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21.
中国黄土的剩磁获得机理和Lock-in深度问题是目前黄土古地磁研究的焦点和核心问题之一,它直接关系到黄土时间标尺的精确度和海陆古气候对比的可靠性.文章以黄土高原东南缘三门峡曹村剖面获得的高分辨率古地磁极性界线作为年代控制点,通过黄土-古土壤序列1.1Ma以来的磁气候记录与近年来中、高纬度大西洋ODP/DSDP钻孔中获得的具有高分辨率古地磁年代约束的深海氧同位素记录进行了详细对比分析,提出与传统的海陆对比不同的基于古地磁界线的海陆对比方案:松山/布容地磁极性转换界线记录在曹村剖面S8的顶部,可对应深海沉积的MIS 19,而不是前人认为的MIS 21.黄土高原不同地区记录东亚冬、夏季风的差异性和变化性可能是全球具同时性的松山/布容地磁极性转换在黄土高原不同地区产出层位不一致性的主要原因,而基于Lock-in模型的天文年代标尺则可能高估了黄土/古土壤的年龄.  相似文献   
22.
The stratified water column of the Black Sea is partitioned into oxic, suboxic, and euxinic zones, each characterized by different biogeochemical processes and by distinct microbial communities. In 2003, we collected particulate matter by large volume in situ filtration at the highest resolution to date for lipid biomarker analysis and bacterioplankton for enumeration of major prokaryotic groups. Abundances of several prokaryotic groups were estimated using CARD-FISH probes specific for Bacteria, Archaea (Crenarchaeota and Euryarchaeota), epsilonproteobacteria (mainly sulfide oxidizers) and sulfate reducing bacteria. We also measured a wide range of bacterial and archaeal lipid biomarkers. Depth distributions of diagnostic biomarkers are matched with zonation of microbial processes, including aerobic bacterial oxidation of methane, oxidation of ammonium by bacteria and archaea, metal reduction, and sulfide oxidation at the chemocline, and bacterial sulfate reduction and anaerobic oxidation of methane by archaea in the anoxic zone. Cell densities for archaea and sulfate reducing bacteria are estimated based on water column biomarker concentrations and compared with CARD-FISH results.  相似文献   
23.
The main terminal processes of organic matter mineralization in anoxic Black Sea sediments underlying the sulfidic water column are sulfate reduction in the upper 2-4 m and methanogenesis below the sulfate zone. The modern marine deposits comprise a ca. 1-m-deep layer of coccolith ooze and underlying sapropel, below which sea water ions penetrate deep down into the limnic Pleistocene deposits from >9000 years BP. Sulfate reduction rates have a subsurface maximum at the SO42−-CH4 transition where H2S reaches maximum concentration. Because of an excess of reactive iron in the deep limnic deposits, most of the methane-derived H2S is drawn downward to a sulfidization front where it reacts with Fe(III) and with Fe2+ diffusing up from below. The H2S-Fe2+ transition is marked by a black band of amorphous iron sulfide above which distinct horizons of greigite and pyrite formation occur. The pore water gradients respond dynamically to environmental changes in the Black Sea with relatively short time constants of ca. 500 yr for SO42− and 10 yr for H2S, whereas the FeS in the black band has taken ca. 3000 yr to accumulate. The dual diffusion interfaces of SO42−-CH4 and H2S-Fe2+ cause the trapping of isotopically heavy iron sulfide with δ34S = +15 to +33‰ at the sulfidization front. A diffusion model for sulfur isotopes shows that the SO42− diffusing downward into the SO42−-CH4 transition has an isotopic composition of +19‰, close to the +23‰ of H2S diffusing upward. These isotopic compositions are, however, very different from the porewater SO42− (+43‰) and H2S (−15‰) at the same depth. The model explains how methane-driven sulfate reduction combined with a deep H2S sink leads to isotopically heavy pyrite in a sediment open to diffusion. These results have general implications for the marine sulfur cycle and for the interpretation of sulfur isotopic data in modern sediments and in sedimentary rocks throughout earth’s history.  相似文献   
24.
In this paper, we develop and apply a multi-dimensional vulnerability assessment framework for understanding the impacts of climate change-induced hazards in Sub-Saharan African cities. The research was carried out within the European/African FP7 project CLimate change and Urban Vulnerability in Africa, which investigated climate change-induced risks, assessed vulnerability and proposed policy initiatives in five African cities. Dar es Salaam (Tanzania) was used as a main case with a particular focus on urban flooding. The multi-dimensional assessment covered the physical, institutional, attitudinal and asset factors influencing urban vulnerability. Multiple methods were applied to cover the full range of vulnerabilities and to identify potential response strategies, including: model-based forecasts, spatial analyses, document studies, interviews and stakeholder workshops. We demonstrate the potential of the approach to assessing several dimensions of vulnerability and illustrate the complexity of urban vulnerability at different scales: households (e.g., lacking assets); communities (e.g., situated in low-lying areas, lacking urban services and green areas); and entire cities (e.g., facing encroachment on green and flood-prone land). Scenario modeling suggests that vulnerability will continue to increase strongly due to the expected loss of agricultural land at the urban fringes and loss of green space within the city. However, weak institutional commitment and capacity limit the potential for strategic coordination and action. To better adapt to urban flooding and thereby reduce vulnerability and build resilience, we suggest working across dimensions and scales, integrating climate change issues in city-level plans and strategies and enabling local actions to initiate a ‘learning-by-doing’ process of adaptation.  相似文献   
25.
26.
Field investigations were carried out to determine the occurrence of tetrachloroethene (PCE) dense nonaqueous phase liquid (DNAPL), the source zone architecture and the aquitard integrity at a 30‐ to 50‐year old DNAPL release site. The DNAPL source zone is located in the clay till unit overlying a limestone aquifer. The DNAPL source zone architecture was investigated through a multiple‐lines‐of‐evidence approach using various characterization tools; the most favorable combination of tools for the DNAPL characterization was geophysical investigations, membrane interface probe, core subsampling with quantification of chlorinated solvents, hydrophobic dye test with Sudan IV, and Flexible Liner Underground Technologies (FLUTe) NAPL liners with activated carbon felt (FACT). While the occurrence of DNAPL was best determined by quantification of chlorinated solvents in soil samples supported by the hydrophobic dye tests (Sudan IV and NAPL FLUTe), the conceptual understanding of source zone architecture was greatly assisted by the indirect continuous characterization tools. Although mobile or high residual DNAPL (S t > 1%) only occurred in 11% of the source zone samples (intact cores), they comprised 86% of the total PCE mass. The dataset, and associated data analysis, supported vertical migration of DNAPL through fractures in the upper part of the clay till, horizontal migration along high permeability features around the redox boundary in the clay till, and to some extent vertical migration through the fractures in the reduced part of the clay till aquitard to the underlying limestone aquifer. The aquitard integrity to DNAPL migration was found to be compromised at a thickness of reduced clay till of less than 2 m.  相似文献   
27.
Groundwater models simulating flow in buried valleys interacting with regional aquifers are often based on hydrogeological models interpreted from dense geophysical datasets and scarce borehole data. For three simple synthetic cases, it is demonstrated that alternative methods of inversion of transient electro-magnetic (TEM) data can lead to very different interpretations of the hydrogeology inside and surrounding a buried valley. The alternative interpreted hydrogeological models are used in numerical modelling of groundwater flow to a pumping well. It is demonstrated that the alternative models result in quite different groundwater-model predictions of capture zone, recharge area, and groundwater age for the pumping well. It is briefly demonstrated that model calibration against hydraulic head data is not likely to improve the predictions or to identify the structural error of the interpreted hydrogeological models. It is therefore concluded that when TEM-based resistivity models are interpreted to construct the hydrogeological framework of a groundwater model, it must be done cautiously with support from deep borehole information. Too much reliance on geophysical mapping can lead to seriously wrong hydrogeological models and correspondingly wrong groundwater-model predictions.  相似文献   
28.
Airborne electromagnetics (AEMs) is increasingly being used across the globe as a tool for groundwater and environmental management. Focus is on ensuring the quality of the source data, their processing and modeling, and the integration of results with ancillary information to generate accurate and relevant products. Accurate processing and editing of raw AEM data, the topic of this article, is one of the crucial steps in obtaining quantitative information for groundwater modeling and management. In this article, we examine the consequences that different levels of processing of helicopter transient electromagnetic method data have on the resulting electrical models and subsequently on hydrogeological models. We focus on different approaches used in the industry for processing of the raw data and show how the electrical resistivity–depth models, which is the end “geophysical” product (after data inversion) of an AEM survey, change with different levels of processing of the raw data. We then extend the study to show the impact on some of the hydrogeological parameters or models, which can be derived from the geophysical results. The consequences of improper handling of raw data to groundwater and environmental management can be significant and expensive.  相似文献   
29.
Following the first International Conference on Gas in Marine Sediments in Edinburgh, UK (1990), another eight successful conferences have provided a continuous forum for scientists from a variety of disciplines, organisations and countries. The 9th meeting of the Shallow Gas Group was held in September 2008 in Bremen, a hanseatic city more than 1,200 years old in northern Germany. The Shallow Gas Group was joined for this conference by participants of the HERMES EU-funded project and by members of an industry-funded project. Volume 30 (3/4) of Geo-Marine Letters is a double issue containing 25 selected papers from the 9th conference in Bremen, guest edited by G. Bohrmann and B.B. Jørgensen. The papers represent the broad spectrum of oral and poster contributions from the conference, covering a wide range of aspects of gas in marine sediments from many parts of the world. The next conference of the Shallow Gas Group is planned to be held in Listvyanka at Lake Baikal, Russia, in September 2010.  相似文献   
30.
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