珊瑚的高精度热电离质谱定年和Sr/Ca温度计对古环境研究意义     

王兆荣  彭子成  倪守斌  马志邦 《海洋地质与第四纪地质》1999,19(4)

珊瑚等海底沉积物中留下了过去气候变化的高分辨率记录,利用高分辨中的取样方法和热电离质谱（TIMS）铀系法对其进行测年,可以提取很短时间间隔内的环境参数,进一步证实了海洋珊瑚骨骼的Sr／Ca与海水温度间有很好的相关关系,是恢复古环境的一个有效方法。  相似文献   

北京猿人洞穴堆积气候地层的重新划分与对比     

刘泽纯  周春林  陈晔 《地层学杂志》2003,27(1):26-32

周口店第一地点洞穴四十余米厚的堆积层自下而上共分为 17层 ,新近测量的年代推前了近 2 0 0 ka。对堆积层所含哺乳动物化石和孢粉资料进行聚类统计和因子分析 ,结合风化系数和微量元素含量等古气候代用指标 ,重新定量地描绘它所记录的古气候波动旋回。根据第 2层 TIMS测年为 410 ka B.P.,第 14层上部是磁性地层测量的B/ M界线 ,可以将该洞穴堆积层 1— 14层对比于深海岩心 δ1 8O气候曲线的 11— 19段或中国黄土—古土壤序列S4— S7,并且古气候旋回内的次级波动也可进行一定程度的对比。  相似文献   

天山中西段古生代花岗岩TIMS法锆石U-Pb同位素定年及岩石地球化学特征研究   总被引：23，自引：0，他引：23  

徐学义  马中平  夏祖春  夏林圻  李向民  王立社 《西北地质》2006,39(1):50-75

通过对天山中西段古生代花岗岩的锆石TIMS法U-Pb同位素定年,表明中天山托克逊南—库米什北侵入于奥陶纪可可乃克群中的碱长花岗岩形成时代为395.1±0.9Ma,花岗闪长岩体形成于393.5±2.7Ma,石英闪长岩体形成于327.3±0.9Ma,斜长花岗岩体形成时代为424.1±1.1Ma,并揭示出中天山中段库米什地区的3期构造岩浆事件,分别相当于早志留世、中泥盆世和早石炭世。中天山哈希勒根大坂黑云母花岗岩形成于286.8±0.8Ma。对伊犁石炭—二叠纪裂谷带中花岗侵入岩类的锆石TIMS法U-Pb同位素定年,表明霍城果子沟角闪花岗岩形成于351.9±1.6Ma,昭苏煤矿花岗闪长岩体形成时代为348.4±0.8Ma,新源则克台角闪辉长岩体形成于308.2±1.2Ma。南天山巴音布鲁克地区侵入于巴音布鲁克群中的石英闪长岩体形成时代为446.8±1.2Ma,独—库公路南段库尔干道班14.6km和15.2km处的角闪斜长花岗岩体与黑云母花岗岩体分别形成于426.3±1.9Ma和425.1±1.8Ma。对花岗岩的岩石地球化学研究表明,中天山托克逊南—库米什北志留纪—早泥盆世花岗岩为钙碱系列,轻稀土富集,微量元素洋脊花岗岩标准化具有Rb、Th、Ba富集,Ta、Nb亏损的分配型式,形成于火山弧环境;石炭—二叠纪花岗岩为钙碱系列,准铝—过铝质花岗岩,轻稀土富集程度较前者低,微量元素洋脊花岗岩标准化具有Rb、Th富集,Ba略亏损和高场强元素亏损的特点,形成于后碰撞(post-collision)构造环境。伊犁石炭—二叠纪裂谷带中石炭—二叠纪花岗岩为过铝质花岗岩,轻稀土富集,微量元素洋脊花岗岩标准化分配型式同样具有Rb、Th富集,Ba明显亏损和高场强元素亏损的特点,亦形成于后碰撞(post-collision)构造环境。南天山库尔干花岗岩为Al2O3含量高的钙碱性系列、过铝质花岗岩,稀土元素含量中等(157.89×10-6~81.81×10-6),轻稀土富集,Eu负异常明显,微量元素洋脊花岗岩标准化呈现出K、Rb、Th、Ba富集和Nb、Ta、Zr、Hf高场强元素亏损的特点,其形成时代与天山古生代洋盆俯冲时限相当,为岛弧构造环境。依据Sr-Nd-Pb同位素回时计算结果,本次研究所取的花岗岩初始锶同位素比值高,介于0.70435~0.70982,εNd(t)值多小于零或为很低的正值,T2DM或TDM均远大于岩体形成年龄,δ18O‰多大于10,个别为6.7,显示出古老壳源物质在花岗岩浆的形成过程中起了重要作用。同时,鉴于花岗岩的εNd(t)均在0左右变动,同样说明,新生地壳在花岗岩浆的形成过程中同样起着重要作用。花岗岩的εNd(t)值与前寒武纪岩石的εNd(t)对比研究表明,中天山库米什北志留纪斜长花岗岩体可能是中新元古界斜长角闪岩部分熔融的产物,而石炭—二叠纪花岗岩既有中新元古界片麻岩或片岩部分熔融生成,亦有新生地壳部分熔融受到古老地壳混染后岩浆结晶产物。伊犁石炭—二叠纪花岗岩和南天山库尔干志留纪花岗岩均显示出新生地壳部分熔融,并受古老地壳混染的Nd同位素信息。  相似文献   

岩石样品中低含量铂族元素和锇同位素比值的高精度测量方法   总被引：9，自引：1，他引：9  

杨竞红  GerharBRUGMANN 《岩石学报》2001,17(2):325-331

铂族元素（Os,Ir,Pt,Ru,Rh,Pd)具有强亲铁性和强亲铜性，为一组地球化学性质相近的相容元素，铂族元素包含两个同位素衰变体系（^190Pt-^186Os和^187Re-^187Os)。近年来，铂族元素和Re-Os同位素在研究各类不同地持作用过程中，尤其是在地幔岩石的研究中，作用独特，效果显著。由于地幔岩石的铂族元素含量较低，因此高精度，高灵敏度的分析测试方法的研究就显得十分重要。以往的分析方法（如常规的ICP－MS和中子活化分析方法），对含10^-9-10^012级低含量铂族元素的产品分析精度一般较差（＞15％－100％）。所采用的分析流程通常也无法同时获得样品的铂族元素含量和Os同位素比值。本文采用新的熔样方法（HAP－S高温高压釜酸溶法），新的化学流程（溶剂萃取和阴离子交换树脂柱）和新的分析仪器（多接收等离子体质谱MC－ICPMS和负离子热电离质谱N－TIMS）。用同位素稀释法对低含量地幔橄榄岩样品同时测定的铂族元素含量和Os同位素比值，获得了高精度的分析结果。对所分析的地橄榄样品中的铂族元素分配曲线和Os同位素组成的地质意义进行了初步探讨。  相似文献   

南京汤山洞穴石笋稳定同位素指示的气候与环境意义   总被引：16，自引：1，他引：15  

汪永进  许汉奎 《地质学报》2000,74(4):333-338

对南京汤山葫芦洞南壁钙板上一支长８２ｍｍ石笋进行了高精度热电离质谱（ＴＩＭＳ）定年及氧碳同位素分析。结果表明,该支短石笋生长时段长达３００ｋａ左或（距今４６３～１５９ｋａ）,其底部年龄进一步证实南京直立人生存时代早于４５０ｋａＢＰ。δ＾１３Ｃ值在ＭＩＳ６／７界线上的显著漂移揭示了一次土壤侵蚀事件,结束了洞穴文化层的堆积历史。  相似文献   

Activity of Changbaishan Tianchi Volcano Since Late Pleistocene--The Constrain From Geochronology of High Precision U- Series Tims Method     

Wang Fei  Chen Wenji  Zhang Zhonglu  Hu Yutai  Peng Zicheng 《世界地质(英文版)》2000,3(1)

11 samples of lava and pumice from the cone of Changbaishan Tianchi Volcano, Jiling, China, were dated by using high precision U - series TIMS method. We conclude that the bottom of the cone formed before 350 ka, the middle part in 70～80 ka, the upper during 20～ 1ka, and the top less than 1ka, and the age based periods of the volcano eruption since Late Pleistocene is given as follows: ＞ 350ka, 70ka, 18 ～ 25ka, 10ka, 4C5ka, 1～0.75ka, which may offer the basis for the study of volcanic disaster in future. In addition, the principle of dating young volcanic rocks by using U - series TIMS method is introduced briefly. Differentiation characteristics of U and Th in different minerals of the volcanic rocks are discussed, and the ability producing isochrons, based on U and Th differentiation, are discussed. In the last part of the paper,the closure of samples to the elements U and Th, which is important for age results, is discussed by using (234U/238U)radioactivity ratio which can be used to monitor if the samples have been weathered or eroded or leached since the time they formed. In this study, all samples have (234U/238U) activity ratios within 1% of secular equilibrium ((234U/238U) radioactivity ratios are unity), indicating no disturbance of the 234U- 238U system. All of these discussions show that the TIMS method is good to date Tianchi volcanics and the results are reliable.  相似文献   

热电离质谱铀系法测定碳酸盐标样   总被引：5，自引：0，他引：5  

王兆荣  彭子成 《岩矿测试》1998,17(4):268-270

用高精度热电离质谱（ＴＩＭＳ）铀系法测定碳酸盐标样的年龄,测定结果与α谱仪铀系法进行比较,铀含量和年龄值均吻合。方法对Ｕ的回收率可达９５％,Ｔｈ为９２％。ＴＩＭＳ铀系法具有样品用量少、测试时间短、精度高的优点。  相似文献   

微量岩石样品中Rb-Sr和Pb一步分离及高精度热电离质谱测试   总被引：3，自引：0，他引：3  

李潮峰  李献华  郭敬辉  李向辉  李怀坤  周红英  李国占 《地球化学》2011,(5):399-406

采用30 μL Sr特效树脂微柱,一步分离微量岩石样品中Rb-Sr和Pb,其回收率均优于90％,流程试剂用量仅0.75 mL,分离时间约3h,Rb-Sr流程本底优于5 pg,Pb流程本底优于50 pg.本方法具有样品用量少、本底低、回收率高、分离效率高等优点.结合高灵敏度TIMS分析技术,可以实现微量岩石样品高精度Rb...  相似文献   

Uranium series dates from the windy pits of the North York Moors,United Kingdom: implications for late Quaternary ice cover and timing of speleogenesis     

P. J. Murphy  J. Lundberg 《地球表面变化过程与地形》2009,34(2):305-313

Windy pits are open fissures within the Corallian strata of the North York Moors. Here we present nine thermal ionization mass spectrometry (TIMS) U–Th dates on speleothem from the windy pits, the first radiometric dates on calcite for these features and for this region. The dates cluster within three time periods: the interglacial peaks of marine isotope stage (MIS) 7 (～208 to ～190 ka), MIS 5 (～127 ka to ～109 ka) and the Holocene, correlating with the marine isotope record and with the broad pattern of interglacial calcite deposition observed for northern England. However, of the two high‐resolution studies available for comparison, the windy‐pit dates match only the Lancaster Hole dates. The location of the windy pits outside of the Devensian ice limits, within the ice‐free but periglaciated region, suggests that the region has remained ice‐free since some time before MIS 7. The prevalence of widespread and prolonged permafrost conditions suggests a plausible mechanism for these open rift caves in slope‐side periglacial mass movement. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

High‐Precision Sr‐Nd‐Hf‐Pb Isotopic Composition of Chinese Geological Standard Glass Reference Materials CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 by MC‐ICP‐MS and TIMS     

Yue‐Heng Yang  Ming Yang  Klaus Peter Jochum  Shi‐Tou Wu  Han Zhao  Lie‐Wen Xie  Chao Huang  Xiu‐Chun Zhan  Jin‐Hui Yang  Fu‐Yuan Wu 《Geostandards and Geoanalytical Research》2020,44(3):567-579

To assess the homogeneity of and provide the first Sr‐Nd‐Hf‐Pb isotopic reference values for the Chinese Geological Standard Glasses CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5, we measured these isotopes in several measurement sessions over the course of nearly 3 years. The results were obtained by high‐precision MC‐ICP‐MS and TIMS. Our investigation indicates that these CGSG glass reference materials are homogenous with regard to Sr‐Nd‐Hf‐Pb isotopic distribution and are therefore suitable geochemical materials for Sr‐Nd‐Hf‐Pb isotope measurements. Clear differences in Sr‐Nd‐Hf‐Pb isotopic composition were observed between the glasses and the original powdered rock reference materials (CGSG‐2 and GSR‐7, and especially CGSG‐5 and GSR‐2) because of flux addition during preparation of the glasses. The new Sr‐Nd‐Hf‐Pb isotope data provided here might be useful to the geochemical community for in situ and bulk analysis.  相似文献