Origin and occurrence of 25-norhopanes: a statistical study   总被引：1，自引：0，他引：1  

Ph. Blanc  J. Connan 《Organic Geochemistry》1992,18(6)

The alkane fraction of more than 200 rocks, biodegraded oils and non-biodegraded oils, have been analysed by means of computerized GC-MS, in order to investigate the effect of natural biodegradation on the occurrence of “demethylated hopanes”, i.e. 17α-25-norhopanes. The results obtained indicate that 25-norhopanes are preexisting biomarkers the concentration of which is enhanced by selective biodegradation of more readily degradable homologs, i.e. regular hopanes, rather than by demethylation of hopanes in reservoirs. However, the use of 25-norhopane enrichment as a palaebiodegradation indicator in apparently non-biodegraded oils is still valuable providing the initial background content in the corresponding source rocks is known. Furthermore, 25-norhopanes appear to be diagnostic of specific environmental conditions (marine and lacustrine source rocks, dysoxic and not very hypersaline). Lastly, one other (novel) bacterially resistant rearranged hopanoic compound, namely a C₂₉ neohopane, is applicable for both biodegradation and maturation evaluation.  相似文献   

Organic geochemistry of Cuban oils—I. The northern geological province     

P.G. Campos  J.O. Grimalt  L. Berdie  J.O. Lopez-Quintero  L.E. Navarrete-Reyes 《Organic Geochemistry》1996,25(8):475-488

The isoprenoid, hopanoid and steroid compositions of 15 oils from the most productive oil fields in Cuba were studied to determine source-rock depositional environments and organic matter sources. The oils, which are from the northern geological province of Cuba and can be defined by the position with respect to the overthrust belt, can be grouped into two families: those from the Remedios (1) and those from the Placetas (2) tectonostratigraphic units.Remedios oils contain 17α(H)-diahopane, high relative amounts of 18α(H)-22,29,30-trisnorneohopane and diasteranes, which is indicative of generation from clay-rich source rocks. The crude oils of the Placetas Unit exhibit a sterane/hopane composition consistent with a carbonate origin. Nevertheless, these polycyclic hydrocarbons exhibit significant changes in composition, indicating that several organic matter sources, e.g. a carbonate/evaporitic origin of Varadero and Varadero Sur oils, have contributed to the oils from this Unit. The Remedios oils are more mature [evaluated from the and sterane indices] than the Placetas oils.A wide range of biodegradation levels are encountered in these oils (from 0 to 7–8 using the scale derived by Volkman et al. (1983). The high relative abundance of 25-norhopanes is a distinctive feature of Remedios oils. The presence of these compounds in lightly biodegraded or nondegraded oils corresponds to a mixing of paleobiodegraded oil with more recently sourced nondegraded oil in the reservoir. The most biodegraded oil, Cantel, exhibits and sterane ratios, and hopane ratios that have been altered by microbial attack.  相似文献   

面向带洞面状对象间的拓扑关系描述模型   总被引：1，自引：1，他引：0  

沈敬伟  周廷刚  朱晓波 《测绘学报》2016,45(6):722-730

为研究带洞面状对象间的拓扑关系,提出了一种25IM(25交集模型)。以点集拓扑理论为基础,对带洞面状区域的内部、边界和外部进行定义。分析了9IM(9交集模型)在表达带洞面状对象间拓扑关系方面存在的问题,将带洞面状对象分为内部、外边界、内边界、外边界外部、内边界外部共5部分,提出了一种5×5的矩阵模型,即25IM。基于点集拓扑理论,定义了8条规则来排除不符合逻辑的拓扑关系。基于25IM,对8种基本拓扑关系:相离、相接、重叠、覆盖、包含、相等、被覆盖和被包含,进行细分描述。结果表明,本文提出的25IM能够更为详细地表达带洞面状对象间的拓扑关系。  相似文献   

A numerical study of swash flows generated by bores     

Qinghai Zhang  Philip L.-F. Liu   《Coastal Engineering》2008,55(12):1113-1134

The dynamic processes of bore propagation over a uniform slope are studied numerically using a 2-D Reynolds Averaged Navier–Stokes (RANS) solver, coupled to a non-linear k − ε turbulence closure and a volume of fluid (VOF) method. The dam-break mechanism is used to generate bores in a constant depth region. Present numerical results for the ensemble-averaged flow field are compared with existing experimental data as well as theoretical and numerical results based on non-linear shallow water (NSW) equations. Reasonable agreement between the present numerical solutions and experimental data is observed. Using the numerical results, small-scale bore behaviors and flow features, such as the bore collapse process near the still-water shoreline, the ‘mini-collapse’ during the runup phase and the ‘back-wash bore’ in the down-rush phase, are described. In the case of a strong bore, the evolution of the averaged turbulence kinetic energy (TKE) over the swash zone consists of two phases: in the region near the still-water shoreline, the production and the dissipation of TKE are roughly in balance; in the region farther landwards of the still-water shoreline, the TKE decay rate is very close to that of homogeneous grid turbulence. On the other hand, in the case of a weak bore, the bore collapse generated turbulence is confined near the bottom boundary layer and the TKE decays at a much slower rate.  相似文献   

极端生物降解沥青中8,14- 开环藿烷系列及其地球化学意义     

包建平  朱翠山  杨茜 《地质学报》2023,97(8):2659-2675

借助色谱- 质谱（GC- MS）和色谱- 质谱- 质谱（GC- MS- MS）分析,对黔南坳陷凯里残余油藏凯棠和洛棉剖面上储层沥青中的烃类组成进行了系统分析,以判断其所遭受生物降解作用的程度,探寻在极端降解原油中是否还存在原生生物标志物,为这类原油的油源研究开拓新的途径和方法。结果表明：凯棠剖面上的储层沥青中尽管仍可检测到较为完整的C19- 30三环萜烷和C27- 35藿烷系列,但C19- 29脱甲基三环萜烷系列和C26- 34 25- 降藿烷系列丰富而完整,甾烷系列中C21- 22低分子量甾烷和重排甾烷优势明显,这一系列特征表明这些沥青遭受了剧烈生物降解作用的改造。但三芳甾类仍保存完好,依据原油生物降解程度的评判标准,判断其生物降解级别介于8~9级之间。洛棉剖面上的储层沥青中藿烷系列基本消失殆尽,三环萜烷系列及其脱甲基产物和25- 降藿烷系列的分布因极端生物降解作用而发生显著变异,某些化合物如C23T、C24T、C23NTE和C28- 29NH成为优势成员;甾烷系列中C21- 22低分子量甾烷占绝对优势,三芳甾类完全消失,据此判断该剖面上沥青的生物降解级别已达到10级或更严重。由于这两个剖面上的沥青遭受了极端生物降解作用的改造,常用的甾、萜类生物标志物完全失去了实用价值。但是,在所分析的这些沥青中都检测到三个系列的C27- 35 8,14- 开环藿烷系列,它们与塔里木盆地塔中地区海相端元油中存在的同类标志物的分布特征相似。正常海相端元油和极端生物降解沥青中同时检测到这三个系列的8,14- 开环藿烷,这一事实表明这类生物标志物在成因上具有原生性,而与生物降解作用无关。此外,在极端生物降解作用沥青中的完好保存,表明它们具有极强的抗生物降解能力,因而它们在此类原油的油源研究中可能具有潜在的实用价值。  相似文献   

北极冰海耦合模式对两种不同大气再分析资料响应的分析   总被引：2，自引：2，他引：0  

牟龙江  赵进平 《海洋学报》2015,37(11):79-91

本文中我们比较了Climate Forecast System Reanalysis(CFSR)高分辨率的再分析数据集和低分辨率的Japanese 25-year Reanalysis Project(JRA25)再分析数据集在向下短波辐射、向下长波辐射、10m风场、近地面气温、降水、湿度上的不同,发现二者差异最大的为降水数据,其次为向下短波辐射数据、向下长波辐射数据。用这两个数据集驱动同一冰海耦合模式,CFSR强迫的海冰、北冰洋中层水和加拿大海盆温盐结构与实测相比有很大差距,等密度面上的地转流速在加拿大海盆和欧亚海盆比JRA25强迫的结果高20%,同时等密度面的深度偏深、位温偏高,在弗拉姆海峡的流通量也比海洋再分析数据Simple Ocean Data Assimilation(SODA)偏多。CFSR的向下辐射数据更加接近实测,采用此数据的敏感性实验模拟结果与实测符合的更好。对于海冰的模拟,云量起着至关重要的作用,降水带来的淡水通量通过影响大西洋入流水携带的热量进而影响到冰区。此外,CFSR过量的降水也是二者对于北冰洋温盐结构、弗拉姆海峡流通量以及地转流强度模拟产生偏差的主要原因。尽管风场的分辨率不同,在海盆尺度上对于海冰和海水温盐结构的影响并不大。  相似文献   

长白山圆池泥炭沼泽演变及环境信息记录   总被引：1，自引：0，他引：1  

张彦  史彩奎  王健  马小凡  吕宪国  王国平 《湿地科学》2012,10(3):271-277

通过分析长白山圆池泥炭剖面总有机碳含量、总正构烷烃含量、奇偶优势指数、(C23+C25)含量和2C31/(C27+C29)比值,讨论了泥炭发育不同时期植物输入情况,同时结合210Pb测年建立的年代序列来探讨该区的气候变化规律.研究结果显示,约1400年前,气候干冷,圆池尚没有出现沼泽化;1400年开始,气候稍暖,少量植物输入,圆池开始沼泽化;约从1860年至今,气候逐步转暖,大量植物输入,圆池沼泽化速度加快.  相似文献   

A CLIMATOLOGY OF EXTRATROPICAL TRANSITION OF TROPICAL CYCLONES IN THE WESTERN NORTH PACIFIC   总被引：1，自引：1，他引：0  

钟霖浩  华丽娟  冯士德 《热带气象学报(英文版)》2009,15(2):130-147

Based on best-track data and JRA-25 reanalysis, a climatology of western North Pacific extratropical transition (ET) of tropical cyclone (TC) is presented in this paper. It was found that 35% (318 out of 912) of all TCs underwent ET during 1979–2008. The warm-season (June through September) ETs account for 64% of all ET events with the most occurrence in September. The area 120°E–150°E and 20°N–40°N is the most favorable region for ET onsets in western North Pacific. The TCs experience ET at latitudes 30°N–40°N and have the greatest intensity in contrast to other latitude bands. The distribution of ET onset locations shows obviously meridional migration in different seasons. A cyclone phase space (CPS) method was used to analyze the TC evolution during ET. Except for some cases of abnormal ET at relatively high latitudes, typical phase evolution paths—along which TC firstly showed thermal asymmetry and an upper-level cold core and then lost its low-level warm core—can be used to describe the main features of ET processes in western North Pacific. Some seasonal variations of ET evolution paths in CPS were also found at low latitudes south of 15°N, which suggests different ET onset mechanisms there. Further composite analysis concluded that warm-season ETs have generally two types of evolutions, but only one type in cold season (October through next May). The first type of warm-season ETs has less baroclinicity due to long distance between the TC and upper-level mid-latitude system. However, significant interactions between a mid-latitude upper -level trough and TC, of either approaching or being absorbed into the trough, and TC’s relations with downstream and upstream upper-level jets, are the fingerprints for both a second type of warm-season ETs and almost all the cold-season ETs. For each type of ETs, detailed structural characteristics as well as precipitation distribution are illustrated by latitude.  相似文献   

CAN总线通信接口设计     

张建文  冯林  李百余 《华东地质学院学报》2010,33(3)

提出了一种用单片机STC89C52及SJA1000总线控制器组成CAN总线智能节点的设计方案,给出了硬件电路,并详细介绍了SJA1000初始化、接收及发送数据程序的框图及程序设计.设计中程序均已通过调试,介绍的设计方法易于掌握且具有较强的灵活性和通用性,方便使用者学习和掌握.  相似文献   

渤中25-1地区油气运移的输导通道及其示踪分析   总被引：1，自引：0，他引：1  

张成  解习农  张功成  刘晓峰  姜涛 《地质科技情报》2005,24(2):27-32

渤中25-1地区是渤中坳陷重要的含油气区,具有复杂的构造演化与沉积充填史,输导通道一直是该地区成藏动力学研究的关键.采取宏观与微观相结合的研究思路,在理清研究区构造演化、沉积充填及其油气地质特征的基础上,讨论了油气运移的输导通道并对其进行了示踪分析,进而总结了该区的油气成藏模式.研究表明,长期继承性活动的基底断层是油气垂向运移的主输导通道,原油性质及地层水化学特征证实了断层的输导作用.上新统明化镇组和渐新统沙河街组渗透性储层是油气侧向运移的主要通道.沙河街组油藏具有自源压控侧向运移成藏的特点,明化镇组油藏具有它源断控垂向运移成藏的特点.  相似文献