Metal-residence sites in lavas and tuffs from Volcán Popocatépetl, Mexico: implications for metal mobility in the environment     

A. C. L. Larocque  James A. Stimac  Claus Siebe 《Environmental Geology》1998,33(2-3):197-208

 Volcan Popocatépetl is a Quaternary stratovolcano located 60 km southeast of Mexico City. The summit crater is the site of recent ash eruptions, excess degassing, and dacite dome growth. The modern cone comprises mainly pyroclastic flow deposits, airfall tephras, debris flows, and reworked deposits of andesitic composition; it is flanked by more mafic monogenetic vents. In least-degassed fallout tuffs and mafic scoria, transition metals are concentrated in phases formed before eruption, during eruption, and after eruption. Preeruptive minerals occur in both lavas and tephra, and include oxides and sulfides in glass and phenocrysts. The magmatic oxides consist of magnetite, ilmenite, and chromite; the sulfides consist of both (Fe,Ni)_1-xS (MSS) and Cu–Fe sulfide (ISS). Syn- and posteruptive phases occur in vesicles in both lavas and tephra, and on surfaces of ash and along fractures. The mineral assemblages in lavas include Cu–Fe sulfide and Fe–Ti oxide in vesicles, and Fe sulfide and Cu–Fe sulfide in segregation vesicles. Assemblages in vesicles in scoria include Fe–Ti oxide and rare Fe–Cu–Sn sulfide. Vesicle fillings of Fe–Ti oxide, Ni-rich chromite, Fe sulfide, Cu sulfide, and barite are common to two pumice samples. The most coarse-grained of the vesicle fillings are Cu–Fe sulfide and Cu sulfide, which are as large as 50 μ in diameter. The youngest Plinian pumice also contains Zn(Fe) sulfide, as well as rare Ag–Cu sulfide, Ag–Fe sulfide, Ag bromide, Ag chloride, and Au–Cu telluride. The assemblage is similar to those typically observed in high-sulfidation epithermal mineralization. The fine-grained nature and abundance of syn- and/or posteruptive phases in porous rocks makes metals susceptible to mobilization by percolating fluids. The abundance of metal compounds in vesicles indicates that volatile exsolution prior to and/or during eruption played an important role in releasing metals to the atmosphere. Received: March 1997 · Accepted: 27 May 1997  相似文献   

Tankering strategies for evading emissions trading in aviation     

MARTIN CAMES 《Climate Policy》2013,13(2):104-120

Which actors in the aviation sector ought to be obliged to participate in emissions trading? The European Commission opted for the aircraft operator in their proposal for a Directive. A major drawback is that non-EU aircraft operators might legally challenge their inclusion in this scheme and, if the challenge was successful, discrimination between EU and non- EU operators would undermine the scheme. An alternative would be to place an obligation on fuel suppliers to prove possession of allowances, thus avoiding discrimination. However, emissions trading can be evaded to some extent by increased refuelling beyond EU boundaries (tankering). Typical city pairs were used to analyse the conditions under which such tankering strategies are economically attractive. The analysis shows that the attractiveness of tankering depends substantially on the relationship between fuel prices and allowance prices. If the price relation as of March 2006 is taken as a basis, tankering would be attractive within a radius of up to 4,000 km especially on southbound and eastward routes. Emissions trading could, under unfavourable conditions, be evaded for up to 20% of the total fuel consumption in aviation with the help of tankering. Although this value is only a theoretical upper limit, more than 10% of fuel consumption could be affected by tankering.  相似文献   

Slovenia's climate policy efforts: CO2 tax and implementation of EU ETS     

TANJA MARKOVIČ-HRIBERNIK  ALEKSANDRA MURKS 《Climate Policy》2013,13(2):139-155

Slovenia is required to reduce its greenhouse gas emissions to an average of 8% below the base year 1986 in the period 2008–2012, due to the ratification of the Kyoto Protocol in 2002. It was the first of the transition countries to implement a CO₂ tax in 1997. At the beginning of 2005, Slovenia joined other EU Member States by implementing the Emissions Trading Scheme. In contrast with other new EU Member States, Slovenia will be a net buyer of allowances. Therefore future movements on the emissions market will play an important role in the compliance costs of achieving the Kyoto target. The main purpose of this article is to present the establishment and characteristics of the first national allocation plan (NAP1) and to describe the main elements of the second national allocation plan (NAP2) for Slovenia within the EU Emissions Trading Scheme, the expected movements on the emissions allowances market in Slovenia, the expected compliance cost of achieving the Kyoto target and to present the main characteristics and efficiency of the CO₂ tax in Slovenia.  相似文献   

A shale gas revolution for China?     

Neil Gunningham 《Climate Policy》2013,13(2):302-320

The question of whether China is on the verge of a ‘shale gas revolution’ is examined. This has potentially significant consequences for energy policy and climate change mitigation. Contrary to the optimistic reading of some commentators, it argues that various technological, environmental, political, regulatory and institutional factors will constrain the growth of China's shale gas market and that such a revolution might in any event have consequences that are at best mixed, at worst antithetical to climate change mitigation.Policy relevanceChina's reserves of unconventional gas have the potential to transform energy policy, as has occurred in the US, resulting in the substitution of shale gas for coal in the energy mix. Because gas emits only approximately half the GHG per unit as coal, such a move would have important implications for climate policy. However, substantial obstacles stand in the way of the ‘energy revolution’ that some policy analysts see China as embarking upon. The need to acknowledge these obstacles, particularly those relating to regulation and governance (and whether or to what extent they can be overcome), is an issue of profound importance to the future of climate and energy policy.  相似文献   

Achieving a low-carbon society     

John Reilly 《Climate Policy》2013,13(2):155-158

Climate change is perhaps the central challenge that faces humanity. If the concept of green growth is to be anything more than a mere rebranding of the concept of sustainability, then it must elucidate the relationship between economic activity and pollution and provide a more detailed economic account of it. The articles in this Special Issue focus on ways in which GHG emissions may be reduced while satisfying the increasing demand for energy: from global, technological or economic solutions, to sub-national, financial or regulatory ones. Although the wide disparity in income between the least and most wealthy makes it difficult to reach a consensus on the best way to achieve a low-carbon society, the scale and potential effects of climate change make it imperative that one is reached.  相似文献   

Alternative climate policy pathways in the US     

Robert MacNeil 《Climate Policy》2013,13(2):259-276

Although it is likely that the political–economic coalition required for implementing a federal cap-and-trade programme for GHGs in the US is now sufficiently strong, the structural impediments that have prevented its legislative passage remain impressively durable and can be expected to continue to lay waste to congressional proposals for the foreseeable future. Indeed, given the complex history of environmental policy gridlock in Washington since the early 1980s, any expectations that a cap-and-trade programme could have been realistically achieved through the traditional legislative passage in Congress are fundamentally misplaced. Building on previous research, it is argued that – as with most other forms of environmental policy in the US over the past three decades – a national carbon market is more plausible given alternative policy pathways, which if taken are capable of circumventing the Federal Congress altogether. In particular, the interaction between litigation against the federal government and the ‘rulemaking’ authority possessed by the Executive Branch provides the potential space for the current administration to unilaterally establish a model rule for a national carbon-trading programme.

Policy relevance

This article aims to contribute to American climate policy debates by re-thinking the policy mechanisms most capable of establishing a national carbon market in the US. By taking into account the array of structural factors that have prevented the legislative passage of such a programme in federal Congress, a range of alternative policy ‘pathways’ is considered that have historically allowed progressive environmental policies to endure in Washington (despite increased Congressional gridlock over the past few decades). Two specific alternative strategies and the relationship between them are assessed: the use of litigation to impose legal obligations on federal agencies to regulate effluents, and the use of executive authority to define the nature and scope of environmental regulation. The administration's current potential to unilaterally develop a model-rule for a cap-and-trade programme under the Clean Air Act is emphasized, and the political implications of such a strategy are considered.  相似文献   

Sectoral targets for developing countries: combining ‘common but differentiated re-sponsibilities’ with ‘meaningful participation’     

《Climate Policy》2013,13(1):731-751

Although a global cap-and-trade system is seen by many researchers as the most cost-efficient solution to reduce greenhouse gas (GHG) emissions, the governments of developing countries refuse to enter into such a system in the short term. Many scholars and stakeholders, including the European Commission, have thus proposed various types of commitments for developing countries that appear less stringent, such as sectoral approaches. A macroeconomic assessment of such a sectoral approach is provided for developing countries. Two policy scenarios in particular are assessed, in which developed countries continue with Kyoto-type absolute commitments, while developing countries adopt an emissions trading system limited to electricity generation and linked to developed countries' cap-and-trade systems. In the first scenario, CO₂ allowances are auctioned by the government, which distributes its revenues as a lump sum to households. In a second scenario, the auction revenues are used to reduce taxes on, or to give subsidies to, electricity generation. The quantitative analysis, conducted with a hybrid general equilibrium model, shows that such options provide almost as much emissions reduction as a global cap-and-trade system. Moreover, in the second sectoral scenario, GDP losses in developing countries are much lower than with a global cap-and-trade system, as is also the effect on the electricity price.  相似文献   

The impact of the unilateral EU commitment on the stability of international climate agreements     

《Climate Policy》2013,13(2):148-166

The negotiation strategy of the European Union was analysed with respect to the formation of an international climate agreement for the post-2012 era. Game theory was employed to explore the incentives for key players in the climate policy arena to join future climate agreements. A ?20% unilateral commitment strategy by the EU was compared with a multilateral ?30% emission reduction strategy for all Annex-B countries. Using a numerical integrated assessment climate—economy simulation model, we found that leakage, in the sense of strategic policy reactions on emissions, was negligible. The EU strategy to reduce emissions by 30% (compared with 1990 levels) by 2020, if other Annex-B countries follow suit, does not induce the participation of the USA with a comparable reduction commitment. However, we argue that the original EU proposal can be reshaped so as to stabilize a larger and more ambitious climate coalition than the Kyoto Protocol in its first commitment period.  相似文献   

Identifying carbon leakage sectors in the EU ETS and implications of results     

Ingmar Juergens  Jesús Barreiro-Hurlé  Alexander Vasa 《Climate Policy》2013,13(1):89-109

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Achieving additional emission reductions under a cap-and-trade scheme     

Paul Twomey  Regina Betz  Iain MacGill 《Climate Policy》2013,13(4):424-439

Over the last decade, cap-and-trade emissions schemes have emerged as one of the favoured policy instruments for reducing GHG emissions. An inherent design feature of cap-and-trade schemes is that, once the cap on emissions has been set, no additional reductions beyond this level can be provided by the actions of those individuals, organizations and governments within the covered sectors. Thus, the emissions cap constitutes an emissions floor. This feature has been claimed by some to have undesirable implications, in that it discourages ethically motivated mitigation actions and preempts the possibility that local, state and national governments can take additional mitigation action in the context of weak national or regional targets. These criticisms have become prominent in Australia and the US within the public debate regarding the adoption of an emissions trading scheme (ETS). These criticisms and their potential solutions are reviewed. A set-aside reserve is proposed to automatically retire ETS permits, which would correspond to verified and additional emissions reductions. This minimizes the possibility that ethically motivated mitigation actions are discouraged, allows for additional action by other levels of government, while providing transparency to other market participants on the level of permit retirements.  相似文献