钨的地球化学性质与华南地区钨矿成因   总被引：2，自引：1，他引：2  

祝红丽  张丽鹏  杜龙  隋清霖 《岩石学报》2020,36(1):13-22

在地球演化早期的强还原条件下,钨表现为中等亲铁元素,因此地球中 90%的钨进入地核。在地幔和地壳的演化过程中,钨是极度不相容亲石元素,从而导致钨元素在地壳中的丰度约是地幔丰度的250倍。钨在岩浆熔体中主要以钨酸的形式迁移,在成矿热液中主要以氟、硼化合物或其络合物的形式运移。钨的矿化需要其在部分熔融、岩浆演化和晚期热液等各阶段逐渐富集。中国是世界上钨矿产资源最丰富的国家,约占世界总储量的60%以上,其中绝大多数矿床产在华南地区,与华南大规模的中生代岩浆活动具有密切的时空联系。微量元素特征(高Rb/Sr和K/Rb比值,低Nb/Ta和Zr/Hf比值)显示它们往往经历了强烈的岩浆分异,这可能与这些花岗岩通常具有高挥发分含量(如F)有关。岩浆中高的F含量对钨的富集和矿化十分重要,它可以降低熔体固相线、粘度和密度,有利于提高岩浆的结晶分异程度,因而使得高度不相容的钨元素在岩浆演化过程和后期热液阶段的富集与矿化。富挥发分岩浆的形成可能与俯冲板块后撤,软流圈物质上涌导致的多硅白云母等富F矿物的高温分解有关。研究表明,华南南岭地区侏罗纪的钨矿化花岗岩主要形成于太平洋板块的俯冲后撤,而华南南部晚白垩世钨成矿作用与新特提斯洋的俯冲后撤有关。  相似文献   

吕梁地区古元古代花岗岩浆作用——来自同位素年代学的证据   总被引：7，自引：20，他引：7  

耿元生杨崇辉  万渝生 《岩石学报》2006,22(2):305-314

古元古代吕梁变质地块位于华北克拉通中部构造带中段的西缘，其中有大量的古元古代花岗闪长质到花岗质的侵入体。根据花岗岩岩石组合和同位索地质年代学资料，吕梁地区古元古代的花岗岩浆事件可分四个阶段。在早期拉张阶段，2364Ma的盖家庄片麻状花岗岩侵位，并伴随有大陆边缘裂谷型的吕梁群的火山活动。拉张一挤压转化阶段的花岗岩浆活动，代表性产物是2150Ma左右的赤坚岭片麻状花岗闪长岩；中期的挤压阶段的花岗岩浆活动，代表性产物是2063Ma的道仁沟石英二长岩、1906Ma的惠家庄似斑状黑云母花岗岩和1848Ma的市庄细粒花岗闪长岩等；晚期的拉张阶段的花岗岩浆活动，主要有1805Ma的大草坪斑状花岗岩和1800Ma的芦芽山斑状花岗岩、云中山花岗岩等。锆石SHRIMP U-Pb年代学研究结果表明，以往划分的关帝山杂岩是由不同时期的花岗岩所组成，应以解体。可将其划分为挤压阶段的惠家庄岩体、市庄岩体和后造山阶段的大草坪岩体等。  相似文献   

北京房山岩体形成过程中的岩浆混合作用证据   总被引：15，自引：6，他引：15  

覃锋  徐晓霞  罗照华 《岩石学报》2006,22(12):2957-2970

北京房山侵入岩体主要由石英二长闪长岩单元和三种不同结构的花岗闪长岩单元组成,岩体中广泛分布的镁铁质微粒包体、富集暗色矿物的线状条带以及各岩相单元的非渐变接触关系等宏观特征,指示岩体的形成与岩浆混合作用有密切联系。122个斜长石成分剖面电子探针分析表明,它们众数成分为 An=29的更长石。但是,其成分变化范围极宽(An=14～56),晶体内不同部位的成分有很大差别,出现正常环带的 An 值较低(14～42),内环带的 An 值较高(24～56)的特殊情况,指示斜长石结晶环境的改变,暗示具有富钙基性岩浆的加入。从岩体边部到中心,斜长石 An 牌号逐渐降低,但相邻岩相单元之间有较大的重叠,表明不同岩石单元中的斜长石成分主要受控于岩浆成分的变化,与分离结晶作用无关。斜长石的韵律性环带、特别是内环带的发育则是岩浆混合作用机制的有力证据。基性岩浆的反复注入不仅改变寄主岩浆的成分,而且也控制了它的温度、定位机制和岩石的结构特征。因此,房山岩体的形成过程还包含了镁铁质岩浆多次注入的历史,并且从外到里基性岩浆的作用逐渐减弱。  相似文献   

甘肃西秦岭金矿富集区花岗岩与金成矿作用的关系   总被引：7，自引：0，他引：7       下载免费PDF全文

殷勇  赵彦庆 《甘肃地质》2006,15(1):36-41

依据甘肃西秦岭金矿富集区矿床和相关花岗岩的同位素年龄和稳定同位素数据,探讨了该区金矿床成矿作用与花岗岩成岩作用的关系及成矿物质来源。从数据显示,成岩和成矿作用均发生在侏罗纪;成岩年龄集中分布在200Ma~171Ma;大规模成矿作用年龄分布在195Ma~140Ma;成矿事件同步或略滞后于花岗岩浆活动;相关花岗岩是地壳物质重熔而成的S型;花岗岩浆侵入是该区金矿形成的主导因素;成矿物质和流体来源于地壳。  相似文献   

柴达木盆地北缘大柴旦地区古生代花岗岩锆石SHRIMP定年   总被引：15，自引：2，他引：15  

吴才来郜源红  吴锁平陈其龙 Joseph L. WOODEN Frank K．MAZADAB Chris MATTINSON 《岩石学报》2007,23(8):1861-1875

大柴旦地区是柴北缘古生代超高压带的重要组成部分,与超高压岩石相伴的花岗岩十分发育。这些花岗岩具有两类不同的岩石地球化学特征,Ⅰ类以 Na_2O/K_2O 比值小于1、明显的负 Eu 异常和低 Sr、高 Y 为特征,具有 S-型花岗岩的属性,Ⅱ类以 Na_2O/K_2O 比值大于1、弱负 Eu 异常到正 Eu 异常和高 Sr、低 Y 为特征,具有Ⅰ-型花岗岩的属性,反映了它们的源岩及成因上的差异。锆石 SHRIMP U—Ph 定年结果表明,大柴旦地区花岗岩的年龄可分为三组,第一组年龄为446.3±3.9Ma,第二组年龄分别为408.6±4.4Ma、403.3±3.8Ma、401.8±3Ma,第三组年龄分别为374.5±1.6Ma、372±2.1Ma。结合区域地质特征,我们认为,第一组年龄可能反映了柴达木陆块与中南祁连板块碰撞的时代,第二组年龄可能反映了深俯冲地下的板块由于拆沉而折返的时代,第三组年龄可能反映了碰撞隆起后造山带上不同块体之间的伸展、滑塌的时代。  相似文献   

Granite fracture index to check suitability of granite outcrops for quarrying   总被引：1，自引：0，他引：1  

Luís M.O. Sousa   《Engineering Geology》2007,92(3-4):146-159

A correct knowledge of fracture patterns previous to quarrying is important for economical exploitation. This work comprises the general characterization of the discontinuities of 10 granite rock masses in NE Portugal. During the study some discontinuity characteristics such as orientation, persistence, aperture, trace length and spacing were evaluated. The differences in the characteristics of the selected granites were described, and the most important exploration factors were identified. In the granites studied, most of the joints are oriented from N10°E to N50°E, which is compatible with the regional fracture pattern. Concerning joint termination, the XX type is common, while the RR type is rare; the persistence index ranges from 3.5% to 25.4%. Closed joints are predominant in the granites studied (> 72.4%), and openings of the others are about 1–2 mm as a result of superficial displacement of the granite blocks. The percentage of filled joints, usually by quartz and pegmatite, is different from one granite to another, but most are < 20%. The average joint length ranges from 11.1 m in post-tectonics granites to 4.6 m in syntectonic granites. Joint spacing varies from 0.98 to 2.8 m with higher values in post-tectonic granites. Joint-space distributions of the granites studied are close to log-normal and exponential distributions. Volumetric joint count (Jv) ranges from 0.8 to 2.1 joints/m³ and is used for categorizing the places of each granite. The relationships between Jv and other joint characteristics, such as length, spacing and number of joint sets, were investigated. A Granite Fracturing Index (GFI) is introduced, computed on the basis of volumetric joint count, number of joint sets and true joint spacing. The GFI classification of studied places allows us evaluate the suitability for profitable exploitation.  相似文献   

U–Pb dating of the end of the Pan-African orogeny in the Tuareg shield: the post-collisional syn-shear Tioueine pluton (Western Hoggar, Algeria)     

J. L. Paquette  R. Caby  M. T. Djouadi  J. L. Bouchez 《Lithos》1998,45(1-4):245-253

The Tioueine pluton intrudes the Neoproterozoic series of the Iskel terrane, located in the Tuareg shield, western Hoggar. The consistency of the internal structures as well as the nature and organization of the associated microstructures demonstrate that the Tioueine pluton was emplaced syn-kinematically while N–S strike–slip shear zones were active. The syn-tectonic emplacement of the Tioueine massif implies that this pluton, although belatedly crystallized, entirely belongs to the concept of post-collisional magmatism. In order to date precisely the late Pan-African tectono-metamorphic event in the studied area, an U–Pb age of 523±1 Ma was obtained from abraded zircons of a late quartz–syenite from the Tioueine pluton. This early Cambrian age is younger than the other plutons of the Tuareg shield, which were mainly emplaced between 630 Ma and 580 Ma. This dating also shows that the Tuareg shield was not a single coherent block at 525 Ma, but rather an amalgam of active terranes moving each other along major shear zones. Finally, the Tioueine massif represents probably the final welding of the Tuareg shield assembly of terranes and consequently the end of the post-collisional orogenic episode in the whole Pan-African belt.  相似文献   

Fluid and melt inclusion evidence for the origin of idiomorphic quartz crystals in topaz-bearing granite from the Salmi batholith, Karelia, Russia   总被引：1，自引：0，他引：1  

M. Poutiainen  T. F. Scherbakova 《Lithos》1998,44(3-4):141-151

Idiomorphic quartz crystals in topaz-bearing granite from the Salmi batholith contain primary inclusions of silicate melt and abundant mostly secondary aqueous fluid inclusions. Microthermometric measurements on melt inclusions give estimates for the granite solidus and liquidus of 640–680°C and 770–830°C, respectively. Using published solubility models for H₂O in granitic melts and the obtained solidus/liquidus temperatures from melt inclusions, the initial water concentration of the magma is deduced to have been approximately 3 wt.% and the minimum pressure about 2 kbar. At this initial stage, volatile-undersaturation conditions of magma were assumed. These results indicate that the idiomorphic quartz crystals are magmatic in origin and thus real phenocrysts. During subsolidus cooling and fracturing of the granite, several generations of aqueous fluid inclusions were trapped into the quartz phenocrysts. The H₂O inclusions have salinities and densities of 1–41 wt.% NaCl eq. and 0.53–1.18 g/cm³, respectively.  相似文献   

Mineral chemistry constraints on the evolution of the 1.88–1.87 Ga post-kinematic granite plutons in the Central Finland Granitoid Complex     

Brent A. Elliott  O. Tapani Rm  Mikko Nironen 《Lithos》1998,45(1-4):109-129

A suite of post-kinematic, 1.88–1.87 Ga, silicic plutons crosscut 1.89–1.88 Ga synkinematic granitoids in the Central Finland Granitoid Complex (CFGC) in south-central Finland. The plutons range from biotite±hornblende quartz monzonite to syenogranite and include pyroxene- and olivine-bearing varieties. Mineral chemical data on feldspars, biotite, amphibole, pyroxenes, olivine, and oxides of the post-kinematic plutons are presented. The data are interpreted to show that these plutons register (1) a considerable range in pressure from 2–4 kbar (amphibole barometry) to 5–7 kbar (olivine–pyroxene barometry), (2) temperatures mostly reflecting resetting during cooling (450–800°C; QUIlF thermometry), and (3) low fO₂ (log fO₂ ΔFMQ −0.3 to −1.5; QUIlF equilibria). In particular, plutons with olivine- and pyroxene-bearing margins and amphibole-dominated central parts record progressive oxidation and hydration upon cooling, shifting from the QUIlF equilibrium toward KUIlB. The post-kinematic granites can be considered post-collisional in regard to compressional events in the CFGC and display many of the characteristics of the anorogenic 1.6 Ga rapakivi granites further south. They were presumably derived from a deep and dry crustal source, like the rapakivi granites.  相似文献   

吉林省西南部地区花岗岩类微量元素特征研究及成因探讨     

郭巍  郑喜森 《吉林地质》1998,17(3):51-57

本文对吉林省西南部地区花岗岩类的微量元素特征进行了系统的研究,并利用微量元素的某些特征值对区内花岗岩成因进行了探讨。  相似文献