北羌塘盆地中侏罗统夏里组蒸发岩锶同位素地球化学特征及物质来源     

杜少荣  苗忠英  郑绵平  张永生  张雪飞  陈文西 《矿床地质》2021,40(5):1072-1084

北羌塘盆地位于青藏高原的中部,属东特提斯构造域,是一个具有成盐远景的蒸发岩盆地.前人对盆地的研究多局限于层序地层、构造运动、油气成藏等,对于盆地内蒸发岩的研究,特别是其成矿流体来源的研究报道较少.文章通过对北羌塘盆地龙尾湖QY-1钻孔中硬石膏岩层锶同位素进行测定,首次对盆地中侏罗统夏里组蒸发岩成矿流体的来源进行探讨.结果表明,笔者所分析的样品的锶同位素比值变化范围为0.707475～0.709048,均值0.708331,与同时期全球海水锶同位素比值(0.706860～0.707081)相比略高,表明成矿流体来源主要是海水.结合前人对羌塘盆地构造运动与盆地演化的认识,认为陆源锶的输入造成了本区的锶同位素比值高于同期海水.此外,钻孔中的同位素组成与前人公布的全球中侏罗世(164～160.2 Ma)海水锶同位素曲线具有较好的对比性,中晚侏罗世羌塘盆地海侵海退作用的强弱是控制盆地夏里组锶同位素演化的主要因素.  相似文献   

北京平原区永定河地下水系统地下水化学和同位素特征   总被引：1，自引：0，他引：1  

翟远征  王金生  滕彦国  左锐 《地球学报》2011,32(1):101-106

北京平原区永定河地下水系统位于北京市的西部.在该区采集了一个水文年的大气降水样,并对其中的D和18O组成作了分析;于旱季在该地下水系统中采集了大量地下水样,并对其中的八大离子浓度、D和18O组成、Sr浓度以及87Sr/86Sr比值作了分析.研究结果表明,研究区地下水的水化学类型较为单一;研究区地下水主要来源于大气降水入...  相似文献   

息烽新萝地热井成因浅析   总被引：1，自引：0，他引：1  

李志成 《地质与勘探》2014,50(6):1155-1159

贵州息烽县城南新萝地热探采结合井位于洋水背斜西翼南倾伏端,洋水背斜为勘查区主要热储构造,近东西向的区域性白马洞大断层为该区的热源通道。储热单元为寒武系金顶山组(1j)、震旦系灯影组、洋水组(Zbdn+y);盖层为寒武系金顶山(1j)、明心寺组(1m)、牛蹄塘组(1n)的页岩、砂岩、粘土岩;热储层为震旦系灯影组、洋水组(Zbdn+y)粉-细晶白云岩、块状内碎屑白云岩、藻屑白云岩。地热井开采深度2500余米,最大开采量约1500 m3/d,热矿水井口温度46℃,为低温温热水地热资源。热矿水水化学类型为弱碱性水锶矿泉水,勘查类型热储类型为带状与层状组合热储(Ⅱ-3型)。  相似文献   

Dolomitization by hypersaline reflux into dense groundwaters as revealed by vertical trends in strontium and oxygen isotopes: Upper Muschelkalk,Switzerland     

Arthur Adams  Larryn W. Diamond  Lukas Aschwanden 《Sedimentology》2019,66(1):362-390

The Trigonodus Dolomit is the dolomitized portion of the homoclinal ramp sediments of the Middle Triassic Upper Muschelkalk in the south‐east Central European Basin. Various dolomitizing mechanisms, followed by recrystallization, have been previously invoked to explain the low δ¹⁸O, high ⁸⁷Sr/⁸⁶Sr, extensive spatial distribution and early nature of the replacive matrix dolomites. This study re‐evaluates the origin, timing and characteristics of the dolomitizing fluids by examining petrographic and isotopic trends in the Trigonodus Dolomit at 11 boreholes in northern Switzerland. In each borehole the ca 30 m thick unit displays the same vertical trends with increasing depth: crystal size increase, change from anhedral to euhedral textures, ultraviolet‐fluorescence decrease, δ¹⁸O_VPDB decrease from ?1·0‰ at the top to ?6·7‰ at the base and an ⁸⁷Sr/⁸⁶Sr increase from 0·7080 at the top to 0·7117 at the base. Thus, dolomites at the top of the unit record isotopic values similar to Middle Triassic seawater (δ¹⁸O_VSMOW = 0‰; ⁸⁷Sr/⁸⁶Sr = 0·70775) while dolomites at the base record values similar to meteoric groundwaters from the nearby Vindelician High (δ¹⁸O_VSMOW = ?4·0‰; ⁸⁷Sr/⁸⁶Sr = >0·712). According to water–rock interaction modelling, a single dolomitizing or recrystallizing fluid cannot have produced the observed isotopic trends. Instead, the combined isotopic, geochemical and petrographic data can be explained by dolomitization via seepage‐reflux of hypersaline brines into dense, horizontally‐advecting groundwaters that already had negative δ¹⁸O and high ⁸⁷Sr/⁸⁶Sr values. Evidence for the early groundwaters is found in meteoric calcite cements that preceded dolomitization and in fully recrystallized dolomites with isotopic characteristics identical to the groundwaters following matrix dolomitization. This study demonstrates that early groundwaters can play a decisive role in the formation and recrystallization of massive dolomites and that the isotopic and textural signatures of pre‐existing groundwaters can be preserved during seepage‐reflux dolomitization in low‐angle carbonate ramps.  相似文献   

High‐resolution synchrotron X‐ray fluorescence investigation of calcite coralloid speleothems: Elemental incorporation and their potential as environmental archives     

Valentina Vanghi  Andrea Borsato  Silvia Frisia  Daryl L. Howard  Gertruida Gloy  John Hellstrom  Petra Bajo 《Sedimentology》2019,66(7):2661-2685

Synchrotron high‐resolution and micro‐X‐ray fluorescence elemental mapping of two coeval coralloid speleothems from Lamalunga Cave (Italy) are complemented with petrographic, morphological and microstratigraphic studies. The importance of these speleothems relies on their direct and indirect association with a complete Neanderthal skeleton (‘Altamura Man’) found inside the cave. The coralloids grew discontinuously between 64·6 ka and the Holocene and reveal exceptionally high concentrations of Mg, Sr and Si, particularly on convex surfaces, where evaporation is more intense. The incorporation of trace elements depends on several factors including location, shape and geometrical evolution during their growth, as well as climate and environmental parameters. This resulted in calcite precipitation with Sr compositions from 100 to 1200 ppm and an average concentration of 7000 ppm Mg. An unusually high Si content (up to 16%) is possibly derived from volcanic ash transported as particulate and in solution inside the cave. The most common fabrics observed consist of non‐fluorescent elongated columnar calcite forming clean isopachous bands and fluorescent fibre‐like crystals associated with laminated, lenticular bands high in Sr, Mg and Si. Variability in Sr, Mg and Si concentrations appears to induce fabric changes in the coralloids. Elongation and lattice distortion of the crystals was found to coincide with high Mg concentrations. The transition from compact elongated to open to fibre‐like, is here interpreted as due to high concentrations of Si and Sr, which are preferentially incorporated in the speleothem at crystal boundaries and intra‐laminae. It is here inferred that coralloid fabric changes and their elemental content potentially record local rainfall variations through time, with the clean compact calcite marking high infiltration and open fibre‐like and micrite fabrics recording dry periods.  相似文献   

Preparation of strontium ferrite from strontium residue   总被引：1，自引：0，他引：1  

Chenglun Liu  Longjun Xu  Xueyan Yang  Tiefeng Peng  Jianjun Ren 《中国地球化学学报》2012,31(1):74-77

Strontium ferrite was prepared from Strontium Waste Residue (SWR) as a material. Strontium chloride was obtained by leaching SWR with ammonia chloride, and then SrCl2 was converted to SrCO3. Strontium ferrite (SrFe12O19) was formed by roasting the mixture of SrCO3 and FeCl3 in a proper proportion. The structure and magnetic susceptibility of strontium ferrite were investi-gated. The results showed that strontium conversion ratio increased with decreasing SWR grain diameter. The largest ratio was pre-sented when n(NH4Cl/Sr) was 3.6. What is more, the conversion process coincided with the kinetic characteristics of fractal reaction. The magnetic susceptibility of strontium ferrite decreased with increasing Fe3+/Sr2+ mole ratio and pH. SrFe12O19 exhibited face-centered and cubic closely-packed hexagonal structures. There were the strong diffraction peaks of Fe2O3 in the X-ray diffracto-gram of strontium ferrite. Strontium recovery ratio was 87.0%.  相似文献   

Alice Springs age shear zones from the southeastern Reynolds Range,central Australia     

I. Cartwright  I. S. Buick  D. A. Foster  D. D. Lambert 《Australian Journal of Earth Sciences》2013,60(3):355-363

The southeast Reynolds Range, central Australia, is cut by steep northwest‐trending shear zones that are up to hundreds of metres wide and several kilometres long. Amphibolite‐facies shear zones cut metapelites, while greenschist‐facies shear zones cut metagranites. Rb–Sr and ⁴⁰Ar–³⁹Ar data suggest that both sets of shear zones formed in the 400–300 Ma Alice Springs Orogeny, with the sheared granites yielding well‐constrained ⁴⁰Ar–³⁹Ar ages of ca 334 Ma. These data imply that the shear zones represent a distinct tectonic episode in this terrain, and were not formed during cooling from the ca 1.6 Ga regional metamorphism. A general correlation between regional metamorphic grade and the grade of Alice Springs structures implies a similar distribution of heat sources for the two events. This may be most consistent with both phases of metamorphism being caused by the burial of anomalously radiogenic heat‐producing granites. The sheared rocks commonly have undergone metasomatism implying that the shear zones were conduits of fluid flow during Alice Springs times.  相似文献   

准噶尔盆地哈山地区石炭系—二叠系裂缝充填方解石的成因机制及石油地质意义     

刘勇  袁海锋  高耀  赵永福  徐国盛 《地质学报》2017,91(11):2573-2583

准噶尔盆地西北缘哈山地区经历了多期强烈构造活动,石炭系、二叠系裂缝发育且普遍充填方解石脉。通过对充填方解石脉的碳、氧、锶同位素和流体包裹体等地球化学分析,探讨了该区石炭系、二叠系成缝期后的地层流体活动及其与油气成藏的关系。结果表明,充填的方解石普遍受火山热液与油源流体的双重影响,δ13 C特征反映形成方解石的碳元素存在两类来源:地幔和大气CO2,δ18 O偏负特征主要反映高温流体介质的影响,87Sr/86Sr比值说明其受幔源锶和壳源锶的混合叠加影响;综合分析认为,区内裂缝充填的方解石脉存在三种成因机制:火山热液成因、油源流体改造成因和大气水改造成因,分别对应于三类流体活动,第一类,二叠纪火山热液的活动,第二类,晚二叠世以来的油源流体,第三类,燕山期—喜马拉雅期的大气水。与油源流体有关的方解石脉中次生含烃盐水包裹体的均一温度分布在70~80℃,100~110℃,130~160℃三个温度区间,分别对应二叠纪末、三叠纪末、白垩纪末三期油源流体充注,油源流体活动对区内石炭系、二叠系的油气成藏具有重要贡献。  相似文献   

江苏栖霞山铅锌多金属矿床深部碳-氧-锶同位素地球化学特征及其指示意义   总被引：1，自引：0，他引：1  

张明超  陈仁义  李景朝  李永胜  姚磊  陈辉  来守华  王涛 《地质通报》2019,38(9):1529-1542

以栖霞山铅锌多金属矿床深部找矿钻孔岩心为对象,开展碳-氧-锶同位素地球化学研究。结果表明,栖霞山矿床矿石样品δ13CV-PDB同位素值为-5.1‰～1.9‰,且由浅部至深部,矿石样品的δ13C、δ18O值处于增大的趋势,指示成矿流体中的碳起源于碳酸盐岩、源自地幔和岩浆的深源碳。对锶同位素的研究显示,栖霞山矿石~(87)Sr/~(86)Sr值为0.704816～0.71405,部分大于矿体围岩黄龙组灰岩的~(87)Sr/~(86)Sr值(0.708329～0.709685),部分小于矿体围岩黄龙组灰岩的~(87)Sr/~(86)Sr值,并与不同来源的Sr同位素对比,揭示栖霞山矿石中Sr兼具基底地层Sr和幔源Sr的混合来源特征,且在围岩蚀变过程中~(87)Sr/~(86)Sr的变化应主要由成矿流体引起。结合本区成矿地质特征认为,栖霞山矿床成矿流体可能来自花岗岩的期后热液,在热动力作用下,流经元古宇基底地层,形成具有混合物质来源的成矿流体,成矿作用过程主要为成矿流体与围岩碳酸盐岩发生水-岩反应所致。  相似文献   

Données isotopiques (8786/Sr) et changements hydrologiques depuis 15 000 ans sur l'Altiplano andin     

ANNE COUDRAIN  MICHEL LOUBET  THOMAS CONDOM  AMAL TALBI  PIERRE RIBSTEIN  BERNARD POUYAUD 《水文科学杂志》2013,58(2):293-306

Abstract

In catchments characterized by spatially varying hydrological processes and responses, the optimal parameter values or regions of attraction in parameter space may differ with location-specific characteristics and dominating processes. This paper evaluates the value of semi-distributed calibration parameters for large-scale streamflow simulation using the spatially distributed LISFLOOD model. We employ the Shuffled Complex Evolution Metropolis (SCEM-UA) global optimization algorithm to infer the calibration parameters using daily discharge observations. The resulting posterior parameter distribution reflects the uncertainty about the model parameters and forms the basis for making probabilistic flow predictions. We assess the value of semi-distributing the calibration parameters by comparing three different calibration strategies. In the first calibration strategy uniform values over the entire area of interest are adopted for the unknown parameters, which are calibrated against discharge observations at the downstream outlet of the catchment. In the second calibration strategy the parameters are also uniformly distributed, but they are calibrated against observed discharges at the catchment outlet and at internal stations. In the third strategy a semi-distributed approach is adopted. Starting from upstream, parameters in each subcatchment are calibrated against the observed discharges at the outlet of the subcatchment. In order not to propagate upstream errors in the calibration process, observed discharges at upstream catchment outlets are used as inflow when calibrating downstream subcatchments. As an illustrative example, we demonstrate the methodology for a part of the Morava catchment, covering an area of approximately 10 000 km². The calibration results reveal that the additional value of the internal discharge stations is limited when applying a lumped parameter approach. Moving from a lumped to a semi-distributed parameter approach: (i) improves the accuracy of the flow predictions, especially in the upstream subcatchments; and (ii) results in a more correct representation of flow prediction uncertainty. The results show the clear need to distribute the calibration parameters, especially in large catchments characterized by spatially varying hydrological processes and responses.  相似文献