R. Rodgers 《Physics and Chemistry of Minerals》2005,32(8-9):564-567

Polynomial expressions for the elastic tensor coefficients, the bulk, the shear and Young’s moduli, the speed of sound for longitudinal and transverse waves, the equation of state and the x coordinate of the sulfur atom in pyrite are reported based on ab initio calculations in the range of 0–135 GPa. Comparison with published experimental data indicates good agreement for the equation of state and for values at 0 GPa as well as reasonable agreement for first derivatives. All modeling and interpretation was performed with Materials Toolkit v.2.0 and all ab initio computations with VASP.  相似文献   

The natural attenuation of two acidic effluents in Tharsis and La Zarza-Perrunal mines (Iberian Pyrite Belt, Huelva, Spain)     

Javier Sánchez España  Enrique López Pamo  Esther Santofimia Pastor  Jesús Reyes Andrés  Juan Antonio Martín Rubí 《Environmental Geology》2005,49(2):253-266

The geochemical evolution of two acid mine effluents in Tharsis and La Zarza-Perrunal mines (Iberian Pyrite Belt, Huelva, Spain) has been investigated. In origin, these waters present a low pH (2.2 and 3.1) and high concentrations of dissolved sulphate and metals (Fe, Al, Mn, Cu, Zn, As, Cd, Co, Cr, Ni). However, the natural evolution of these acidic waters (which includes the bacterial oxidation of Fe(II) and the subsequent precipitation of Fe(III) minerals) represents an efficient mechanism of attenuation. This self-mitigating process is evidenced by the formation of schwertmannite, which retains most of the iron load and, by sorption, toxic trace elements like As. The later mixing with pristine waters rises the pH and favours the total precipitation of Fe(III) at pH 3.5 and, subsequently, Al compounds at pH 4.5, along with the sorption of trace metals (Mn, Zn, Cu, Cd, Co, Ni) until chemical equilibrium at circumneutral conditions is achieved.  相似文献   

陕西镇旬地区金矿黄铁矿的标型特征与初步总结及其找矿意义     

侯满堂 《陕西地质》1995,(2)

陕西镇（安）旬（阳）地区主要分布着微细浸染型、钠长石碳酸盐角砾岩型和石英脉型金矿。黄铁矿是区内金矿中分布最广、最重要的载金矿物。通过对诸金矿中黄铁矿的形态、主成分、微量元素、晶体结构、红外吸收光谱及热电性标型特征的总结和研究表明，黄铁矿标型特征的明显差异反映了其成因的不同，其形态和热电性标型特征是预测成矿远景地段的有效方法之一。  相似文献   

南极洲万达盐湖底部现代沉积物中黄铁矿物的发现及其地球化学意义     

于升松  Green W. J. 《盐湖研究》1993,(1)

作者首次在南极洲万达盐湖底部现代沉积物中发现了自生的黄铁矿颗粒。该发现对解释万达湖还原层湖水中铁离子的垂直迁移具有重要地球化学意义。基于1.目前万达湖还原层湖水的FeS_2活度积(IAP)大于它的热动力溶度积(Ksp)2.该湖还原层湖水的pH—pE数据组落在黄铁矿的pH—pE相图中的黄铁矿相区。相图预测到现在万达湖还原层湖水有析出自生黄铁矿的可能性,而且进一步被X射线衍射分析及电镜扫描等资料证实,湖底沉积物中存在黄铁矿矿物。这样,就有力地解释了还原层湖水中铁离子浓度降低的原因—由于黄铁矿颗粒的形成而迁出了水中铁离子。  相似文献   

An attempt to use LA-ICP-SMS to quantify enrichment of trace elements on pyrite surfaces in oxidizing mine tailings     

Björn Öhlander  Barbara Müller  Mikael Axelsson  Lena Alakangas 《Journal of Geochemical Exploration》2007

Metals released from oxidation and weathering of sulphide minerals in mine tailings are to a high degree retained at deeper levels within the tailings themselves. To be able to predict what could happen in the future with these secondarily retained metals, it is important to understand the retention mechanisms. In this study an attempt to use laser ablation high-resolution ICP-MS (LA-ICP-SMS) to quantify enrichment of trace elements on pyrite surfaces in mine tailings was performed. Pyrite grains were collected from a profile through the pyrite-rich tailings at the Kristineberg mine in northern Sweden. At each spot hit by the laser, the surface layer was analyzed in the first shot, and a second shot on the same spot gave the chemical composition of the pyrite immediately below. The crater diameter for a laser shot was known, and by estimating the crater depth and total pyrite surface, the total enrichment on pyrite grains was calculated. Results are presented for As, Cd, Co, Cu, Ni and Zn. The results clearly show that there was an enrichment of As, Cd, Cu and Zn on the pyrite surfaces below the oxidation front in the tailings, but not of Co and Ni. Arsenic was also enriched on the pyrite grains that survived in the oxidized zone. Copper has been enriched on pyrite surfaces in unoxidized tailings in the largest amount, followed by Zn and As. However, only 1.4 to 3.1% of the Cd and Zn released by sulphide oxidation in the oxidized zone have been enriched on the pyrite surfaces in the unoxidized tailings, but for As and Cu corresponding figures are about 64 and 43%, respectively. There were many uncertainties in these calculations, and the results shall not be taken too literally but allowed the conclusion that enrichment on pyrite surfaces is an important process for retention of As and Cu below the oxidation front in pyrite rich tailings. Laser ablation is not a surface analysis technique, but more of a thin layer method, and gives no information on the type of processes resulting in enrichment on the pyrite surfaces. Although only pyrite grains that appeared to be fresh and without surface coatings were used in this study, the possibility that a thin layer of Fe-hydroxides occurred must be considered. Both adsorption to the pyrite directly or to Fe-oxyhydroxides may explain the enrichment of As, Cd, Cu and Zn on the pyrite surfaces, and, in the case of Cu, also the replacement of Fe(II) by Cu(II) in pyrite.  相似文献