Road construction through sulfidic materials in Virginia has resulted in localized acid rock drainage (ARD) that threatens water quality, sedimentation, integrity of building materials, and vegetation management. Geologic formations associated with acid roadcuts were characterized by potential peroxide acidity (PPA), expressed as calcium carbonate equivalence (CCE), and total sulfur (total-S) in order to develop a statewide sulfide hazard rating map. The geologic formations were grouped into four categories based on potential acid-producing severity: i) Tabb formation (PPA<6 Mg CCE/1000 Mg; S<0.2%); ii) Ashe formation (PPA<18 Mg CCE/1000 Mg; S<2.0%); iii) Chesapeake Group, Lower Tertiary deposits, Millboro shale, Marcellus shale, and Needmore Formation (PPA<60 Mg CCE/1000 Mg; S<2.6%), and; iv) Chattanooga shale and Quantico slate (PPA<99 Mg CCE/1000 Mg; S<3.9%). Sulfide hazard analysis should be an essential step in the pre-design phase of highway construction and other earth-disturbing activities. 相似文献
SW Iberia is interpreted as an accretionary magmatic belt resulting from the collision between the South Portuguese Zone and the autochthonous Iberian terrane in Variscan times (350 to 330 Ma). In the South Portuguese Zone, pull-apart basins were filled with a thick sequence of siliciclastic sediments and bimodal volcanic rocks that host the giant massive sulphides of the Iberian Pyrite Belt. Massive sulphides precipitated in highly efficient geochemical traps where metal-rich but sulphur-depleted fluids of dominant basinal derivation mixed with sulphide-rich modified seawater. Massive sulphides formed either in porous/reactive volcanic rocks by sub-seafloor replacement, or in dark shale by replacement of mud or by exhalation within confined basins with high biogenic activity. Crustal thinning and magma intrusion were responsible for thermal maturation and dehydration of sedimentary rocks, while magmatic fluids probably had a minor influence on the observed geochemical signatures.The Ossa Morena Zone was a coeval calc-alkaline magmatic arc. It was the site for unusual mineralization, particularly magmatic Ni–(Cu) and hydrothermal Fe-oxide–Cu–Au ores (IOCG). Most magmatism and mineralization took place at local extensional zones along first-order strike-slip faults and thrusts. The source of magmas and IOCG and Ni–(Cu) deposits probably lay in a large mafic–ultramafic layered complex intruded along a detachment at the boundary between the upper and lower crust. Here, juvenile melts extensively interacted with low-grade metamorphic rocks, inducing widespread anatexis, magma contamination and further exsolution of hydrothermal fluids. Hypersaline fluids (δ18Ofluid > 5.4‰ to 12‰) were focused upward into thrusts and faults, leading to early magnetite mineralization associated with a high-temperature (> 500 °C) albite–actinolite–salite alteration and subsequent copper–gold-bearing vein mineralization at somewhat lower temperatures. Assimilation of sediments by magmas led in turn to the formation of immiscible sulphide and silicate melts that accumulated in the footwall of the layered igneous complex. Further injection of both basic and sulphide-rich magmas into the upper crust led to the formation of Ni–(Cu)-rich breccia pipes.Younger (330 to 280 Ma?) peraluminous granitoids probably reflect the slow ascent of relatively dry and viscous magmas formed by contact anatexis. These granitoids have W–(Sn)- and Pb–Zn-related mineralization that also shows geochemical evidence of major mantle–crust interaction. Late epithermal Hg–(Cu–Sb) and Pb–Zn–(Ag) mineralization was driven by convective hydrothermal cells resulting from the high geothermal gradients that were set up in the zone by intrusion of the layered igneous complex. In all cases, most of the sulphur seems to have been derived from leaching of the host sedimentary rocks (δ34S = 7‰ to 20‰) with only limited mixing with sulphur of magmatic derivation.The metallogenic characteristics of the two terranes are quite different. In the Ossa Morena Zone, juvenile magmatism played a major role as the source of metals, and controlled the styles of mineralization. In the South Portuguese Zone, magmas only acted as heat sources but seem to have had no major influence as sources of metals and fluids, which are dominated by crustal signatures. Most of the magmatic and tectonic features related to the Variscan subduction and collision seem to be masked by those resulting from transpressional deformation and deep mafic intrusion, which led to the development of a metallogenic belt with little resemblance to other accretionary magmatic arcs. 相似文献
Volcanic rocks from Serra Branca, Iberian Pyrite Belt, Portugal, consist of calc-alkaline felsic and intermediate rocks. The latter are massive andesites, whereas the former include four dacitic to rhyolitic lithologies, distinguishable on spiderdiagrams and binary plots of immobile elements. Zircon thermometry indicates that two felsic suites may have formed from different magmas produced at distinct temperatures, with only limited fractionation within each suite. Alternatively, all the felsic rocks can be related through fractionation of a single magma if the lower zircon saturation temperature obtained for one suite merely results from Zr dilution, mostly reflecting silicification.
The relatively high magma temperatures at Serra Branca ease the classification of felsic rocks based on their HFSE contents and also indicate volcanogenic massive sulfide deposit favorability. This contrasts with other areas of the Belt that register lower magma temperatures and are subsequently barren. However, magma temperatures may have not been high enough to cause complete melting of refractory phases in which HFSE reside during crustal fusion of an amphibolite protolith, implying difficult discrimination of tectonic environments for the felsic rocks. The intermediate rocks were possibly formed by mixing between basaltic magmas and crustal material, compatible with volcanism in an attenuated continental lithosphere setting. 相似文献
As a result of the collapse of a mine tailing dam, a large extension of the Guadiamar valley was covered with a layer of pyritic sludge. Despite the removal of most of the sludge, a small amount remained in the soil, constituting a potential risk of water contamination. The kinetics of the sludge oxidation was studied by means of laboratory flow-through experiments at different pH and oxygen pressures. The sludge is composed mainly of pyrite (76%), together with quartz, gypsum, clays, and sulphides of zinc, copper, and lead. Trace elements, such as arsenic and cadmium, also constitute a potential source of pollution. The sludge is fine grained (median of 12 μm) and exhibits a large surface (BET area of 1.4±0.2 m2 g−1).
The dissolution rate law of sludge obtained is r=10−6.1(±0.3) [O2(aq)]0.41(±0.04)aH+0.09(±0.06) gsludge m−2 s−1 (22 °C, pH=2.5–4.7). The dissolution rate law of pyrite obtained is r=10−7.8(±0.3) [O2(aq)]0.50(±0.04)aH+0.10(±0.08) mol m−2 s−1 (22 °C, pH=2.5–4.7). Under the same experimental conditions, sphalerite dissolved faster than pyrite but chalcopyrite dissolves at a rate similar to that of pyrite. No clear dependence on pH or oxygen pressure was observed. Only galena dissolution seemed to be promoted by proton activity. Arsenic and antimony were released consistently with sulphate, except at low pH conditions under which they were released faster, suggesting that additional sources other than pyrite such as arsenopyrite could be present in the sludge. Cobalt dissolved congruently with pyrite, but Tl and Cd seemed to be related to galena and sphalerite, respectively.
A mechanism for pyrite dissolution where the rate-limiting step is the surface oxidation of sulphide to sulphate after the adsorption of O2 onto pyrite surface is proposed. 相似文献
This paper describes coal petrographic characteristics, sulfur abundance, distribution and isotopic signature in coals in the Wuda coalfield, Inner Mongolia, northern China. Petrographic studies suggest that depositional environment influences petrographic composition. The No. 9 and No. 10 coal seams, which are thought to have formed on a tidal delta plain, have high collodetrinite contents (up to 66.1%) indicating enhanced gelification and bacteria activity during coal accumulation, and also have the highest sulfur content (3.46% and 3.42%). Both organic and pyritic sulfur isotope values (−12.3‰ to 5.8‰ and −18.7‰ to 1.1‰, respectively) are variable and generally tend to be more negative in high-sulfur coals than those in low-sulfur coals in the Wuda coalfield. The negative sulfur isotope values indicate that a large portion of sulfur in the high-sulfur coals has a bacterial origin. Sulfur isotopic compositions and variations within the section were used to propose a model to explain the origin of sulfur in these coals. The presence of pyritized rod-like bacteria, cyanophyte's gelatinous sheaths and degraded algae organic matter suggests that bacteria, and perhaps algae, may play an important role in the formation of these high-sulfur coals. 相似文献
The assessment of the aluminosilicate buffering potential during acid weathering of the Estonian alum shale is provided.
It is found that the stoichiometric interaction between dissolved pyrite oxidation products and illite of the shale best describe
the buffering process and are consistent with earlier field studies. The scheme includes incongruent dissolution of illite
with smectite and K-jarosite precipitating. This complex mechanism involves buffering of 8% of the acidity by K+ and temporary precipitation of 25% of the acidity as K-jarosite. Dissolution proceeds at a low pH (1.5–3) until all pyrite
in the shale particle is oxidised. Hence, if the total amount of illite present is larger than needed for stoichiometric interactions,
only part of it is involved in a buffering process, neutralising a certain percentage of acidity. The next stage in shale
weathering is the incongruent dissolution of K-jarosite with the release of the precipitated acidity and the formation of
ferric oxyhydroxide.
Received: 3 August 1998 · Revised paper: 26 January 1999 · Accepted: 23 February 1999 相似文献