High-frequency multi-solute calibration using an in situ UV–visible sensor     

Juan Pesántez  Christian Birkel  Giovanny M. Mosquera  Pablo Peña  Viviana Arízaga-Idrovo  Emma Mora  William H. McDowell  Patricio Crespo 《水文研究》2021,35(9):e14357

Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.  相似文献   

紫外分光光度法测定秋水仙碱中毒血清的临床应用     

刘军生  王淑萍  杜书明 《地下水》2015,(1)

目的：探讨紫外分光光度法测定秋水仙碱中毒血清,为临床秋水仙碱中毒提供诊疗依据。方法取0．5 mL 血清加提取液（三氯甲烷∶甲醇＝95∶5）4．0 mL。充分震荡萃取,高速离心,取有机层于另一试管中氮气吹干,取0．2 mL 甲醇溶解残渣,混匀,取50 mL 做紫外扫描。结果血清中秋水仙碱最大吸收峰（351±1）nm,浓度在5．0～40μg／mL 范围内呈线性,回归方程Y ＝0．0502X ＋0．0013,其相关系数为0．9995,回收率为83．8％～102．8％,相对标准差为3．3％～4．8％。日内、日间相对标准差分别为3．22％～4．74％和3．45％～4．66％,最低检出浓度为1．0μg／mL。结论该方法操作简便,分析快速,结果准确,为临床诊断秋水仙碱中毒提供了一个简便准确的检测方法。  相似文献   

夏季南海浮游植物光合固碳对不同波长阳光紫外辐射的响应   总被引：2，自引：1，他引：1  

吴亚平  高坤山 《海洋学报》2011,33(5):146-151

阳光紫外(UV)辐射影响浮游植物光合固碳,且不同波长UV辐射的生理效应不一.本文以夏季南海近岸海域浮游植物为研究对象,采用生物加权函数(Biological weighting function,BWF,亦被称为UV辐射作用光谱)的研究方法,探讨了不同波长UV辐射对浮游植物群落光合固碳的作用.结果表明,在只有可见光情况...  相似文献   

冕流电流片的白光和紫外观测研究          下载免费PDF全文

史广禄  应蓓丽  封莉  黎辉  杨翠红 《天文学报》2020,61(4):44

日冕电流片是日冕磁重联发生的主要区域, 这一过程将磁能转化为等离子体的热能和动能. 通过选取大角度光谱日冕仪(Large Angle and Spectrometric Coronagraph, LASCO)的白光与远紫外日冕成像光谱仪(Ultraviolet Coronagraph Spectrometer, UVCS)的紫外观测, 研究了2003年1月3日观测到的冕流电流片. LASCO C2白光数据显示电流片中的等离子体团在视场中可从60km·s^-1加速至340km·s^-1, 加速度为 60m·s^-2; 假设视向深度为0.3--1.5R_⊙, 得到所研究电流片在UVCS狭缝高度处的平均电子数密度约为(1.52--7.60)×10⁷cm^-3. 对沿UVCS视场狭缝分布的[Fe xviii ] 974 ? A和Lyα谱线强度进行研究, 发现电流片处的[Fe xviii ]谱线强度比周围明显增大, 计算得到所研究时段内电流片的电子温度范围为(2.94–4.04)×10⁶K; 而在电流片处的Lyα谱线强度相对周围变化不大, 在电流片内部两侧强度比中心略高, 可能的主要原因是电流片内部中心处等离子体的运动速度要比两侧快, 这使得中心比两侧有更强的多普勒暗化作用. 以UVCS观测的Lyα和[Fe xviii ]谱线的辐射强度比和计算的电子温度为约束条件, 发现当狭缝电流片处等离子体运动速度约为237–254 km·s ^?1 时, 通过理论计算的Lyα和[Fe xviii ]谱线的辐射发射率比值和观测谱线强度比值相当. 在该速度范围内, 电流片内部Lyα辐射的碰撞项约为辐射项的42%–57%. 此事件中的冕流电流片比通常情形下的冕流电流片中等离子体温度更高、运动速度更大, 可能的原因在于其南侧爆发的两个日冕物质抛射促进了电流片中的磁重联过程, 更多的磁能释放用于等离子体的加热和加速. 所得研究结果可以为我国将要发射的先进天基太阳天文台(Advanced Space-based Solar Observatory, ASO-S)未来的资料处理提供重要参考.  相似文献   

rGO-TiO_2/ASC新型光催化剂用于烟气光氧化脱硝性能研究     

李春虎  杨微微  孙圣楠  郑昱  闫欣  郑思怡  王亮 《中国海洋大学学报(自然科学版)》2014,44(10):92-97

采用一步溶剂热法制备了活化半焦负载还原氧化石墨烯掺杂二氧化钛新型负载型光催化剂,即rGO-TiO2/ASC。分别考察了高温水汽活化方法和还原氧化石墨烯rGO掺杂量对光催化脱硝性能的影响,并进一步探究光照条件、烟气氧含量和烟气湿度对NO氧化脱除的作用,得出新型负载型光催化剂rGO-TiO2/ASC光催化脱硝过程主要过程。结果表明,5%水汽高温活化半焦ASC的脱硝效率最高,反应4h后可达52%。rGO负载量为8%时,负载型光催化剂rGOTiO2/ASC脱硝性能4h后转化率达70.68%。有无O2对脱硝率影响较大,有无光照对其影响次之。无H2O时,脱硝率呈现先平稳后下降的趋势。新型负载型光催化剂rGO-TiO2/ASC的脱硝过程由光催化活性组分rGO-TiO2/ASC的光催化氧化和载体部分ASC的常规氧化两部分组成。  相似文献   

Continuous measurement of spectrophotometric absorbance in peatland streamwater in northern England: implications for understanding fluvial carbon fluxes     

Richard Grayson  Joseph Holden 《水文研究》2012,26(1):27-39

Bog systems tend to have a flashy hydrological regime with low baseflows and rapid and high storm peaks. Water derived from peatlands often contains significant amounts of organic humic and fulvic materials which form the largest fraction of the dissolved organic carbon component of the fluvial carbon flux. However, most estimates of dissolved organic carbon flux from peatlands are based on sampling that is infrequent and which may miss the periods of high flux during storm events. In order to better characterize the behaviour and fluxes of fluvial carbon it is necessary to operate more frequent sampling. This paper presents data from a continuously operating field‐based spectrophotometer simultaneously measuring absorbance across 200–730 nm at 2·5 nm intervals in runoff from an upland peatland stream. It is shown that absorbance at different wavelengths that have previously been used to characterize dissolved organic carbon varies rapidly during storm events. The probe is shown to even detect changes in absorbance characteristics in response to rainfall events before the stream discharge starts to rise. The high‐resolution behaviour of absorbance characteristics during storm events is different depending on the wavelength studied. Thus, the choice of wavelength used as a proxy for dissolved organic carbon needs careful attention and it may be that automated spectrophotometric methods which provide rich time‐series data from across the spectrum can tell us more about fluxes, processes and sources of aquatic carbon in peatland systems in the future than traditional practices have hitherto allowed. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Cyclic light and period variations of the UV Leonis system     

D. Manzoori 《Astronomische Nachrichten》2012,333(3):256-265

Solutions of the new standard V‐light curves for the EA type binary UV Leo are obtained using the PHOEBE code (0.31a version). Absolute parameters of the stellar components were then determined, enabling them to be positioned on the absolute magnitude‐color (l.e. M_V vs. B – V) isochrones diagram, based on which the age of the system is estimated to be >4×10⁹ yr. Also times of minima data (“O – C curve”) have been analyzed. Apart from an almost sinusoidal variation with a period of 29.63 yr, which modulates the orbital period, and was attributed to a third body orbiting around the system, other cyclic variation in the orbital period and also brightness, with time scales of 24.25 and 22.77 yr were found, respectively. We associate this with a magnetic activity cycle newly reported here for UV Leo (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

黄姑鱼(Nibea albiflora)雌核发育的人工诱导及鉴定          下载免费PDF全文

徐冬冬  楼宝  薛宝贵  史会来  詹炜  马世磊  毛国民 《海洋与湖沼》2013,44(2):310-317

采用紫外线(UV)灭活的同源精子通过冷休克抑制第二极体排放诱导黄姑鱼(Nibea albiflora)的雌核发育。结果表明,黄姑鱼精子最适的灭活剂量为420mJ/cm2,紫外照射剂量与黄姑鱼精子和卵子授精后的受精率及孵化率之间表现出明显的Hertwig效应。多次试验筛选的黄姑鱼雌核发育的最适条件为授精后2min于3℃处理8min。雌核发育仔鱼经形态学和流式细胞仪鉴定为二倍体。进一步利用10对微卫星分析了遗传物质在亲本和子代中的传递情况,结果表明雌核发育后代的等位基因完全来自于母本,没有父本基因参与;雌核发育后代在5个微卫星位点具有较高的重组率,使其与母本保持了高度同质性。  相似文献   

Statistical study of EUV and X-ray transient brightenings     

Jing-Wei Li  Hui Li 《中国天文和天体物理学报》2010,10(7)

Using the visual inspection and base difference method and data from the X-ray Telescope(XRT)onboard Hinode and TRACE with improved spatial and temporal resolution,we selected 48 X-ray transient brightenings(XTBs)and 237 EUV transient brightenings(ETBs)to study the connection between these two types of transient brightenings(TBs).These ETBs and XTBs have smaller areas(8.42 Mm2 and 36.3 Mm2,respectively,on average)and shorter durations(9.0 rain and 6.9 min,respectively,on average)than previous studies.These XTBs show three types of morphological structure: point-like,single-loop and multiple-loop.We find only 20% of the ETBs have corresponding XTBs while the other 80% have no X-ray signatures at all.This is presumably due to the small amount of released energy,which is not enough to heat the plasma to coronal temperatures which produce X-ray emission rather than being due to the limitation of spatial resolution and temperature sensitivity of the X-ray instrument.These small ETBs may significantly contribute to the coronal heating.  相似文献   

UVolution, a photochemistry experiment in low earth orbit: Investigation of the photostability of carbonates exposed to martian-like UV radiation conditions     

Fabien Stalport  Yuan Yong Guan  Patrice Coll  Frédérique Macari  Didier Chaput  Hervé Cottin 《Planetary and Space Science》2010,58(12):1617-1624

The detection and identification of carbonates on Mars are of prime importance to establish the evolution of its atmosphere, correlated to the history of the liquid water, or even to determine the existence of a possible ancient biological activity. Till date, no large deposits of carbonates have been found. In fact, their detection is specific to local areas and in very low amounts. The absence of such deposits is commonly attributed to the harsh environmental conditions at the surface of Mars. Additionally, the presence of UV radiation has been proposed to explain their photodecomposition and hence their absence. However, contradictory results from laboratory experiments mimicking Mars’ surface UV radiation did not resolve the behaviour of carbonates in such an environment, which is why we exposed, in low Earth orbit and in laboratory experiments, both abiotic and biotic calcium carbonates to UV radiation of wavelength above 200 nm, the same spectral distribution as the one reaching the surface of Mars. For low Earth orbit (LEO) exposure, this was done for the UVolution experiment on board the BIOPAN ESA module, which was set outside a Russian Foton automated capsule, and exposed to space conditions for 12 days in September 2007. The targeted carbonates are biominerals and abiotic samples. Our laboratory results mainly show that the exposed carbonates appear to be stable to UV radiation if directly exposed to it. The LEO experiment results tend to the same conclusion, but the integrated exposition time to Solar UV during the experiment is not sufficient to be conclusive. However, the stability of the biominerals derived from the laboratory experiment could strengthen the interest to explore deeper their potential as life records at Mars. Hence, they should be considered as primary targets for in situ analyses during future missions.  相似文献