Clay mineral,geochemical and Sr–Nd isotopic fingerprinting of sediments in the Murray–Darling fluvial system,southeast Australia     

M. Raetz  M. Krabbendam  A. G. Donaghy 《Australian Journal of Earth Sciences》2013,60(6):965-983

The Willyama Supergroup of the Broken Hill region in southern Australia consists of supracrustal sedimentary and magmatic rocks, formed between 1810 and 1600 Ma. A statistical analysis of nearly 2000 SHRIMP U–Pb zircon spot ages, compiled from published and unpublished sources, provides evidence for three distinct tectonostratigraphic successions and four magmatic events during this interval. Succession 1 includes Redan Geophysical Zone gneisses and the lower part of the Thackaringa Group (Cues Formation). These rocks were deposited after 1810 Ma and host granite sills of the first magmatic event (1710–1700 Ma). Succession 2 includes the upper Thackaringa Group (Himalaya Formation), the Broken Hill Group and the Sundown Group and was deposited between 1710 and 1660 Ma. These rocks all contain detrital zircons from the first magmatic event (1710–1700 Ma) and in some cases from the second magmatic event (1690–1680 Ma). The second magmatic event (1690–1680 Ma) was bimodal, resulted from crustal extension, and was coeval with deposition of the Broken Hill Group and deepening of the basin. With this event a mafic sill swarm focused in the Broken Hill Domain. Mafic sills lack any trace of inheritance, unlike the granitoids that commonly contain inherited zircons typical of the supracrustal sediments. Succession 3, the Paragon Group and equivalents were deposited after 1660 Ma, but before a regional metamorphic event at 1600 Ma. Metamorphism was closely followed by inversion of the succession into a fold‐and‐thrust belt, accompanied by a fourth late to post‐orogenic magmatic event (ca 1580 Ma) characterised by granite intrusion and regional acid volcanism (the local equivalents of the Gawler Range Volcanics in South Australia).  相似文献   

电流对钋青霉菌吸附和固定铅离子的响应机制          下载免费PDF全文

王明粲  郝瑞霞  丁杨 《岩石矿物学杂志》2017,36(6):858-864

重金属铅污染是一种主要的环境污染类型,对生态以及人类健康存在着极大的威胁。如何修复铅污染是目前亟待解决的关键性问题。在众多的铅污染修复方法中,微生物修复法具有独特的优势。本实验中所使用的钋青霉菌是已被验证的对铅具有高耐受度和高吸附率的优秀菌种。在此基础上,本实验的主要研究目的在于进一步提高该菌种对铅的吸附、固定能力。实验采用双室电解池体系,分组设置0.5 V至1.5 V的梯度槽压,以观察不同电压下电流对钋青霉菌生长环境及对铅离子吸附作用的影响。实验结果表明,电流既可能促进也可能抑制钋青霉菌对铅离子的吸附和固定作用,其作用结果与外加电压的大小有关,在1.0~1.25 V的最适电压区间下,电流能增强钋青霉菌对铅离子的吸附和固定能力。  相似文献   

Fluid Inclusions and Hydrogen,Oxygen, and Lead Isotopes of the Antuoling Molybdenum Deposit,Northern Taihang Mountains,China   总被引：1，自引：0，他引：1       下载免费PDF全文

Meng Zhe  Jian‐zhong Hu  Yang Song  Xue‐qin Zhang  Hai‐yang Ding  Wei Zhou 《Resource Geology》2017,67(4):399-413

The Antuoling Mo deposit is a major porphyry‐type deposit in the polymetallic metallogenic belt of the northern Taihang Mountains, China. The processes of mineralization in this deposit can be divided into three stages: an early quartz–pyrite stage, a middle quartz–polymetallic sulfide stage, and a late quartz–carbonate stage. Four types of primary fluid inclusions are found in the deposit: two‐phase aqueous inclusions, daughter‐mineral‐bearing multiphase inclusions, CO₂–H₂O inclusions, and pure CO₂ inclusions. From the early to the late ore‐forming stages, the homogenization temperatures of the fluid inclusions are 300 to >500°C, 270–425°C, and 195–330°C, respectively, with salinities of up to 50.2 wt%, 5.3–47.3 wt%, and 2.2–10.4 wt% NaCl equivalent, revealing that the ore‐forming fluids changed from high temperature and high salinity to lower temperature and lower salinity. Moreover, based on the laser Raman spectra, the compositions of the fluid inclusions evolved from the NaCl–CO₂–H₂O to the NaCl–H₂O system. The δ¹⁸O_H2O and δD values of quartz in the deposit range from +3.9‰ to +7.0‰ and ?117.5‰ to ?134.2‰, respectively, reflecting the δD of local meteoric water after oxygen isotopic exchange with host rocks. The Pb isotope values of the sulfides (²⁰⁸Pb/²⁰⁴Pb, 36.320–37.428; ²⁰⁷Pb/²⁰⁴Pb, 15.210–15.495; ²⁰⁶Pb/²⁰⁴Pb, 16.366–17.822) indicate that the ore‐forming materials originated from a mixed upper mantle–lower crust source.  相似文献   

冻融循环条件下水泥固化铅污染土强度模型研究     

王强  尹钰婷  崔进杨  汤瑞 《冰川冻土》2017,39(3):623-628

以冻融循环条件下水泥固化铅污染土为研究对象,通过室内试验研究冻融条件下水泥固化铅污染土的抗压强度特性。试验结果表明：水泥固化铅污染土的强度随水泥掺量增大而增大,随冻融循环次数的增加先略微增加,达到峰值后,随冻融循环次数的增加而快速减小,最后趋于稳定。随着冻融循环次数的增加,不同铅离子浓度的固化铅污染土的强度损失量不同,并表现出在相同水泥掺量下,铅离子浓度为0.5%的固化污染土抗压强度损失量最小。通过回归分析,建立了水泥固化铅污染土强度随冻融循环次数变化的预测模型,为实际工程提供理论参考。  相似文献   

泥蚶(Tegillarca granosa)重组铁蛋白富集重金属离子的特性及化学传感器的研究     

张涛  苏倡  刘艳  张迪骏  周君  芦晨阳  明庭红  司开学  苏秀榕 《海洋与湖沼》2017,48(4):870-876

利用泥蚶(Tegillarca granosa)铁蛋白原核表达工程菌获得的重组铁蛋白,通过圆二色光谱分析蛋白二级结构,扫描电镜和电感耦合等离子质谱研究重组铁蛋白富集Fe~(2+)、Mn~(2+)、Cd~(2+)、Cr~(3+)、Hg~(2+)、Pb~(2+)和As~(3+)等7种重金属离子的特性,同时探索利用重组铁蛋白修饰丝网印刷电极,设计和制备重组铁蛋白检测Pb~(2+)和Cd~(2+)浓度的电化学生物传感器。结果表明复性成功的铁蛋白多为完整的?-螺旋结构,而复性不成功的蛋白聚集体则多为无规卷曲。重组铁蛋白的直径和形态与富集的离子种类有关。泥蚶铁蛋白对单一金属离子Fe~(2+)和Mn~(2+)的富集凸显优势。对两种混合金属离子的富集大多表现为竞争关系。但重组铁蛋白对Hg~(2+)和As~(3+)混合组的富集量明显高于单一金属离子组的富集量,对Hg~(2+)和As~(3+)混合组的富集表现出协同促进作用。重组铁蛋白传感器对Pb~(2+)和Cd~(2+)溶液的最低检测限为10μg/L。  相似文献   

具有可靠抗震性能的农居房屋设计     

范雷彪  李嘉昕  任忠 《华北地震科学》2012,30(2):68-72

从减少地震波吸收的角度考虑建筑物的安全性,对提升普通农居房屋的抗震性能提出一种新的设计思路。具体做法:一是设计并应用了新的建筑构件承载结构棒和新结构砌块砖;二是将框架结构技术有效应用到普通房屋的建造中,使普通农居房屋具有了框架结构的稳固作用效果;三是对墙体砖块采用捆绑加固手段,并将房屋的墙体结构和屋顶结构实现整体式连接;四是对地基结构进行改进,采用了减震和隔震手段。通过上述做法既加强了墙体强度,消除了应力集中的可能性,同时通过减轻屋顶重量达到降低、缓解地震作用力的目的。  相似文献   

关于滇东北MVT型铅锌矿成矿时代的讨论     

蒋斌斌  祝新友  黄行凯  赵伟策  吕晓强  刘孜 《地质论评》2022,68(1):138-146

滇东北地区是我国重要的铅锌矿产品生产基地,区内发育多个大型密西西比河谷型(Mississippi valley-type,MVT型)铅锌矿床,个别矿床(会泽)达到超大型.前人对该区域的铅锌矿床开展了大量的年代学研究工作,获得了一大批成矿年龄,本文在通过对各类同位素测年方法在该类型矿床中使用存在的弊端进行分析后,基于滇东...  相似文献   

Mired in the past — looking to the future: Geochemistry of peat and the analysis of past environmental changes     

Richard Bindler   《Global and Planetary Change》2006,53(4):209

Peat cores from ombrotrophic bogs have been used as a valuable archive to study environmental change for over a century. Much of this focus on the peat record has been on biological proxies of environmental change, such as pollen and peat-forming macrofossils, but there is growing interest in the geochemical record to study environmental changes. Several studies of long-term peat records in Europe have reconstructed past changes in atmospheric lead pollution, for example, and the general cohesiveness of the results and their agreement with known historical trends in metal production exemplify the best potential of peat geochemistry as an environmental archive. Based on the success with lead, a current emphasis in peat reconstructions is to assess the record of past mercury deposition and results thus far show generally consistent trends, e.g., a pre-anthropogenic mercury accumulation rate of about 0.5–1.5 μg Hg m^− 2 year^− 1. Despite this general consistency there is increasing concern that there may be diagenetic effects on the quantitative record of some metals, which can be inferred based on a strong relationship between mercury and other organically bound elements and proxies for peat decomposition (C/N ratio). However, it is possible that changes in decomposition and the alteration of some metal records could provide climatic information. A few recent studies show that closer examination of the geochemical matrix, in some cases along with biological proxies, can provide valuable information on landscape changes and climate; for example, partitioning metals into different weight fractions and source regions can be applied to climate studies. The best interpretations of the peat geochemical record in the context of environmental and climate change will likely come when geochemical and biological records are considered simultaneously.  相似文献   

Seasonal variations in the origin of lead in snow at Dye 3, Greenland   总被引：1，自引：0，他引：1  

K.J.R Rosman  W Chisholm  C.F Boutron  J.-P Candelone  J.-L Jaffrezo  C.I Davidson 《Earth and Planetary Science Letters》1998,160(3-4):383-389

The isotopic composition and concentration of lead has been measured in fresh and slightly aged snow collected at Dye 3 in southern Greenland during one full year. The lead concentration displayed large variations ranging from 14–3016 pg/g in April (spring) to 3–6 pg/g in September (summer) while the isotopic ratios changed in regular manner during the year. The ²⁰⁶Pb/²⁰⁷Pb ratios were 1.15 from spring to mid-summer snow, and increased in late summer to early autumn, reaching 1.20 in winter. These isotopic data indicate that the lead in the autumn to winter snow originated in North America, while that in spring to mid-summer snow is from Eurasia.  相似文献   

装有铅橡胶复合阻尼器结构的减震研究   总被引：7，自引：3，他引：4  

周云  邓雪松  黄文虎 《地震工程与工程振动》1998,18(4):103-110

本文在普通铅芯橡胶垫的基础上,提出了一种新型阻尼器－铅橡胶复合阻尼器,并介绍了其构造与工作原理,建立了铅橡胶复合阻尼器结构的分析模型,并对铅橡胶复合阻尼器的减震效果进行了初步分析。结果表明,铅橡胶复合阻尼器具有很好的减震效果具有广阔的应用前景。  相似文献