Chemistry of chromium spinel in high-Mg rocks from the Morungava Intrusion,Cretaceous Paraná Igneous Province,southernmost Brazil     

Pinto  Viter Magalhães  Massonne  Hans-Joachim  Wildner  Wilson  Hartmann  Léo Afraneo  Debruyne  David  Theye  Thomas 《Mineralogy and Petrology》2019,113(6):765-782

Mineralogy and Petrology - Mafic-ultramafic intrusions within continental flood basalt terrains are frequently associated with Cu-Ni-PGE mineralization. This study aims to constrain the...  相似文献   

Comment on “Chelyabinsk,Zond IV,and a possible first-century fireball of historical importance”          下载免费PDF全文

William K. Hartmann  Alexander Forte  Alina SABYR 《Meteoritics & planetary science》2018,53(10):2243-2246

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Regional grain size variations in aeolian sediments along the transition between Tibetan highlands and north‐western Chinese deserts – the influence of geomorphological settings on aeolian transport pathways          下载免费PDF全文

Veit Nottebaum  Frank Lehmkuhl  Georg Stauch  Kai Hartmann  Bernd Wünnemann  Stefan Schimpf  Huayu Lu 《地球表面变化过程与地形》2014,39(14):1960-1978

Sediment distribution is investigated applying grain size analysis to 279 surface samples from the transitional zone between high mountains (Qilian Shan) and their arid forelands (Hexi Corridor) in north‐western China. Six main sediment types were classified. Medium scale (10³ m) geomorphological setting is carefully considered as it may play an important role concerning sediment supply and availability. A tripartite distribution of sedimentological landscape units along the mountain to foreland transition is evident. Aeolian sediments (e.g. loess and dune sands) are widespread. They are used to identify aeolian transport pathways. The mU/fS‐ratio (5–11 µm/48–70 µm) among primary loess opposes the two grain size fractions being most sensitive to varying accumulation conditions. The first fraction is attributed to long‐distance transport in high suspension clouds whereas the latter represents local transport in saltation mode. The ratio shows strong correlation with elevation (R² = 0.77). Thus, it indicates a relatively higher far‐traveled dust supply in mountainous areas (>3000 m above sea level [a.s.l.]) compared to the foreland. The contribution of westerlies to high mountain loess deposits is considered likely. Hereby, the influence of the geomorphological setting on grain size composition of aeolian sediments becomes apparent: the contribution from distant dust sources is ubiquitous in the study area. However, the far‐distance contribution may be reduced by the availability of fine sand provided in low topography settings. Plain foreland areas support fine sand deflation from supplying river beds, allowing the formation of sandy loess in foreland areas and intramontane basins. In contrast, high mountain topography inhibits strong sand deflation into loess deposits. Eastern parts of the Hexi Corridor show higher aeolian sand occurrence. In contrast, the western parts are dominated by gravel gobi surfaces. This is attributed to higher sand supply in eastern parts provided by the Badain Jaran Desert and fluvial storages as sand sources. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Reconstructing the Cryogenian–Ediacaran evolution of the Porongos fold and thrust belt,Southern Brasiliano Orogen,based on Zircon U–Pb–Hf–O isotopes     

J. Pertille  L. A. Hartmann  J. O. S. Santos  N. J. McNaughton  R. Armstrong 《International Geology Review》2017,59(12):1532-1560

The Neoproterozoic geotectonic triad of the Brasiliano Orogen is reconstructed in southern Brazil from studies focused on the Porongos fold and thrust belt. We integrate field geology with isotopic studies of zircon U–Pb SHRIMP and Lu–Hf–O laser determinations in seven metasedimentary and three metavolcanic rock samples. The results indicate that the Porongos palaeo-basin was derived from mixed sources (3200–550 Ma), with major contributions from Rhyacian (2170 Ma) and Ediacaran (608 Ma) sources. Minor contributions from Archaean to Tonian sources are also registered. The maximum depositional age of the Porongos palaeo-basin is established by the age range of 650–550 Ma with T_DM model ages between 2.5 and 1.3 Ga. The reworked signature (ε_Hf values = ?34 to ?4) and the characteristic crustal magma reservoirs (δ¹⁸O ≥5.3 ‰) indicate that these sediments are equivalent to Neoproterozoic granites of the Dom Feliciano Belt. The episodic depositional history started in the Cryogenian (650 Ma) and lasted until the Ediacaran (most likely 570 Ma). A magmatic event of Tonian age is recorded in rhyodacite samples interleaved with the metasedimentary rocks and dated at 773, 801, and 809 Ma. The crustal evolution of the Sul-Riograndense Shield included mountain building, folding and thrusting and flexural subsidence in the foreland. An orogenic triad is revealed as the Pelotas Batholith, the Porongos fold and thrust belt and the Camaquã Basin, all part of the Dom Feliciano Belt.  相似文献   

Time frame of 753–680 Ma juvenile accretion during the São Gabriel orogeny,southern Brazilian Shield     

L.A. Hartmann  R.P. Philipp  J.O.S. Santos  N.J. McNaughton 《Gondwana Research》2011,19(1):84-99

The time frame of the three main geological events in the Neoproterozoic Cambaí Complex, juvenile São Gabriel belt in the southern Brazilian Shield is established by integrating field mapping, back-scattered electron imaging and sensitive high-resolution ion microprobe (SHRIMP II) U–Pb dating of 96 zircon crystals from nine granitic and metasedimentary rock samples. The three events are: (1) voluminous flat-lying paragneisses (Cambaizinho Complex) and orthogneisses (Vila Nova gneisses) between 735 and 718 Ma, (2) tonalite–trondhjemite association (Lagoa da Meia-Lua Suite) between 710 and 690 Ma, and (3) late granodiorite intrusions (Sanga do Jobim Suite) at 680 Ma. An additional older volcanic event (Campestre Formation) was dated at 753 Ma. These results are most significant for the reconstruction of West Gondwana.  相似文献   

Inducing mineral precipitation in groundwater by addition of phosphate     

Wright KE  Hartmann T  Fujita Y 《Geochemical transactions》2011,12(1):8-13

Background

Induced precipitation of phosphate minerals to scavenge trace elements from groundwater is a potential remediation approach for contaminated aquifers. The success of engineered precipitation schemes depends on the particular phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for phosphate mineral precipitation rely on stimulation of native microbial populations, we also tested the effect of bacterial cells (initial densities of 10⁵ and 10⁷ mL^-1) added to the precipitation medium. In addition, we tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM).

Results

The general progression of mineral precipitation was similar under all of the study conditions, with initial formation of amorphous calcium phosphate, and transformation to poorly crystalline hydroxylapatite (HAP) within one week. The presence of the bacterial cells appeared to delay precipitation, although by the end of the experiments the overall extent of precipitation was similar for all treatments. The stoichiometry of the final precipitates as well as Rietveld structure refinement using x-ray diffraction data indicated that the presence of organic acids and bacterial cells resulted in an increasing a and decreasing c lattice parameter, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the solids was decreased in the treatments with cells and organic acids, compared to the control.

Conclusions

Our results suggest that the minerals formed initially during an engineered precipitation application for trace element sequestration may not be the ones that control long-term immobilization of the contaminants. In addition, the presence of bacterial cells appears to be associated with delayed HAP precipitation, changes in the lattice parameters, and reduced incorporation of trace elements as compared to cell-free systems. Schemes to remediate groundwater contaminated with trace metals that are based on enhanced phosphate mineral precipitation may need to account for these phenomena, particularly if the remediation approach relies on enhancement of in situ microbial populations.  相似文献   

Challenges in optics for Extremely Large Telescope instrumentation     

P. Span  F. M. Zerbi  C. J. Norrie  C. R. Cunningham  K. G. Strassmeier  A. Bianco  P. A. Blanche  M. Bougoin  M. Ghigo  P. Hartmann  L. Zago  E. Atad‐Ettedgui  B. Delabre  H. Dekker  M. Melozzi  B. Snÿders  R. Takke  D. D. Walker 《Astronomische Nachrichten》2006,327(7):649-673

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How can we model subsurface stormflow at the catchment scale if we cannot measure it?     

Peter Chifflard  Theresa Blume  Katja Maerker  Luisa Hopp  Ilja van Meerveld  Thomas Graef  Oliver Gronz  Andreas Hartmann  Bernhard Kohl  Edoardo Martini  Christian Reinhardt‐Imjela  Martin Reiss  Michael Rinderer  Stefan Achleitner 《水文研究》2019,33(9):1378-1385

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Catchment chemostasis revisited: Water quality responds differently to variations in weather and climate     

Sarah E. Godsey  Jens Hartmann  James W. Kirchner 《水文研究》2019,33(24):3056-3069

Solute concentrations in streamflow typically vary systematically with stream discharge, and the resulting concentration–discharge relationships are important signatures of catchment biogeochemical processes. Solutes derived from mineral weathering often exhibit decreasing concentrations with increasing flows, suggesting dilution of a kinetically limited weathering flux by a variable flux of water. However, previous work showed that concentration–discharge relationships of weathering‐derived solutes in 59 headwater catchments were much weaker than this simple dilution model would predict. Instead, catchments behaved as chemostats, with rates of solute production and/or mobilization that were nearly proportional to water fluxes, on both event and interannual timescales. Here, we re‐examine these findings using data for a wider range of solutes from 2,186 catchments, ranging from ~10 to >1,000,000 km² in drainage area and spanning a wide range of lithologic and climatic settings. Concentration–discharge relationships among this much larger set of larger catchments are broadly consistent with the previously described chemostatic behaviour, at least on event and interannual timescales for weathering‐derived solutes. Among these same catchments, however, site‐to‐site variations in mean concentrations of weathering‐derived solutes exhibit strong negative correlations with long‐term average precipitation and discharge, reflecting strong climatic control on long‐term leaching of the critical zone. We use multiple regression of site characteristics including discharge to identify potential controls on long‐term mean concentrations and find that lithologic and land cover controls are significant predictors for many analytes. The picture that emerges is one in which, on event and interannual timescales, weathering‐derived stream solute concentrations are chemostatically buffered by groundwater storage and fast chemical reactions, but each catchment's chemostatic “set point” reflects site‐to‐site differences in climatically driven evolution of the critical zone. In contrast to these weathering products, some nutrients and particulates are often near‐chemostatic across all timescales, and their long‐term mean concentrations correlate more strongly with land use than climatic characteristics.  相似文献   

Diurnal cycles of formic and acetic acids in the northern part of the Guayana shield,Venezuela     

W. R. Hartmann  M. Santana  M. Hermoso  M. O. Andreae  E. Sanhueza 《Journal of Atmospheric Chemistry》1991,13(1):63-72

Formic and acetic acids were measured in a scrub-grass savanna and in a nearby semideciduous forest. Gaseous HCOOH and CH₃COOH were collected using the mist-scrubber technique, and were determined using ion chromatography. A strong diurnal cycle was observed at both sites, with higher mixing ratios during daytime. Concentrations in the savanna were always higher than in the forest. Most of the time HCOOH/CH₃COOH ratios greater than one were recorded at the savanna site, and ratios less than one at the forest site. Boundary-layer mixing ratios in the savanna region, derived from measurements during midday, are 1.3±0.4 ppbv and 0.7±0.3 ppbv for HCOOH and CH₃COOH. Dry depositions velocities between 0.5 and 1 cm s^-1 were estimated for the savanna region. Atmospheric residence times of <3 days and >5 days were estimated for the rainy and dry season, respectively.  相似文献