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A new simple, rapid, selective and sensitive analytical procedure based on chemiluminescence (CL) detection is described for the determination of vanadium (V) at sub-nanogram levels in natural waters by use of controlled-reagent- release technology in a flow injection system. The analytical reagents involved in the CL reaction, including luminal and periodate, were both immobilized on anion-exchange resins in a flow injection system. Through water injection, luminol and periodate were eluted from the anion exchange column to generate the chemiluminescence, which was enhanced in the presence of V(V). The increased CL intensity was linear with V(V) concentration in the range from 0.2 to 100 ng mL− 1. The limit of detection was 60 pg mL− 1 (3σ) and the relative standard deviation (RSD) was 1.45% (n = 5) for a 0.5 ng mL− 1 V(V). At a flow rate of 2.0 mL min− 1, including sampling and washing, a typical analytical procedure could be performed in 0.5 min with a RSD of less than 3.0%. The proposed method was successfully applied to determine vanadium in natural waters, and the results were in good agreement with those obtained by ion chromatography. 相似文献
22.
我国不同自然条件下的水域气候效应 总被引：15，自引：1，他引：15
本文根据我国分布在全国各地的２６个湖泊、水库和河流的实际观测资料，结合理论分析，探讨了在不同自然条件下各各水域气候效应的特点和规律，并给出了其对温度、湿度、风速和降水正负影响的大致数值范围。 相似文献
23.
At Segura, granitic pegmatite veins with cassiterite and lepidolite, hydrothermal Sn–W quartz veins and Ba–Pb–Zn quartz veins intruded the Cambrian schist–metagraywacke complex and Hercynian granites. Cassiterite from Sn–W quartz veins is richer in Ti and poorer in Nb and Nb+Ta than cassiterite from granitic pegmatite. Wolframite from Sn–W quartz veins is enriched in ferberite component. The Sn–W quartz veins contain pyrrhotite, arsenopyrite, sphalerite, chalcopyrite, stannite, matildite and schapbachite and the Ba–Pb–Zn quartz veins have cobaltite, pyrite, sphalerite, chalcopyrite, galena and barite, which were analyzed by electron microprobe. The presently abandoned mining area was exploited for Sn, W, Ba and Pb until 1953. Stream sediments and soils have higher concentrations of metals than parent granites and schists. Sn, W, B, As and Cu anomalies found in stream sediments and soils are associated with Sn–W quartz veins, while Ba, Pb and Zn anomalies in stream sediments and soils are related to Ba–Pb–Zn quartz veins. Sn, W, B, As, Cu, Ba, Pb and Zn anomalies in stream sediments and soils are also related to the respective old mining activities, which increased the mobility of trace metals from mineralized veins to soils, stream sediments and waters. Stream sediments and soils are sinks of trace elements, which depend on their contents in mineralized veins and weathering processes, but Sn, W and B depend mainly on a mechanic process. Soils must not be used for agriculture and human residence due to their Sn, B, As and Ba contents. Waters associated with mineralized veins were analyzed by flame atomic absorption spectroscopy (FAAS) and ICP-AES have high As, Fe and Mn and should not be used for human consumption and agriculture activities. The highest As values in waters were all related to Sn–W quartz veins and the highest Fe and Mn values were associated with the Ba–Pb–Zn quartz veins. No significant acid drainage was found associated with the old mine workings. 相似文献
24.
A. Chovanec 《洁净——土壤、空气、水》1997,25(5):233-241
Pesticides in Austrian Running Waters – a Country-wide Overview The analyses of pesticides in Austrian running waters are major part of the country-wide water quality monitoring system which has been established in 1991. This paper summarizes the data which were collected for 29 substances between December 1991 and June 1995. The monitoring activities focus on herbicides because they are the most important pesticide group in Austria. Substances of the triazines and phenoxyalkanecarboxylic acid group analyzed within the programme represent the major part of the total amount of herbicides applied. The most detected pesticides were atrazine and its metabolite deethylatrazine. Peak concentrations were obtained in rivers situated in the eastern and southern regions of Austria with intensive agriculture. Other substances play a minor role as contaminants in running waters. These findings correspond to the data obtained by investigations of groundwater in porous media. 相似文献
25.
Determination of a Group Parameter for Organic Halogen Compounds in High Salt-laden Water Samples Using XAD-4 Resin Concerning the often discussed ‘chloride error’ in AOX determination, a method is described with allows the determination of the group parameter organic halogen compounds (OX) for chloride concentrations more than 1 g/L. In opposite to the standard method DIN 38409 part 14, no chloride influence up to a concentration of 10 g/L in real water samples occurs. The basis of the method is the adsorption of the organic compounds from the water sample on XAD-4 resin, a nonpolar copolymer of styrene and divinylbenzene. The organic compounds are concentrated on the XAD-4 resin conditioned with methanol. After the enrichment step, the adsorption columns are treated with sodium nitrate solution. Model experiments with p-chlorophenol and chloride concentrations of 50 g/L showed the effectiveness of this method. The loaded and washed adsorption columns are first eluated with acetone and then with ethyl acetate. Quantification of the OX compounds in the eluates is carried out by microcoulometric detection after combustion in a furnace equipped with a special injector for eluates. For optimal work, the instrument was modified and improved. The presented method was developed on model samples and tested on different real samples. 相似文献
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本文介绍了我们改装的一台浅海海洋质子磁力仪,它不仅能用于深水海区,而且可以用于浅水的近岸浅海区的海洋磁力测量。对于近岸浅水工程,石油开发和地质等提供了有利的手段。 相似文献
28.
南沙海域天然气水合物地震特征 总被引：5，自引：1，他引：5
南沙海域水深为200∽2500m，其中大于500m的水域约50万km^2，该区大部分区域发育沉积盆地，构造类型多样，具有形成天然气水合物的气源、温度及压力条件。根据地质及地球物理调查资料，分析了南沙海域天然气水合物成藏的地质条件及地球物理标志特征，认为南沙海域具备形成天然气水合物矿藏的条件，南沙海槽和南沙中部海域是天然气水合物形成的有利地区。 相似文献
29.
Essyllt Louarn Pascal Morin 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(9):932-942
This study of the mixing of Mediterranean Sea Water (MW) with the surrounding waters was made possible by the Semane 2002 cruise (Sortie des Eaux Meditérranéennes dans l'Atlantique Nord-Est) that took place in the Gulf of Cadiz in July 2002. Potential temperature, salinity, oxygen, nutrients and CFC data are used to describe the water masses present in the Gulf. In the southern part of the basin, a water mass characterised by low oxygen, high nutrient and low CFC concentrations occurs along the African continental slope. This water has been identified as the modified Antarctic Intermediate Water (AAIW). It has been previously observed south of this section, at the latitude of the Canary Islands, as a northward flow between the African shelf and the islands. The modified AAIW found in the Gulf of Cadiz is situated at a density of 27.5 kg m−3. Above, at 27.3 kg m−3, the lower limb of the North Atlantic Central Water is observed as a salinity minimum. The modified AAIW enters the Gulf of Cadiz along the south-western part of the continental shelf. It flows cyclonically and exits north-westward. In the northern part of the gulf, due to the presence of the Mediterranean Undercurrent (MU), the AAIW flows off the coast. An optimum multiparameter analysis was conducted to evaluate the influence of the AAIW on the MW northwest of the basin. We show that the AAIW is present in the lower core of the MU at a proportion of 12.9±8.2% and is absent in the upper core. 相似文献
30.
洋山港海域水体和悬沙输运机制研究 总被引：2，自引：0，他引：2
对洋山港海域水体和悬沙长期输运速度分离,并进行机制分解,分析各种物理过程对水体和悬沙长期输运速度所起的作用.结果表明,水体和悬沙输运存在明显差异,直接描述悬沙净输运更准确合理;欧拉余流在水体长期输运中占主导地位,平流输运和潮泵输运是洋山港海域悬沙输运的主要动力因素,由于潮动力混合较强,垂向输运作用很小. 相似文献