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151.
城市污泥接种堆置处理对重金属的形态及其生物有效性的影响 总被引:1,自引:0,他引:1
污泥堆肥化后的土地利用是污泥处理处置的重要方法之一。经过对荆马河底泥接种堆置处理,揭示出污泥中重金属的形态发生明显的变化。荆马河底泥中的重金属污染物主要以结合态和残渣态的形式存在,水溶态和交换态的量很小,经接种堆置处理后,水溶态和交换态量大幅削减,结合态和残渣态量有所增加,总量变化不大,生物学方法和化学方法测定都表明,处理后的底泥生物毒性有明显降低,重金属的生物有效性降低。 相似文献
152.
《海洋技术学报》2024,(1)
滨海湿地作为一种具有多种功能和蕴含丰富资源的生态系统,是人类重要的生存环境之一。湿地土壤重金属污染问题是当前湿地科学领域内的热点话题。为研究河北省滦南滨海湿地重金属污染特征,本文利用单因子指数法、内梅罗综合污染指数法和地累积指数法对重金属污染状况进行评价。结果表明:铜(Cu)、锌(Zn)、铬(Cr)、铅(Pb)、镉(Cd) 的单因子质量指数均小于1.0,说明研究区重金属含量小于土壤背景值,土壤未受到污染。内梅罗综合指数法Cu、Zn、Cr、Pb、Cd 指数均小于0.7,表明滦南湿地土壤重金属污染水平处于未污染。湿地各区域重金属地累积指数为无污染或较轻污染,其中Pb 污染为较轻污染,监测点主要与人类活动有关。利用地累积指数分析认为Pb 在湿地北区为轻度污染水平,经调查发现该区域主要为居民点,人类活动频繁,其他重金属均无污染。河北滦南滨河湿地土壤未受到重金属污染,湿地土壤环境较好。 相似文献
153.
Contents of heavy metals, polycyclic aromatic hydrocarbons (PA Hs), dichlorodiphenyltrichloroethanes (DDTs) and hexachlorcy- clohexanes (HCHs) in surface sediments from mangrove areas of the Leizhou Peninsula were analyzed in July and November 2005. Risk assessment criteria applied by Long E R et al. (1995) and Long E D et al. (1995) (effects range low, ERL; effects range mean, ERM) of chemicals in sediments from the gulf or estuary were used to assess the potential ecological risks of heavy metals, PAHs, DDTs and HCHs to aquatic organisms in the studied area. The results indicated that the average contents of zinc, nickel, chromium, lead, copper, arsenic and mercury were (61.97 ± 55.87), (59.99 ± 39.01 ), (47.93 ± 28.37), (26.64± 13.00) , (23.45 ± 41.96), (9.32 ± 3.62), (0.14 ± 0.18) mg/kg in dry weight in the sediment samples col- lected from five studied sites in the Leizhou Peninsula, respectively. Cadmium was not calculated due to its content being below the detection limit ( 〈 0.3 mg,/kg). The average levels of Cr, Cu, Ni, Pb, Zn and Hg exceed their background values. The average contents of Ni were higher than ERM. The contents of PAHs in the sediments from the five studied sites were (79.78 ± 43.70) ng/g in dry weight, far lower than ERL(4 022 ng/g). The contents of DDE, DDD and DDTs in the sediments from five studied sites were (2.60 ± 4.68), ( 17.52 ± 27.25 ), (27.78 ± 46.64) ng/g in dry weight respectively, clearly higher than ERL, and the average contents of DDT were (7.66 ± 15.93) ng/g in dry weight, much higher than ERM. HCHs could be detected in the sediments only from Gaoqiao sampling site, with the average contents (0.07 ± 0.08) ng/g in dry weight. 相似文献
154.
Accumulation of petroleum hydrocarbons and heavy metals in clams (Ruditapes philippinarum) in Jiaozhou Bay, China 总被引:2,自引:0,他引:2
Accumulation and distributions of aliphatic and polyaromatic hydrocarbons (PAHs) and heavy metals were measured in tissues
of the clam Ruditapes philippinarum collected from 5 sites in Jiaozhou Bay, Qingdao, China. The concentrations of total aliphatic hydrocarbon and PAHs ranged
from 570 to 2 574 ng/gdw (gram dry weight) and from 276 to 939 ng/gdw, in the most and least polluted sites, respectively.
The bio-accumulation of hydrocarbons and PAHs in the clams appeared to be selective. Aliphatic hydrocarbons were predominantly
represented by short chain (<nC23) n-alkanes, suggesting that petroleum hydrocarbons were likely the major contamination source. The selective uptake of 3 and
4 ring PAHs, such as naphthalene, fluorene, phenanthrene, fluoranthene and pyrene, by the clams was probably related to the
physiological and bio-kinetic processes that were energetically favorable for uptake of compounds with fewer rings. Accumulation
of the metals Cd, Cu, Zn, Pb, Cr, Hg, and As in the clam tissues also showed high variability, ranging from 0.043 to 87 μg/gdw.
Among the 7 detected metals, Zn, Cd, Cu, and As had a particularly high potential of accumulation in R. philippinarum. In general, a positive correlation was found between the tissue concentrations and sediment concentrations of hydrocarbons
and of some metals. Our study suggests that moderate contamination with polyaromatic hydrocarbons, and low to moderate contamination
with metals, currently exists for clam R. philippinarum in Jiaozhou Bay, in comparison with other regional studies. A long-term monitoring program is certainly needed for assessment
of the potential ecological influence and toxicity of these contaminants of R. philippinarum in Jiaozhou Bay. 相似文献
155.
土壤污染具有隐蔽性、潜伏性和长期性。土壤重金属污染基本上是一个不可逆转的过程。大庆市规划区土壤污染主要表现为石油烃类和重金属元素污染。 相似文献
156.
汕头湾地处汕头东部,是珠三角经济区和海峡西岸经济区重要的海上交通枢纽。因受周边城镇、养殖区排污等影响,汕头湾的海洋环境已受污染,生态健康问题不容忽视。沉积物中重金属是反映区域环境质量的重要因子,本研究通过测定汕头湾海域29个表层沉积物样品中重金属Zn、Cu、Cr、Cd、Pb、Hg、As含量,分析了各元素的平面分布特征,并运用主成分分析法(PCA)、地累积指数法和潜在生态风险指数法对该区域沉积物中重金属的来源及潜在生态风险进行了探讨。结果表明:汕头湾海域表层沉积物的金属含量变化范围为CZn(15. 3~280. 4 mg/kg)、CCu(2. 0~84. 6mg/kg)、CCr(3. 0~130. 8 mg/kg)、CCd(0. 05~1. 07 mg/kg)、CPb(12. 97~39. 31 mg/kg)、CHg(0. 008~0. 171 mg/kg)、CAs(1. 60~16. 50 mg/kg),榕江入海口处为重金属元素的高值区,在拦沙堤的两侧,元素Zn、Cu、Cr、Cd的含量差别较大。相关性分析和主成分分析结果显示,重金属具有相同污染来源,工业废水和城市排污等人类活动输入是主要途径,其分布特征受有机碳、硫化物及细粒级组分等环境因子的影响。地累积指数法和潜在生态风险指数法的结果表明,在榕江入海口附近区域,重金属表现出强的生态风险,而拦沙堤东侧海域为轻微生态风险,Hg、Cu、Cd是主要污染元素。 相似文献
157.
158.
Distribution characteristics of heavy metals in surface sediments and core sediments of the Shenzhen Bay in Guangdong Province, China 总被引:1,自引:1,他引:0
The concentration of zinc, chromium, cadmium, nickel, lead and copper was measured on both surface sediments and core sediments in the Shenzhen Bay. The average contents of all metals have exceeded the background values in the coastal zone of Guangdong Province. Cadmium is a heavy pollution matter which indicates a strong pollution level according to the ecological risk coefficient method. The ecological risk index of the whole area is 299 which belongs to middle and strong level. The area with strong pollution level is the near shore area closing to the inside of Shenzhen Bay, Shakou area is in the middle level while the weak pollution level occurs in Shenzhenhe Estuary according to ecological risk index. The four sediment cores can be divided into two parts based on lead-210 dating, sediments size analysis and economic development period in surrounding areas since 1950 with strong human intervention. The sediment size, deposition rate and human activities have positive relationship with the contents of heavy metals which directly impact the pollution level of heavy metals in sediments in Shenzhen Bay. 相似文献
159.
平阴县土壤中重金属元素异常成因研究 总被引:1,自引:0,他引:1
通过对平阴县周边及其西部农田区采样调查,平阴县周边元素异常具有异常衬度较高,富集系数大等特征,西部农田区异常具有各元素套合关系好,多数异常衬度不高,富集系数小的特点。结果表明,西部农田区异常是以As,Cd为主要成分的异常,元素含量与SiO2,Al2O3,Fe2O3等常量组分间具有显著的相关性,随SiO2含量的增加而降低,随Al2O3,Fe2O3含量的增加而增加,说明土壤常量组分及其所决定的土壤质地是导致异常形成的主要因素;而平阴城区异常是以S,Hg,As,Zn,Mn等元素为主的异常,是典型的人为综合因素(化工烟尘、工厂污水、生活垃圾)产生的异常。 相似文献
160.