Dehydration experiments on natural omphacites: qualitative and quantitative characterization by various spectroscopic methods   总被引：1，自引：0，他引：1  

M. Koch-Müller  I. Abs-Wurmbach  D. Rhede  V. Kahlenberg  S. Matsyuk 《Physics and Chemistry of Minerals》2007,34(9):663-678

A series of natural omphacites from a wide range of P, T occurrences were investigated by electron microprobe (EMP), infrared (IR)-, Mössbauer (MS)- and optical spectroscopy in the UV/VIS spectral range (UV/VIS), secondary ion mass spectrometry (SIMS) and single crystal structure refinement by X-ray diffraction (XRD) to study the influence of hydrogen loss on valence state and site occupancies of iron. In accordance with literature data we found Fe²⁺ at M1 as well as at M2, and in a first approach assigned Fe³⁺ to M1, as indicated by MS and XRD results. Hydrogen content of three of our omphacite samples were measured by SIMS. In combination with IR spectroscopy we determined an absorption coefficient: ε _i,tot = 65,000 ± 3,000 lmol_H2O ^?1 cm^?2. Using this new ε _i,tot value, we obtained water concentrations ranging from 60 to 700 ppm H₂O (by weight). Hydrogen loss was simulated by stepwise heating the most water rich samples in air up to 800°C. After heat treatment the samples were analyzed again by IR, MS, UV/VIS, and XRD. Depending on the type of the OH defect, the grade of dehydration with increasing temperature is significantly different. In samples relatively poor in Fe³⁺ (<0.1 Fe³⁺ pfu), hydrogen associated with vacancies at M2 (OH bands around 3,450 cm^?1) starts to leave the structure at about 550°C and is completely gone at 780°C. Hydrogen associated with Al³⁺ at the tetrahedral site (OH bands around 3,525 cm^?1, Koch-Müller et al., Am Mineral, 89:921–931, 2004) remains completely unaffected by heat treatment up to 700°C. But all hydrogen vanished at about 775°C. However, this is different for a more Fe³⁺-rich sample (0.2 Fe³⁺ pfu). Its IR spectrum is characterized by a very intense OH band at 3,515 cm^?1 plus shoulder at 3,450 cm^?1. We assign this intense high-energy band to vibrations of an OH dipole associated with Fe³⁺ at M1 and a vacancy either at M1 or M2. OH release during heating is positively correlated with decrease in Fe²⁺ and combined with increase in Fe³⁺. That dehydration is correlated with oxidation of Fe²⁺ is indirectly confirmed by annealing of one sample in a gas mixing furnace at 700°C under reducing conditions keeping almost constant OH^? content and giving no indication of Fe²⁺-oxidation. Obtained data indicate that in samples with a relatively high concentration of Fe²⁺ at M2 and low-water concentrations, i.e., at a ratio of Fe^{2+ M2}/H > 10 dehydration occurs by iron oxidation of Fe²⁺ exclusively at the M2 site following the reaction: \( {\left[ {{\text{Fe}}^{{{\text{2 + [ M2]}}}}{\text{OH}}^{ - } } \right]} = {\left[ {{\text{Fe}}^{{{\text{3 + [ M2]}}}} {\text{O}}^{{{\text{2}} - }} } \right]} + {\text{1/2}}\;{\text{H}}_{{\text{2}}} \uparrow . \) In samples having relatively low concentration of Fe²⁺ at M2 but high-water concentrations, i.e., ratio of Fe^{2+ M2}/H < 5.0 dehydration occurs through oxidation of Fe²⁺ at M1.  相似文献   

大气臭氧层,紫外辐射与人类健康   总被引：16，自引：0，他引：16  

柳燕 《地球物理学进展》1998,13(3):103-110

本文首先评述了近数十年来大气Ｏ３层的演变,其中包括全球与中国地区及南极臭氧洞的情况,之后,评述了由此引发的达地面太阳紫外辐射强度的变化,以及对人类健康与环境的影响。  相似文献   

Study of the dependence of the star formation rate in the nuclear regions of 39 Kazarian galaxies on their integral parameters     

V. Zh. Adibekyan  A. R. Petrosian 《Astrophysics》2009,52(2):192-204

A statistical study of the dependence of the star formation rate in the nuclear regions of 39 Kazarian galaxies on the integral parameters of these galaxies is carried out on the basis of spectra from SDSS DR6. The value of SFR/kpc² for our sample lies in the range 0.013÷2.04M _⨀ year⁻¹kpc⁻² (with the maximum value of 2.04 corresponding to the Kaz 98 (merger)). It is found that the surface density of the rate of star formation correlates positively with the bar structure parameter and EW(Hα), and that, for spiral galaxies of early morphological types, SFR/kpc² is greater than for the later types. It is shown that the color B-R for the galaxies and the color (u − g) _nucl for the nuclear region correlate positively with the total absorption A(Hα) in the Ha line for the nuclear region. The average value of A(Hα) for our samples is found to be A(Hα)=1.3±0.09 magnitudes. Translated from Astrofizika, Vol. 52, No. 2, pp. 211–224 (May 2009).  相似文献   

Measurements of spectral lines observed with Hinode/EIS as implications for coronal heating     

Ying Li  Ming-De Ding 《中国天文和天体物理学报》2009,9(7)

We have measured the line widths and nonthermal velocities in 12 solar regions using high resolution EUV data taken by Hinode/EIS. We find that there exists a positive correlation between the intensity and nonthermal velocity for the Fe XII emission line as well as some other lines. The correlation coefficients decrease from the disk center to the limb. However, the nonthermal velocities of a particular spectral line do not vary much in different regions, so they are considered isotropic. In particular, we find that for a coronal loop structure, the largest widths and nonthermal velocities occur at the footpoints, where outflows appear. Based on these observational results, we discuss several physical processes responsible for coronal heating.  相似文献   

Solar ultraviolet transfer in the Martian atmosphere: biological and geological implications     

C Córdoba-Jabonero  L.M LaraA.M Mancho  A MárquezR Rodrigo 《Planetary and Space Science》2003,51(6):399-410

  相似文献   

北京晴天紫外波段气溶胶光学厚度反演与分析   总被引：4，自引：1，他引：4  

刘新罡  吕达仁  肖稳安  刘春田  屈玉 《南京气象学院学报》2005,28(1):51-57

利用太阳一大气紫外光谱辐射计(SAUVS)，测量到达北京地表的太阳直接和散射紫外光谱辐射，给出反演大气气溶胶光学厚度的一种方法。结果表明：在紫外波段，大气气溶胶的光学厚度随波长的增加而单调减小，用指数函数可以很好地拟合反演结果。统计得到了3个水平能见度状况下拟合函数的系数值，与全球气溶胶监测网络(AERONET)北京站的资料对比，表明反演结果基本合理。  相似文献   

基于宽带网的河南省太阳紫外线强度监测系统研究   总被引：2，自引：1，他引：2  

冶林茂  厉玉昇  杨海鹰  陈海波 《气象科技》2005,(Z1)

使用自主研发的Gstar-Ⅱ型太阳紫外线监测仪,建立基于宽带网的河南省城市紫外线强度监测系统。太阳紫外线强度自动监测站将从紫外线传感器获得的气象要素信息传给本地专用计算机,进行数据处理和编码,然后通过互联网把数据信息送到数据业务中心站,数据业务中心站具有对接收数据进行初步处理和进库的功能;各级气象台站可以很方便地通过宽带Internet网WinSock协议进入数据处理中心,按照自己的要求调用全省紫外线强度历史和实时资料,为本地紫外线预报提供有力的科学依据和手段。  相似文献   

Sunlight Degradation of Aquatic Humic Substances Abbau von Huminstoffen unter dem Einfluß von Sonnenlicht     

D. Hongve 《洁净——土壤、空气、水》1994,22(3):117-120

Coloured bog water and an aqueous solution of fulvic acid were exposed to natural sunlight. Up to 67% reduction in colour and 32% reduction in DOC concentration were measured after 12 days exposure. Colour bleaching and reduction in ultraviolet light absorbance were independent of added preservatives. The high molecular weight fraction of dissolved organic matter was most reduced in concentration while substances with low molecular weight increased. The reduction in absorbance (λ = 254 nm) per DOC was most significant for substances with high molecular weight. The final concentration of DOC was highest in samples where microbial activity was suppressed.  相似文献   

Ultraviolet absorption spectra of some Br-containing haloalkanes     

V. L. Orkin  E. E. Kasimovskaya 《Journal of Atmospheric Chemistry》1995,21(1):1-11

The ultraviolet absorption cross sections were measured for CF₃Br, CF₂ClBr, CF₂Br-CF₂Br, CF₂Br₂, CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃ in the wavelength range 190–320 nm at 295 K. The photolysis is concluded to be the minor atmospheric sink for CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃.  相似文献   

紫外线辐射增加对大豆的影响及其估算   总被引：8，自引：0，他引：8       下载免费PDF全文

郑有飞  颜景义 《应用气象学报》1995,6(4):442-448

在田间及盆栽试验中观测到经超量紫外线（UV280～400 nm）辐射处理的大豆作物，其株型、生理活动及产量均受到不同程度的影响，其影响量随UV辐射强度，大豆品种以及环境条件不同而异。文章还给出了计算紫外线辐射对大豆影响程度的公式，该计算方法效果较好。  相似文献