PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER     

张正斌  杨长春  刘莲生 《中国海洋湖沼学报》1992,(2)

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c  相似文献   

DETERMINATION OF DISSOLVED ORGANIC CARBON IN SEAWATER USING UV/PERSULPHATE METHOD AND HTCO METHOD   总被引：5，自引：0，他引：5  

王江涛  张正斌  刘莲生 《中国海洋湖沼学报》1997,15(1):25-31

MODUonONThermsurmtofdissolvedorganiccarbon.(DoC)inseawaterhasprovedtobeaddricultandcontroversialproedurepeenneretal.,l992,l993,OgawaandOgam,l992,Tanoue,l992).InterestinthemeasurernentofDOCinseaytteyintenSfomtlyinoonnographicdedes(Sharp,l993)largeyduetothesuggestionthathighteIneratU-rcatalyticoxidationanalysisyieklshighervaluesthanhaditionalweoxidationmethods(SugdriraandSuzuki,l988).Thereportedhigherconcenttationsappeatalsignilicantforg1obaloasnfluxmodelingcyoggweiler,l992)andforunderst…  相似文献   

海洋化学中的直线自由能关系——Ⅰ.海水体系     

张正斌  刘莲生  陈镇东 《海洋与湖沼》1984,15(1):68-81

直线自由能关系是化学上一个比较普遍的自然规律,它最初在Br(?)nsted酸碱催化定律上表现出来,之后又出现了著名的Hammett方程,迄今有关这一方程式及其种种修正式已发表的论文已有上万篇左右。直线自由能关系目前已在无机化学、有机化学、生物化学、催化和络合物化学、药物化学等方面得到具体应用,但尚未见在海洋化学上应用的  相似文献   

PHYSICAL AND INTERFACIAL CHEMISTRY OF HUANGHE ESTUARY     

张正斌  刘莲生 《中国海洋湖沼学报》1991,(4)

Summarized results of studies on the physical and interfacial chemistry of the Huanghe estuary are presented as follows: 1. The relationship between the exchange ratio (%) and pH for the Cu (II)-Sedi.ments of the Huanghe Estuary and that of the Cu (II)-illite system were observed to be very similar. 2. A stepwise ion/coordination particle exchange isotherm of trace metal in Huanghe estuary sediment was derived. 3. The ion/coordination particle exchange between trace metal and Huanghe Estuary sediment is analogous to the interfacial chemical characteristic of illite.  相似文献   

Determination of copper complexation in surface microlayer of Daya Bay and Jiaozhou Bay     

张正斌  刘春颖  于志刚  刘莲生  王肇鼎  宫海东 《中国海洋湖沼学报》2005,23(2):238-245

1 INTRODUCTION Bioavailability to the biota and the biogeo-chemistry of trace metals in marine environment areaffected by their chemical speciation in the naturalsystem (Bruland et al., 1991; Van den Berg andDonat, 1992; Wells et al., 1998). Therefore, thesetwo parameters, the ligands concentrations andconditional stability constants, are important todetermine the complexing capacity. Sea surface microlayer (SML), the thin interfa-cial boundary between ocean and atmosphere, playsan imp…  相似文献   

关于〔Si(OH)_4·SO_4〕~(2-)络合物的几点看法     

林开濬  张正斌 《海洋湖沼通报》1983,(4)

最近,美国的Marshall和陈镇东发表了一系列文章,研究了无定形二氧化硅的溶解度。给出了在不同温度下无定形二氧化硅在氯化钠、氯化镁、硫酸钠和硫酸镁四种电解质溶液中的溶解度数据。根据实验结果,建立了经验公式和其相应的参数。为研究海洋中“热泉”附近氧化物的行为提供了可靠的基础。面对硫酸钠增大无定形二氧化硅的溶解度,而不是像其他一些非硫酸盐一样降低其溶解度这一实验事实,Marshall和陈镇东提出了生成三氢键缔合物的假设,以解释在硫酸钠溶液中无定形二氧化硅溶解度增大的原因。他们认为:  相似文献   

Use of microelectrodes for electrochemical measurement of nitric oxide in natural seawater     

张正斌 邢磊蔡卫君  任春艳姜立庆 《中国海洋湖沼学报》2004,22(4):373-380

In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode.  相似文献   

海水中酚类有机污染物在粘土表面上的交换作用——Ⅱ.酚类有机污染物在粘土表面上的交换等温线及其分级交换的空间位阻效应     

杨桂朋  张正斌 《海洋学报》1992,14(5):135-141

  相似文献   

面向疾病的空间聚集性与影响因素分析方法     

胡涛  王丽娜  李响  张正斌  俞鑫楷 《地理信息世界》2024,(1):65-73

疾病的发生与自然环境、社会环境和人群特点密切相关,其发生与流行通常具有一定的空间分布特征。针对目前在疾病空间聚集特征与影响因素的已有研究中,缺少两者关联关系的探讨,以及空间尺度多集中于省、市和县域,因此,本研究提出一种面向疾病空间聚集性与影响因素分析的方法。以武汉市的历史肺结核数据为例,进行基于乡镇尺度的肺结核发病率数据及影响因素数据的处理与整合,基于空间自相关方法分析2011年、2013年和2015年肺结核空间聚集情况;并运用地理探测器探测肺结核发病率空间分布的影响因素及交互作用,探究肺结核空间聚集的成因。结果表明：肺结核热点聚集乡镇主要分布在新洲区、江夏区和蔡甸区,冷点聚集乡镇主要分布在洪山区;植被指数、人口密度、人均GDP及五类兴趣点密度（医疗保健类、生活服务类、餐饮类、住宅类和农林牧渔类）为肺结核发病率空间分布的主要影响因素,其交互作用对肺结核发病率影响显著增强。研究成果可为武汉市肺结核防治提供科学参考。  相似文献   

大亚湾海水胶体粒子生物-化学研究Ⅰ(二)痕量金属交换吸附的昼夜变化     

李丽  王肇鼎  张正斌  潘明祥  黄洪辉  韦桂峰 《中国海洋大学学报(自然科学版)》2000,30(2):303-308

1998年11月对大亚湾大鹏澳网箱养殖海区定点24h连续观测,测定了痕量金属、营养盐、溶解氧和盐度等项目;利用质量平衡实验验证了切向超滤实验对痕量金属回收的可行性;分析了不同粒径微粒上痕量金属与水环境要素的周日变化特征.  相似文献