阴离子树脂-活性炭分离富集等离子体发射光谱法测定富钴锰结壳中的痕量金银铂钯   总被引：10，自引：1，他引：10  

李展强张汉萍  张学华李其英 李锡坤 《岩矿测试》2005,24(2):141-144

采用717阴离子树脂活性炭联合交换分离富集技术,电感耦合等离子体发射光谱法同时测定富钴锰结壳中痕量金、银、铂、钯。方法检出限四元素分别为:Au1. 3、Ag0. 4、Pd0. 6、Pt4. 8ng/g。样品加标回收率在89. 0% ~110. 3%,相对标准偏差3. 5% ~7. 8% (n=4)。方法已用于富钴锰结壳中痕量金银铂钯的测定。  相似文献   

WC类硬质合金胎体材料的试验研究   总被引：4，自引：1，他引：3       下载免费PDF全文

王镇全  王克雄 《探矿工程》2000,(5):25-26

介绍一种ＷＣ类硬质合金胎体材料配方,在胎体材料中添加了微量磷元素,通过其活化作用,使硬质合金材料在１０６０℃温度下烧结成型,并通过调节配方中的Ｃｏ－Ｎｉ含量,使其具 备了所需要的机械性能。并扼要介绍了以ＹＧ１２－Ｎｉ８－Ｐ０．２硬质合金为胎体材料的人造金刚石复合体。  相似文献   

河南信阳上天梯膨润土制备高效活性白土试验研究   总被引：6，自引：0，他引：6  

黄彦林  周一民  李英堂 《高校地质学报》2000,6(2):292-297

上天梯膨润土属于钙基膨润土,主要矿物成分是钙质蒙脱石。矿石的胶体分散性较差,阳离子交换总量较低,主要的可交换阳离子是钙、镁离子。蒙脱石的晶体化学结构研究表明,蒙脱石有较高的有序度和较大的层电荷,因此,上天梯膨润土适合于制备高效活性白土。试验讨论了酸性活化、固液比及活化时间对产品质量的影响,确定了最佳工艺条件。对原矿进行捣浆提纯后,用16％～20％的硫酸溶液对膨润土进行活化,活化时间 6～8小时,固液比1∶2。制得的活性白土的脱色力达156～218,活性度大于222m.mol/100g ,其质量达到和超过了国家行业标准和同行业该产品的指标,脱色效果良好。  相似文献   

黄姜皂素纤维渣的氯化锌热解特性     

张彩香  王焰新  甘义群 《地球科学》2005,30(5):635-638

探讨氯化锌活化黄姜皂素纤维渣的机理, 应用TG-FTIR联用技术考察了黄姜皂素纤维渣的氯化锌热解特性.不同的配比、氛围及升温速率对热解均有影响.低温氧化有利于活性炭的形成, 但高温氧气的存在对炭体烧失较大; 氯化锌与原料的配比越高, 对原料的侵蚀性越强, 采取相应的活化温度较低; 升温速率越低越有利于原料中有机质蓄积热量热解, 相应的活化温度也越低; 红外光谱图也表示挥发分产物的出现与热重分析相符, 没有时间滞后现象.因此, 确定制备活性炭的初步工艺为先在300℃左右低温炭化, 再在保护气氛中(如N2) 500℃左右活化, 升温速率10K/min左右.工业生产条件下, 活化温度最高不宜超过650℃.   相似文献   

D₂₉₀树脂-活性炭吸附富集电感耦合等离子体质谱法测定铜精矿中铂钯   总被引：1，自引：1，他引：0  

胡德新  谷松海  任海  马德起  杨丽飞  苏明跃 《岩矿测试》2013,32(4):572-575

矿产品中痕量贵金属元素的测定通常需要富集分离,在检测过程中谱线干扰较多。本文对铜精矿样品在高温下灼烧除去碳和硫,采用盐酸+王水+氢氟酸消解体系进行分解,利用D290阴离子交换树脂-活性炭作为吸附剂富集铂和钯,以Y、In、Bi为内标元素,105Pd和195Pt作为测量同位素,用电感耦合等离子体质谱法(ICP-MS)测定铂和钯的含量。铂和钯的吸附率均达到90%以上,加标回收率分别为92.0%和96.0%,检出限分别为0.126 ng/g和0.105 ng/g,方法精密度(RSD,n=6)小于4%。应用于实际铜精矿样品分析,测定值与锍镍试金-ICP-MS测定结果一致。本法的样品处理体系最大限度地减少了样品中其他金属离子对待测元素的影响,选择的内标元素和高纯氦碰撞反应可有效地减少基体效应和同质异位素干扰。相比于锍镍试金法,该方法的样品前处理简单,铂和钯的富集效果明显,测定检出限低。  相似文献   

活化构造的动力学机制研究进展   总被引：1，自引：1，他引：0  

林舸 《大地构造与成矿学》2005,29(1):56-62

活化构造理论的核心是构造活化, 他强调的是陆内活化区造山。活化构造动力学机制是活化构造理论的研究重点。在活化构造理论提出的初期, 就提出了热能聚散交替, 地幔蠕动假说。随着大陆动力学研究的深入,活化构造动力学机制的研究也获得了较快的发展。运用“岩石探针”和数值模拟实验, 对中国东部典型构造活化区进行了探讨。华北陆块中新生代构造活化( /岩石圈减薄)的动力学过程, 是源自地幔的热流与伸展应力共同作用的结果,其构造活化( /减薄)过程可以描述为:早期以热侵蚀作用为主,晚期则以机械伸展占主导地位。华南陆块的活化构造动力学机制研究表明,华南陆块的形成与发展,与岩石圈下地幔热能聚集, 导致软流圈上涌的热侵蚀、置换动力机制密切有关。活化构造动力学机制的研究发展, 是对大陆动力学研究的促进。  相似文献   

Trapping Ionic Mercury Using Different Adsorbents     

Adedamola Titi Ojedokun  Abraham Olusegun Oluwole  Olugbenga Solomon Bello 《洁净——土壤、空气、水》2019,47(12)

Of recent, adsorption process has gained a lot of attention as a cheap and effective means of removing trace metals from wastewater prior to discharge into water bodies. Being flexible in design and operation, the process has enabled an optimal recovery of trace metals such that the treated effluents meet the desired standards for waste disposal. Mercury is a toxicant released into the environment from natural and anthropogenic sources. It is notorious for having an unusual tendency to bio‐accumulate and persist in the food chain. Presence of mercury in food, especially those of aquatic sources has drastic implications on human health. Therefore, efforts have been made to develop and optimize low‐cost activated carbon (AC) as adsorbents for scavenging mercury from aqueous effluents. Herein, how mercury accumulates across the food chain, its health implications, and the recent advancement in the use of low‐cost ACs as adsorbent for trapping mercury from wastewater are highlighted. Relationship between the mercury removal efficiency and the surface morphology of the adsorbents as well as the influence of prevailing experimental condition on the sorption process were addressed. Challenges and future prospects of the use of low‐cost adsorbents in addressing mercury pollution in the environment are discussed.  相似文献   

The frequency and distribution of recent landslides in three montane tropical regions of Puerto Rico   总被引：12，自引：0，他引：12  

Matthew C. Larsen  Angel J. Torres-Snchez 《Geomorphology》1998,24(4):309-331

Landslides are common in steep mountainous areas of Puerto Rico where mean annual rainfall and the frequency of intense storms are high. Each year, landslides cause extensive damage to property and occasionally result in loss of life. Average population density is high, 422 people/km², and is increasing. This increase in population density is accompanied by growing stress on the natural environment and physical infrastructure. As a result, human populations are more vulnerable to landslide hazards. The Blanco, Cibuco, and Coamo study areas range in surface area from 276 to 350 km² and represent the climatologic, geographic, and geologic conditions that typify Puerto Rico. Maps of recent landslides developed from 1:20,000-scale aerial photographs, in combination with a computerized geographic information system, were used to evaluate the frequency and distribution of shallow landslides in these areas. Several types of landslides were documented—rainfall-triggered debris flows, shallow soil slips, and slumps were most abundant. Hillslopes in the study area that have been anthropogenically modified, exceed 12° in gradient, are greater than 300 m in elevation, and face the east-northeast, are most prone to landsliding. A set of simplified matrices representing geographic conditions in the three study areas was developed and provides a basis for the estimation of the spatial controls on the frequency of landslides in Puerto Rico. This approach is an example of an analysis of the frequency of landslides that is computationally simple, and therefore, may be easily transferable to other settings.  相似文献   

后弯管波力发电浮标模型性能试验研究   总被引：1，自引：6，他引：1  

梁贤光  王伟  杜彬  蒋念东 《海洋工程》1997,(3)

为改进后弯管波力发电浮标的性能，对多种模型进行了新一轮试验研究。测定了它们的气室平均输出气流功率随波周期的变化曲线ＮＡ－Ｔ；试验了不同质量对性能的影响；测出了不同喷咀比ε的波高比Ｈｉ／Ｈｏ、压力比ΔＰｉ／Ｈｏ和波能转换效率ηＡ。确定了最佳浮体——前方后园浮室后伸型后弯管浮体的尺寸、质量和性能参数。  相似文献   

Efficiency of Moso Bamboo Charcoal and Activated Carbon for Adsorbing Radioactive Iodine     

Chuan‐Chi Chien  Ying‐Pin Huang  Wie‐Chieh Wang  Jun‐Hsing Chao  Yuan‐Yao Wei 《洁净——土壤、空气、水》2011,39(2):103-108

Preventing radioactive pollution is a troublesome problem but an urgent concern worldwide because radioactive substances cause serious health‐related hazards to human being. The adsorption method has been used for many years to concentrate and remove radioactive pollutants; selecting an adequate adsorbent is the key to the success of an adsorption‐based pollution abatement system. In Taiwan, all nuclear power plants use activated carbon as the adsorbent to treat radiation‐contaminated air emission. The activated carbon is entirely imported; its price and manufacturing technology are entirely controlled by international companies. Taiwan is rich in bamboo, which is one of the raw materials for high‐quality activated carbon. Thus, a less costly activated carbon with the same or even better adsorptive capability as the imported adsorbent can be made from bamboo. The objective of this research is to confirm the adsorptive characteristics and efficiency of the activated carbon made of Taiwan native bamboo for removing ¹³¹I gas from air in the laboratory. The study was conducted using new activated carbon module assembled for treating ¹³¹I‐contaminated air. The laboratory results reveal that the ¹³¹I removal efficiency for a single‐pass module is as high as 70%, and the overall efficiency is 100% for four single‐pass modules operated in series. The bamboo charcoal and bamboo activated carbon have suitable functional groups for adsorbing ¹³¹I and they have greater adsorption capacities than commercial activated carbons. Main mechanism is for trapping of radioiodine on impregnated charcoal, as a result of surface oxidation. When volatile radioiodine is trapped by potassium iodide‐impregnated bamboo charcoal, the iodo‐compound is first adsorbed on the charcoal surface, and then migrates to iodide ion sites where isotope exchange occurs.  相似文献