Seasonality in UV transparency of an alpine lake is associated to changes in phytoplankton biomass   总被引：1，自引：0，他引：1  

Ruben Sommaruga  Günther Augustin 《Aquatic Sciences - Research Across Boundaries》2006,68(2):129-141

  相似文献   

Solar radiative output and its variability: evidence and mechanisms   总被引：2，自引：0，他引：2  

Claus?Fr?hlichEmail author  Judith?Lean 《Astronomy and Astrophysics Review》2004,12(4):273-320

Electromagnetic radiation from the Sun is Earths primary energy source. Space-based radiometric measurements in the past two decades have begun to establish the nature, magnitude and origins of its variability. An 11-year cycle with peak-to-peak amplitude of order 0.1 % is now well established in recent total solar irradiance observations, as are larger variations of order 0.2 % associated with the Suns 27-day rotation period. The ultraviolet, visible and infrared spectral regions all participate in these variations, with larger changes at shorter wavelengths. Linkages of solar radiative output variations with solar magnetism are clearly identified. Active regions alter the local radiance, and their wavelength-dependent contrasts relative to the quiet Sun control the relative spectrum of irradiance variability. Solar radiative output also responds to sub-surface convection and to eruptive events on the Sun. On the shortest time scales, total irradiance exhibits five minute fluctuations of amplitude %, and can increase to as much as 0.015 % during the very largest solar flares. Unknown is whether multi-decadal changes in solar activity produce longer-term irradiance variations larger than observed thus far in the contemporary epoch. Empirical associations with solar activity proxies suggest reduced total solar irradiance during the anomalously low activity in the seventeenth century Maunder Minimum relative to the present. Uncertainties in understanding the physical relationships between direct magnetic modulation of solar radiative output and heliospheric modulation of cosmogenic proxies preclude definitive historical irradiance estimates, as yet.Received: 26 August 2004, Published online: 16 November 2004 Correspondence to: Claus Fröhlich  相似文献   

Geochemistry of coral from Papua New Guinea as a proxy for ENSO ocean–atmosphere interactions in the Pacific Warm Pool     

Linda K. Ayliffe  Michael I. Bird  Michael K. Gagan  Peter J. Isdale  Heather Scott-Gagan  Bruce Parker  David Griffin  Michael Nongkas  Malcolm T. McCulloch 《Continental Shelf Research》2004,24(19):2343-2356

A Porites sp. coral growing offshore from the Sepik and Ramu Rivers in equatorial northern Papua New Guinea has yielded an accurate 20-year history (1977–1996) of sea surface temperature (SST), river discharge, and wind-induced mixing of the upper water column. Depressions in average SSTs of about 0.5–1.0 °C (indicated by coral Sr/Ca) and markedly diminished freshwater runoff to the coastal ocean (indicated by coral δ¹⁸O, δ¹³C and UV fluorescence) are evident during the El Niño – Southern Oscillation (ENSO) events of 1982–1983, 1987 and 1991-1993. The perturbations recorded by the coral are in good agreement with changes in instrumental SST and river discharge/precipitation records, which are known to be diagnostic of the response of the Pacific Warm Pool ocean–atmosphere system to El Niño. Consideration of coastal ocean dynamics indicates that the establishment of northwest monsoon winds promotes mixing of near-surface waters to greater depths in the first quarter of most years, making the coral record sensitive to changes in the Asian–Australian monsoon cycle. Sudden cooling of SSTs by 1°C following westerly wind episodes, as indicated by the coral Sr/Ca, is consistent with greater mixing in the upper water column at these times. Furthermore, the coral UV fluorescence and oxygen isotope data indicate minimal contribution of river runoff to surface ocean waters at the beginning of most years, during the time of maximum discharge. This abrupt shift in flood-plume behaviour appears to reflect the duration and magnitude of northwest monsoon winds, which tend to disperse flood plume waters to a greater extent in the water column when wind-mixing is enhanced. Our results suggest that a multi-proxy geochemical approach to the production of long coral records should provide comprehensive reconstructions of tropical paleoclimate processes operating on interannual timescales.  相似文献   

TAUVEX - Tel Aviv University UV Explorer     

Elia M. Leibowitz 《Astrophysics and Space Science》1995,228(1-2):367-372

TAUVEX - Tel Aviv University UV Explorer is a space telescope that is currently being built in Israel, to be flown on board the Russian international sattelite SRG - Spectrum Roentgen Gamma, in late 1995 or early 1996. TAUVEX is an imager in the near UV spectral window. Its major goal is to make a survey of about 10% of the UV sky, in the range = 1350 - 3500Å. A successful operation of TAUVEX will partially fill an important gap in our recognition of the sky, namely the distribution and the nature of the celestial UV sources, which are still mostly unknown. TAUVEX will also operate as a fast multicolor photometer in its UV range of operation. TAUVEX is aligned in parallel to the common optical axix of all the other instruments on board SRG, most of which are telescopes and monitors for high energy radiation. SRG will be thus able to perform for the first time in history simultaneous astronomical observations in one and the same celestial body, that cover together 7 order of magnitude of the recorded radiation. The observations of TAUVEX can be greatly enhanced by ground base observations.  相似文献   

Europa’s disk-resolved ultraviolet spectra: Relationships with plasma flux and surface terrains     

Amanda R. Hendrix  Timothy A. Cassidy  Chris Paranicas 《Icarus》2011,212(2):736-743

The full set of high-resolution observations from the Galileo Ultraviolet Spectrometer (UVS) is analyzed to look for spectral trends across the surface of Europa. We provide the first disk-resolved map of the 280 nm SO₂ absorption feature and investigate its relationship with sulfur and electron flux distributions as well as with surface features and relative surface ages. Our results have implications for exogenic and endogenic sources. The large-scale pattern in SO₂ absorption band depth is again shown to be similar to the pattern of sulfur ion implantation, but with strong variations in band depth based on terrain. In particular, the young chaos units show stronger SO₂ absorption bands than expected from the average pattern of sulfur ion flux, suggesting a local source of SO₂ in those regions, or diapiric heating that leads to a sulfur-rich lag deposit.While the SO₂ absorption feature is confined to the trailing hemisphere, the near UV albedo (300-310 nm) has a global pattern with a minimum at the center of the trailing hemisphere and a maximum at the center of the leading hemisphere. The global nature of the albedo pattern is suggestive of an exogenic source, and several possibilities are discussed. Like the SO₂ absorption, the near UV albedo also has local variations that depend on terrain type and age.  相似文献   

Calibration of a chalcogenide glass membrane ion-selective electrode for the determination of free Fe in seawater: I. Measurements in UV photooxidised seawater     

R. De Marco  D. J. Mackey 《Marine Chemistry》2000,68(4):25

Calibration of a chalcogenide glass membrane, Fe(III)ISE [Fe_2.5(Ge₂₈Sb₁₂Se₆₀)_97.5], in buffered saline media has been undertaken in order to assess the suitability of this ISE for seawater analyses. The electrode slopes in saline citrate and salicylate buffers were 26.3 and 28.2 mV/decade, respectively, for Fe³⁺ concentrations ranging from 10⁻¹⁰ M to less than 10⁻²⁵ M Fe³⁺. The calibration lines in the citrate and salicylate buffers were essentially collinear with the response in unbuffered chloride-free standards containing >10⁻⁵ M Fe³⁺, demonstrating that the response of the FeISE is unaffected by chloride ions. A mechanism involving a combination of charge transfer and ion-exchange of Fe(III), at the electrode diffusion layer, can be used to explain the ≈30 mV/decade slope of the FeISE. The response of the FeISE in UV photooxidised seawater containing 8 nM total Fe was measured as the pH was changed from 8.27 to 3.51. The slope of the response was 24.2 mV/decade [Fe³⁺] calculated as a function of pH using Fe(III) hydrolysis constants for seawater. Moreover, the response was essentially collinear with that in citrate buffers and in unbuffered solutions containing >10⁻⁵ M Fe³⁺ and the slope for the combined data was 26.2 mV/decade. This study was restricted to organic-free seawater because the certainty in Fe(III)–ligand stability constants is insufficient to warrant the selection of an ideal calibration buffer system, and there is evidence that powerful chelating ligands (e.g., EDTA along with humic and fulvic acids) may alter the response of the Fe(III)ISE. The Fe dissolution rate of the FeISE in UV photooxidised seawater was found to be 1.6×10⁻² nmol Fe/min, as measured by cathodic stripping voltammetry (CSV). This would contaminate a 100-ml sample by 0.8–1.6 nM Fe over a typical measurement period of 5–10 min obtained using a stability criterion of 0.5 mV/min. Various methods are proposed for reducing the level of contamination in open ocean samples that contain sub-nanomolar concentrations of iron. The FeISE has the potential to detect free Fe³⁺ at concentrations typically found in natural seawater.  相似文献   

菏泽市紫外线辐射变化特征及月预报方程     

孙翠凤  ;窦坤  ;程德海  ;李瑛  ;吴雷柱 《干旱气象》2014,(4):677-682

利用2008年4月至2012年12月菏泽市紫外线观测资料以及地面常规气象观测资料和空气质量资料,分析了该地区太阳紫外线辐射的变化特征及其与各因子的相关关系,并建立逐月预报方程。结果表明:菏泽紫外线辐射年总量达到187.98 W/m2,春夏两季明显高于秋冬两季,5月达到全年的最大值,1月为全年的最小值;3~9月紫外线辐射极大值均可达到5级,其他月份均可达到4级。不同天气条件下紫外线辐射强度存在明显差异,其中晴天紫外线辐射强且稳定,呈抛物线变化;多云天紫外线辐射波动较大,时强时弱;阴天紫外线辐射相对较弱。紫外线辐射强度与风速、能见度、气温呈正相关,与总云量、低云量、相对湿度呈负相关,与SO2、PM10、NO2、PM2.5多呈负相关。基于多元线性回归分析向后剔除变量方法得出的逐月预报方程,经检验总体预报效果较好,对当地紫外线等级预报工作具有参考意义。  相似文献   

Combined experimental and theoretical studies on methane photolysis at 121.6 and 248 nm—implications on a program of laboratory simulations of Titan’s atmosphere     

C. Romanzin  Y. Bénilan 《Planetary and Space Science》2010,58(13):1748-1757

Methane is, together with N₂, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C₂H₂ (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH₃, CH₂ and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry at 248 nm by comparing the chemical evolution observed after irradiation of CH₄ at 248 and at 121.6 nm (Ly-α). It is indeed important to see if the chemistry is driven the same way at both wavelengths in particular because, on Titan, methane photolysis mainly involves Ly-α photons. An approach combining experiments and theoretical analysis by means of a specifically adapted 0-D model has thus been developed and is presented in this paper. The results obtained clearly indicate that the chemistry is different depending on the wavelength. They also suggest that at 248 nm, methane dissociation is in competition with ionisation, which could occur through a three-photon absorption process. As a consequence, 248 nm photolysis appears to be unsuitable to study methane neutral photochemistry alone. The implications of this result on our laboratory simulation program and new experimental developments are discussed. Additional information on methane photochemistry at 121.6 nm are also obtained.  相似文献   

太阳大气中氢原子的赖曼谱线     

田晖  夏利东  何建森 《天文学进展》2010,28(1)

氢是太阳大气中最主要的元素。氢原子的赖曼(Lyman)谱线,尤其是赖曼阿尔法(Ly-α)谱线的辐射,是太阳色球和低过渡区能量损失的主要形式。在太阳的赖曼α像中,网络组织的辐射比较强,而辐射最强的地方是活动区。由于存在辐射转移效应,在宁静区,低阶赖曼谱线的谱形中央一般会形成一个凹陷,而在中央两侧则形成两个峰,两峰往往呈现出一定的不对称性。数值模拟和观测研究表明,赖曼谱线双峰的不对称性与高层大气中各种系统性流动有关。在太阳活动区,赖曼谱形在谱斑区与在宁静区类似;而在黑子区,赖曼谱形几乎没有中央凹陷。赖曼谱形也可用于诊断日珥、耀斑和日冕物质抛射等结构和现象的等离子体特性。该文回顾了赖曼谱线的观测历史,阐明了观测与模拟结果所揭示的物理过程,并结合笔者的认识进行了相应的评论。  相似文献   

High-frequency multi-solute calibration using an in situ UV–visible sensor     

Juan Pesántez  Christian Birkel  Giovanny M. Mosquera  Pablo Peña  Viviana Arízaga-Idrovo  Emma Mora  William H. McDowell  Patricio Crespo 《水文研究》2021,35(9):e14357

Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.  相似文献