Determination of Platinum‐Group Elements and Re‐Os Isotopes using ID‐ICP‐MS and N‐TIMS from a Single Digestion after Two‐Stage Column Separation     

Jie Li  Xiao‐Ying Jiang  Ji‐Feng Xu  Li‐Feng Zhong  Xuan‐Ce Wang  Gui‐Qin Wang  Pei‐Pei Zhao 《Geostandards and Geoanalytical Research》2014,38(1):37-50

We report an improved procedure for the determination of the platinum‐group elements (PGE) and Re, and Os isotopes from a single sample aliquot by isotope dilution (ID) using inductively coupled plasma‐mass spectrometry (ICP‐MS) and negative thermal ionisation mass spectrometry (N‐TIMS), respectively. A two‐stage column method was used to purify PGE‐Re from their sample matrix and interfering elements (e.g., Mo, Zr and Hf) after Os had been separated by CCl₄ solvent extraction. The first column separation step used cation exchange resin (AG50W‐X8) to concentrate PGE‐Re and some potential interfering elements (e.g., Mo, Zr and Hf). In the second step, N‐benzoyl‐N‐phenylhydroxylamine (BPHA) extraction resin was used to separate PGE‐Re from the remaining interfering elements, which all remained strongly absorbed to the resin. The method was used to determine the PGE and rhenium, and Os isotope ratios in a range of geochemical reference materials (TDB‐1, WGB‐1, BHVO‐2 and UB‐N). The obtained results agree well with those previously published. This new method enables PGE‐Re abundances and Os isotopic ratios to be determined on the same sample digestion, and circumvents the problems created by sample heterogeneity when comparing PGE and Re‐Os isotope data.  相似文献   

Determination of Lithium Contents in Silicates by Isotope Dilution ICP-MS and its Evaluation by Isotope Dilution Thermal Ionisation Mass Spectrometry   总被引：2，自引：0，他引：2  

Takuya Moriguti  Akio Makishima  Eizo Nakamura 《Geostandards and Geoanalytical Research》2004,28(3):371-382

A precise and simple method for the determination of lithium concentrations in small amounts of silicate sample was developed by applying isotope dilution-inductively coupled plasma-mass spectrometry (ID-ICP-MS). Samples plus a Li spike were digested with HF-HClO₄, dried and diluted with HNO₃, and measured by ICP-MS. No matrix effects were observed for ⁷Li/⁶Li in rock solutions with a dilution factor (DF) of 97 at an ICP power of 1.7 kW. By this method, the determination of 0.5 μg g^-1 Li in a silicate sample of 1 mg can be made with a blank correction of < 1%. Lithium contents of ultrabasic to acidic silicate reference materials (JP-1, JB-2, JB-3, JA-1, JA-2, JA-3, JR-1 and JR-2 from the Geological Survey of Japan, and PCC-1 from the US Geological Survey) and chondrites (three different Allende and one Murchison sample) of 8 to 81 mg were determined. The relative standard deviation (RSD) was typically < 1.7%. Lithium contents of these samples were further determined by isotope dilution-thermal ionisation mass spectrometry (ID-TIMS). The relative differences between ID-ICP-MS and ID-TIMS were typically < 2%, indicating the high accuracy of ID-ICP-MS developed in this study.  相似文献   

Continental Oxygen Isotopic Record of the Last 170,000 Years in Jerusalem   总被引：1，自引：0，他引：1  

Amos Frumkin  Derek C. Ford  Henry P. Schwarcz 《Quaternary Research》1999,51(3):317

A long radiometrically dated oxygen isotopic record of continental climatic variations since the penultimate glaciation was obtained from a stalagmite deposited in a sealed cave in Jerusalem. This record shows that speleothems have the potential of assigning dates to long- and short-term climatic events, with possible refining of Milankovitch tuning of ice and marine records which themselves are not datable. Short-term (1000-yr) events are very significant in the region, reaching 50% of glacial/interglacial fluctuations. The Mediterranean Sea was the most probable source of local precipitation throughout the last glacial cycle.  相似文献   

南京直立人生存的年代及气候地层对比   总被引：2，自引：0，他引：2  

周春林  刘泽纯  陈晔  汪永进 《地层学杂志》1999,23(3):196-200

1 朱梅.葡萄酒.北京:轻工业出版社,1954 2 尹克林,梁武,诸葛宏庆.酿酒葡萄品种“蛇龙珠”的叶形结构数值鉴别.园艺学报,1998,25(2  相似文献   

Barbados岛珊瑚礁高精度铀系年龄及讨论   总被引：3，自引：0，他引：3       下载免费PDF全文

马志邦  王兆荣 《地质科学》1999,34(1):116-122

应用同位素稀释法热电离质谱(TIMS)技术测定珊瑚礁的高精度铀系年龄。通过对BarbadosⅢ、Ⅳ阶地等样品分析,RendezvousHil和Curacao+6m的TIMS年龄分别为129.2±1.2kaB.P.和125.4±1.1kaB.P.,对应深海沉积物氧同位素第5期5e段的高海面;Kendal山阶地为208.1±1.9kaB.P.,可能代表7c间冰期高海平面的时代。该结果与Edwards等测定同一阶地的年龄一致,与α谱法数据在误差范围内吻合。另外,探讨了初始铀同位素比值的变化,并对TIMS年龄的可靠性做了评价。  相似文献   

GGR Critical Review of Analytical Developments in 2006–2007     

Janet M. Hergt  L. Paul Bédard  Stefanie M. Brueckner  Klaus Peter Jochum  Kathryn L. Linge  Paul J. Sylvester  Michael Wiedenbeck  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2008,32(4):397-398

In 2005 the Geostandards and Geoanalytical Research editorial team, in the true spirit of scientific endeavour, embarked on an experiment of our own. We decided to trial a new kind of review, somewhat different from those more typically observed in journals, and one that would provide readers with a summary of analytical developments across a broad range of topics appropriate to the Earth sciences. The first contribution of this kind appeared in 2005, and reported on developments in 2003 (Hergt et al. 2005). The second, this time a biennial review, was published in 2006 and reported on highlights of the 2004 and 2005 literature (Hergt et al. 2006). Based on reprint requests, positive remarks at conferences and strong citations we consider the experiment a resounding success and proudly present here the third in this series. This comprises six individual review sections that cover the main analytical technologies and topical application fields in geoanalysis and geochemistry, including geological and environmental reference materials, ICP‐thermal and secondary ionisation‐mass spectrometry, as well as neutron activation analysis, X‐ray fluorescence and atomic absorption spectrometry.  相似文献   

永暑礁西南礁镯生物地貌与沉积环境   总被引：4，自引：2，他引：4  

余克服  赵建新  施祺  钟晋梁  陈特固 《海洋地质与第四纪地质》2003,23(4):1-7

在海上系统调查的基础上提出南沙群岛永暑礁西南部礁镯并非传统的开放型环礁,而是一个封闭型的小环礁,封闭的泻湖能够为高分辨率古环境重建提供原生生物沉积。该小环礁可分为礁前斜坡活珊瑚林带、外礁坪珊瑚生长带、礁突起珊瑚枝块胶结堆积带、内礁坪枝状珊瑚生长-砂质沉积交互带、泻湖坡枝状珊瑚生长-细砂沉积带和泻湖盆底粉砂质生物沉积带共6个生物地貌和沉积带。12个礁坪原生滨珊瑚和2个礁岩滨珊瑚的^14C和TIMS U-Th测年结果表明永暑礁礁坪面形成于近代,它们没有提供中全新世高海平面的证据,约950aBP的中世纪暖期南沙群岛可能有过非常强的风暴潮。此外,1000年以内的珊瑚常规^14C未校正年代与TIMS U-Th年代存在显著差异,在环境解释中需要特别小心。  相似文献   

Barium Isotopic Compositions of Geological Reference Materials          下载免费PDF全文

Kirsten van Zuilen  Thomas F. Nägler  Thomas D. Bullen 《Geostandards and Geoanalytical Research》2016,40(4):543-558

The interest in variations of barium (Ba) stable isotope amount ratios in low and high temperature environments has increased over the past several years. Characterisation of Ba isotope ratios of widely available reference materials is now required to validate analytical procedures and to allow comparison of data obtained by different laboratories. We present new Ba isotope amount ratio data for twelve geological reference materials with silicate (AGV‐1, G‐2, BHVO‐1, QLO‐1, BIR‐1, JG‐1a, JB‐1a, JR‐1 and JA‐1), carbonate (IAEA‐CO‐9) and sulfate matrices (IAEA‐SO‐5 and IAEA‐SO‐6) relative to NIST SRM 3104a. In addition, two artificially fractionated in‐house reference materials BaBe12 and BaBe27 (δ^137/134Ba = ?1.161 ± 0.049‰ and ?0.616 ± 0.050‰, respectively) are used as quality control solutions for the negative δ‐range. Accuracy of our data was assessed by interlaboratory comparison between the University of Bern and the United States Geological Survey (USGS). Data were measured by MC‐ICP‐MS (Bern) and TIMS (USGS) using two different double spikes for mass bias correction (¹³⁰Ba–¹³⁵Ba and ¹³²Ba–¹³⁶Ba, respectively). MC‐ICP‐MS measurements were further tested for isobaric and non‐spectral matrix effects by a number of common matrix elements. The results are in excellent agreement and suggest data accuracy.  相似文献   

内蒙古阿拉善左旗巴音诺尔公花岗岩体TIMS锆石U-Pb年龄   总被引：1，自引：1，他引：0  

党智财  李俊建  赵泽霖  付超  唐文龙  王守光  赵丽君  刘晓雪 《地质通报》2016,35(4):593-598

内蒙古自治区阿拉善东南部的巴音诺尔公花岗岩体,地处华北陆块西北缘,霍尔森-查干楚鲁构造带以南的雅布赖-巴音诺尔公构造带内。岩体整体上受NEE向构造控制,主要由中-细粒黑云母花岗岩和中-粗粒似斑状黑云母花岗岩2种岩石类型组成。采用TIMS锆石U-Pb定年法,测得巴音诺尔公岩体不同位置中-细粒黑云母花岗岩和中-粗粒似斑状黑云母花岗岩样品年龄分别为304.7±2.8Ma和289.0±3.8Ma,属于晚石炭世—早二叠世。结合前人资料,提出巴音诺尔公岩体至少存在2期岩浆活动,分别为晚石炭世(304Ma)和早二叠世(289~272Ma)。  相似文献   

内蒙古阿拉善地区沙拉扎山花岗岩体TIMS锆石U-Pb年龄   总被引：1，自引：0，他引：1  

赵泽霖  李俊建  党智财  唐文龙  付超  王守光  刘利双  赵丽君  刘晓雪 《地质通报》2016,35(4):599-604

内蒙古阿拉善地区的沙拉扎山处于华北板块、塔里木板块和天山-兴蒙造山带接触部位,恩格尔乌苏蛇绿岩带与查干础鲁蛇绿岩带之间。沙拉扎山内出露一套巨大花岗质岩基,为了认识其岩浆活动期次,对沙拉扎山岩体不同部位花岗质岩石样品进行了TIMS锆石U-Pb测年。结果表明,沙拉套尔汗花岗闪长岩年龄为233.1±5.8Ma,乌力吉花岗岩2个样品年龄分别为228.1±0.4Ma和207.7±0.8Ma。对比分析前人对该区岩体年龄的研究成果,认为沙拉扎山出露的花岗岩由早二叠世晚期(273~274Ma)、早三叠世(248~252Ma)、晚三叠世早期(228~236Ma)和晚三叠世末期(207Ma)4期岩浆活动叠加而成,同时发育在沙拉扎山的4期岩浆活动在巴音—诺尔公地区也有相应的岩浆记录。  相似文献