三塘湖盆地二叠系干酪根热模拟气体产物的地球化学特征     

杜军艳  程斌  廖泽文 《地球化学》2014,(5):510-517

针对三塘湖盆地的主力烃源岩二叠系芦草沟组泥质烃源岩开展封闭体系和半开放体系热模拟实验,前者将干酪根密封在金管中开展实验、后者直接对烃源岩样品进行压机半开放体系热解模拟,对实验中生成气体的组分和稳定碳同位素进行分析。实验结果显示,两种热解方法以无机气体生成为主,包括CO2、H2、H2S 和 N2等,其中 CO2含量最丰富,这与样品干酪根中丰富的氧含量一致。半开放体系模拟实验温度达到480℃时,气态烃的含量达40.64%,其中甲烷含量达到26.10%,封闭体系中随着模拟温度升高烃类气体产物的碳同位素呈现先变轻后变重的趋势,但同位素分馏程度不大, CH4气体的δ13C 值分布在-40.2‰~-46.6‰之间, C2H6分布在-34.3‰~-38.0‰之间, C3H8分布在-33.6‰~-36.0‰之间,而CO2气体δ13C值分布在-32.8‰~-28.8‰之间。三塘湖盆地针对气藏的勘探已经有所发现,但有关气藏的地球化学特征报道较少,该工作中的模拟实验结果可为三塘湖盆地深入的气藏地球化学勘探提供基础数据。  相似文献   

Thermal simulation of basic volcanic fluid influence on different source rocks     

Jiyan Li  Xuanlong Shan  Zhe Sun  Xiaoting Xie  Yu Ren 《中国地球化学学报》2014,33(2):168-172

Based on thermal simulation experiment, interactions between volcanic fluids and source rocks were studied. Gas generations in the dry system and fluid system under different temperatures were analyzed. The results showed that the various types of source rocks are similar in composition, containing gaseous C1-C5 hydrocarbons, H2 and CO2 whose gas yields increase with increasing temperature. The gas yield of source rocks of type I is the high- est, followed by type II, and that of source rocks of type III is the lowest, indicating that the yield of hydrocarbon gases is related to their hydrocarbon generating potential. Although the generating potential of type III is the lowest, it can still be regarded as a useful gas source when it is buried deeply enough. The basic volcanic fluid restrains the generation of gaseous hydrocarbons in different types of source rocks, but promotes the generation of inorganic gases.  相似文献   

一滴水     

王静静 《资源导刊(河南)》2007,(7)

我的名字是水,化学式为H2O,有固体、液体、气体三种形态. 自从水妈妈把我生下来以后,我的生活一直很安逸,冬天为固态,夏天为液态.我喜欢固态,因为我可以随意变幻不同的造型,有方,有圆,还有不规则的多边形.  相似文献   

深部碳酸盐储层中轻烃气体对硫酸盐进行热化学还原（TSR）...     

Krou.  HR 肖轶 《地质地球化学》1990,(6):39-43

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生物技术让地里“长”出能源     

董少广  董良 《河南国土资源》2006,(2):38

我们知道，今天人们所用的石油、煤炭、天然气等传统能源，都是由植物等腐烂变成的。由生物体到化成能源这一过程，大自然用了上亿年的时间，数百年来，它们一直是人类能源的主角。但是这些传统能源大多属于不可再生能源，随着工业文明进程的不断加快，这些资源将面临枯竭。同时，传统能源在使用和生产的过程中还会带来各种污染，如温室气体的排放，已经严重影响人类的生活环境。我国是一个有13亿人口、能源短缺的大国，加紧开发低污染乃至无污染的绿色能源已迫在眉睫。  相似文献   

华北地下释放氦,氢等气体异常的时,空,强特征及与地震预报三要素关系的研究     

港树全 《国际地震动态》1994,(7):16-18

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非理想效应的冷密气体状态方程及其在天体物理中的应用     

Luo  GQ 《紫金山天文台台刊》1994,13(2):162-167

On the basis of the theory of the grand-canonical ensemble, we have developed a grand-canonical approach in the 'chemical picture" for the equation of state. The approach defines atomic configuration probabilities and gives a conservation equation for the electron number for calculating the occupation numbers of atoms and molecules. The approach also incorporates the perturbations caused by plasma interactions in cool-dense gases into the equation of state formulation and gives the resulting nonidca) terms of thcrmodynamic properties. The resulting formulae have been applied to the study of the properties of cool-dense plasmas and standard solar models. The phase transitions of high temperature plasmas and the influences of pressure ionization effects through solar interior opacities on solar models have been investigated.  相似文献   

Molecular Gas and Dust in the Massive Star Forming Region S 233 IR     

Rui-Qing Mao  Qin Zeng Purple Mountain Observatory  Chinese Academy of Sciences  Nanjing  National Astronomical Observatories  Chinese Academy of Sciences  Beijing 《中国天文和天体物理学报》2004,4(5):440-454

The massive star forming region S 233 IR is observed in the molecular lines CO J = 2-1, 3-2, NH3 (1,1), (2,2) and the 870#m dust continuum. Four submillimeter continuum sources, labelled SMM 1-4, are revealed in the 870μm dust emission. The main core, SMM1, is found to be associated with a deeply embedded near infrared cluster in the northeast; while the weaker source SMM2 coincides with a more evolved cluster in the southwest. The best fit spectral energy distribution of SMM1 gives an emissivity of β = 1.6, and temperatures of 32 K and 92 K for the cold- and hot-dust components. An SMM1 core mass of 246 M⊙ and a total mass of 445 M⊙ are estimated from the 870μm dust continuum emission.SMM1 is found to have a temperature gradient decreasing from inside out, indicative of the presence of interior heating sources. The total outflow gas mass as traced by the CO J = 3-2 emission is estimated to be 35 M⊙. Low velocity outflows are also found in the NH3 (1,1) emission. The non-thermal dominant NH3 line width as well as the substantial core mass suggest that the SMM1 core is a “turbulent,massive dense core”, in the process of forming a group or a cluster of stars. The much higher star formation efficiency found in the southwest cluster supports the suggestion that this cluster is more evolved than the northeast one. Large near infrared photometric variations found in the source PCS-IR93, a previously found highly polarized nebulosity, indicate an underlying star showing the FU Orionis type of behavior.  相似文献   

河外H2O超脉泽源及与其相关的分子谱线的观测和研究     

俞志尧 《天文学进展》2002,20(3):256-264

自从在活动星系核NGC4945的视线方向上发现第一个河外H2O超脉泽源以来，迄今为止已发现了19个河外H2O超脉泽源，对与活动星系核成协和河外H2O超脉泽源及分子谱线的观测和研究是探测和研究活动星系核核区中央源，拱核气体和尘埃环性质的非常有效的工具，主要评述对河外H2O超脉泽源及与其相关分子谱线的搜索，观测和理论研究现状。  相似文献   

农业气象试验站温室土壤温度控制系统     

马丽  万长健 《南京气象学院学报》1998,21(4):750-754

采用８０３１,８２７９,８２５５,ＡＤＣ０８０９,２８６４,６２６４等芯片组成一实用的温室土壤温度控制系统。由键盘输入温室土壤的上,下限温度,通过ＡＤＣ０８０９对温室土壤温度进行采样,并实时显示土壤温度。当土壤温度超越上,下限时,系统报警,并进行自动处理。  相似文献