Identifying the Sources of Solutes in Karst Groundwater in Chongqing,China: a Combined Sulfate and Strontium Isotope Approach     

PU Junbing  YUAN Daoxian  ZHANG Cheng  and ZHAO Heping 《《地质学报》英文版》2012,86(4):980-992

Groundwater from karst subterranean streams is among the world’s most important sources of drinking water supplies, and the hydrochemical characteristics of karst water are impacted by both natural environment and people. Therefore, the study of hydrochemistry and its solutes’ sources is very important to ensure the normal function of life support systems. In this paper, thirty?five representative karst groundwater samples were collected from different aquifers (limestone and dolomite) and various land use types in Chongqing to trace the sources of solutes and relative hydrochemical processes. Hydrogeochemical types of karst groundwater in Chongqing were mainly of the Ca?HCO3 type or Ca (Mg)?HCO3 type. However, some hydrochemical types of karst groundwater were the K+Na+Ca?SO4 type (G25 site) or Ca?HCO3+SO4 type (G26 and G14 site), indicating that the hydrochemistry of these sites might be strongly influenced by anthropogenic activities or unique geological characteristics. The dissolved Sr concentrations of the studied groundwater ranged from 0.57 to 15.06 μmmol/L, and the 87Sr/86Sr varied from 0.70751 to 0.71627. The δ34S?SO42? fell into a range of ?6.8‰?21.5‰, with a mean value of 5.6‰. The variations of both 87Sr/86Sr and Sr values of the groundwater samples indicated that the Sr element was controlled by the weathering of limestone, dolomite and silicate rock. However, the figure of 87Sr/86Sr vs. Sr2+/[K++Na+] showed that the anthropogenic inputs also obviously contributed to the Sr contents. For tracing the detailed anthropogenic effects, we traced the sources of solutes collected karst groundwater samples in Chongqing according to the δ34S value of potential sulfate sources. The variations of both δ34S and 1/SO42? values of the groundwater samples indicated that the atmospheric acid deposition (AAD), dissolution of gypsum (GD), oxidation of sul?de mineral (OS) or anthropogenic inputs (SF: sewage or fertilizer) have contributed to solutes in karst groundwater. The influence of oxidation of sul?de mineral, atmospheric acid deposit and anthropogenic inputs to groundwater in Chongqing karst areas was much widespread.  相似文献   

NanoSr – A New Carbonate Microanalytical Reference Material for In Situ Strontium Isotope Analysis     

Michael Weber  Federico Lugli  Bodo Hattendorf  Denis Scholz  Regina Mertz‐Kraus  Damien Guinoiseau  Klaus Peter Jochum 《Geostandards and Geoanalytical Research》2020,44(1):69-83

The in situ measurement of Sr isotopes in carbonates by MC‐ICP‐MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well‐characterised carbonate reference materials for Sr mass fractions > 1000 µg g^?1 are available, there is a lack of well‐characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g^?1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution‐based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP‐MS in different laboratories. The ⁸⁷Sr/⁸⁶Sr ratio was determined by well‐established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA‐MC‐ICP‐MS, which resulted in ⁸⁷Sr/⁸⁶Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low‐Sr, low‐REE carbonate samples. NanoSr is available from the corresponding author.  相似文献   

Significance of isotopic and geochemical methods to determine the evolution of inland brackish and bitter water: An example from the Zuli river in the upper reaches of the Yellow River,China     

Zihao Liu  Hongbing Tan  Mark L. Brusseau 《水文研究》2021,35(1):e14024

With the increasing demand for water resources, the utilization of marginal water resources of poor-quality has become a focus of attention. The brackish water developed in the Loess Plateau is not only salty but also famous for its ‘bitterness’. In the present work, multi-isotope analysis (Sr, B) was combined with geochemical analysis to gain insight into the hydrogeochemical evolution and formation mechanisms of brackish water. These results demonstrate that groundwater in the headwater is influenced by carbonate weathering. After the confluence of several tributaries in the headwater, the total dissolved solids (TDS) of water is significantly increased. The dissolution of evaporates is shown to be the main source of salinity in brackish water, which also greatly affects the strontium isotopic composition of water. This includes the dissolution of Mg-rich minerals, which is the main cause of the bitterness. Furthermore, the release of calcium from the dissolution of gypsum may induce calcite precipitation and incongruent dissolution of dolomite, which also contributes to the enrichment of magnesium. The highly fractionated boron isotopic values observed in the upstream groundwater were explained by the absorption with clay minerals. The inflow of brackish groundwater is the source of river water. Then evaporation further aggravates the salinization of river water, with water quality evolving to saline conditions in the lower reach. When the river reaches the valley plain, the ⁸⁷Sr/⁸⁶Sr ratios decreases significantly, which is primarily related to erosion of the riverbanks during runoff. These results indicate that water resource sustainability could be enhanced by directing focus to mitigating salinization in the source area of the catchment.  相似文献   

鲤(Cyprinus carpio)仔鱼耳石锶(Sr)标记及其时滞特征的研究     

邱晨  姜涛  陈修报  刘洪波  杨健 《海洋与湖沼》2019,50(4):903-912

本研究以确认鱼类早期个体规模化耳石锶(Sr)标记的可行性及其时滞特征为目的,选择鲤(Cyprinuscarpio)仔鱼为实验对象,开展了六水氯化锶(SrCl2.6H2O)溶液2d的活体浸泡标记研究。结果显示,该浸泡标记过程对鲤存活、生长无显著影响。利用X射线电子探针微区分析(EPMA)技术进行分析:定量线分析结果显示对照组Sr/Ca比值(3.0左右)趋于稳定,标记组却均出现了明显的标记峰值(远3.0);面分布分析结果表明在标记组鲤耳石上均呈现出一圈明显、清晰可见的红色"高Sr标记环"。此外,对比对照组和标记组微化学结果发现,"高Sr标记环"在恢复续养250d后的鲤耳石仍然可见,说明Sr标记可长期存在。观察鲤仔鱼耳石微结构,发现Sr在耳石上存在明显的时滞效应。首次得出在开始浸泡后的第3天,耳石上才开始出现Sr标记,在浸泡结束后的第6天,耳石Sr标记区才会完全消失的结论。本研究首次揭示出,外源Sr标记的方法在鲤仔鱼种群大规模增殖放流标记和评价中将具有很强的稳定性、可靠性、可行性和应用潜力。  相似文献   

江苏溧水卧龙山锶矿床地质特征及找矿方向   总被引：1，自引：0，他引：1       下载免费PDF全文

陈冬  李鑫  缪柏虎  孙清钟  蔡露明  胡福培 《矿床地质》2016,35(4):709-723

卧龙山锶矿床是江苏省溧水盆地内新发现的热液充填型锶矿床,目前控制规模为中型。矿床地质特征研究表明,卧龙山锶矿床矿体的赋存位置及产状均严格受NW向断裂构造的控制;矿石自然类型以致密块状矿石为主,矿石结构以自形板片状为主,矿石构造以块状、角砾状和网脉状为主;围岩蚀变表现为中低温热液蚀变特征,且沿矿区NW向断裂呈线状分布。根据矿物的世代和穿插关系,将锶矿化划分为天青石-黄铁矿阶段、天青石阶段和方解石-天青石阶段。查明了矿区NW向构造是主要控矿因素,亦是主要找矿标志,而NE向构造是破矿构造。提出了矿区NW向构造是区域主干断裂右行扭动所派生的次级断裂构造;而NE向构造是区域主干断裂左行扭动所派生的次级断裂构造;认为矿区锶矿化发生在主干断裂右行扭动之后,左行扭动之前,并赋存在右行扭动派生的NW向断裂构造中。因此,溧水盆地锶矿勘查重点(找矿方向)应沿着开太-白马山主干断裂开展,找寻其右行扭动派生的NW向构造。  相似文献   

海底地下水排泄对海洋锶储库的影响     

王一清  吴自军 《地质论评》2022,68(1):2022020008-2022020008

海底地下水排泄（submarine groundwater discharge,SGD）不仅是全球水循环的重要组成部分,也是各种溶解化学物质由陆向海输送的重要而隐蔽通道。本文在分析全球海洋锶来源的基础上,综述了多种岩性含水层条件下SGD锶的地球化学行为及其控制因素,并利用已有的SGD通量和高分辨率全球岩性数据,计算出更为保守和精确的SGD锶通量及同位素组成,确认了SGD是海洋贫放射成因锶的重要来源之一,起到平衡河流输入的富放射成因锶的作用。  相似文献   

四川盆地西南部中二叠统白云岩成因分析——来自锶同位素、稀土元素证据     

冯轲  徐胜林  陈洪德  董翼昕 《中国岩溶》2018,37(5):659-670

白云岩作为优质的油气储层,其成因一直是沉积学研究热点,通过地球化学分析揭示其流体性质是探究白云岩成因的重要途径。本文通过对川西南中二叠统典型剖面和钻井的碳酸盐岩样品进行岩石学、稀土元素和锶同位素特征研究,分析结果显示:（1）其岩石类型主要有石灰岩、泥微晶白云岩、细-中晶白云岩和鞍形白云石4种。（2）研究区白云岩锶同位素比值（平均值0.709 77）明显高于石灰岩和同期海水,接近全球壳源锶同位素平均比值,显示白云岩化流体是热液来源,同时部分泥微晶白云岩显示海水锶同位素特征。（3）研究区碳酸盐岩相较于同期海相沉积物有较高的δCe值（平均值0.86）,显示其开放的成岩环境。（4）3种类型的白云岩相较于石灰岩有较高的δEu值（平均值0.99）和显著不同的稀土总量特征,显示研究区白云岩与石灰岩成岩流体性质不同且白云岩受到高温影响。综合分析表明,川西南地区白云岩主要是受构造控制的热液白云岩,部分为被岩浆和热液加热的海水改造的热对流白云岩。   相似文献   

微波消解-多接收电感耦合等离子体质谱高精度测定锶钕同位素组成   总被引：4，自引：4，他引：0  

袁永海  杨锋  余红霞  刘希军  许继峰 《岩矿测试》2018,37(4):356-363

应用多接收器电感耦合等离子体质谱仪(MC-ICP-MS)测定地质样品中锶、钕同位素组成时,化学前处理流程冗长、复杂,且容易出现样品未完全溶解的现象。本文采用微波消解法消解样品,在保证消解效果的前提下有效地缩短了溶样时间,在此基础上研究了锶、钕化学分离和质谱测试流程,重点考察了树脂柱的回收率和记忆效应。结果表明:树脂经10次使用后的锶、钕流程空白均低于1.0 ng,但回收率明显下降,分别由原来的98%和90%降到20%和50%,若待测样品中锶、钕含量较低,所接收的锶、钕则达不到质谱仪测试范围,因此建议锶特效树脂使用次数不超过5次,AG50W-X8稀土柱和Ln树脂使用次数不超过10次。整套流程应用于国际地质标准样品(BCR-2、W-2a、BHVO-2、AGV-2)的锶、钕分离,MC-ICP-MS所得的87Sr/86Sr、143Nd/144Nd测定值与文献报道值一致,仪器的内精度2SE(n=50)和方法的外精度2SD(n=6)均优于0.0015%,表明该流程可以满足地质样品中锶、钕同位素高精度测定的要求。  相似文献   

湘西唐家寨铅锌矿床锶、硫同位素及其对成矿物质来源的指示意义          下载免费PDF全文

王云峰  杨红梅  刘重芃  蔡应雄  谭娟娟  邱啸飞  张利国  朱随州 《中国地质》2018,45(3):564-572

唐家寨铅锌矿床位于湘西龙山—洛塔铅锌矿区的中部。对闪锌矿开展了锶同位素测试分析,通过成矿年龄(372Ma)的校正,得到初始(~(87)Sr/~(86)Sr)i的范围为0.70904~0.71143,平均值为0.70998(n=10),大于矿床形成时的海水Sr同位素,远小于富含有机质的下寒武统石牌组页岩层的Sr同位素,推测成矿流体中的Sr,可能是由具有较低Sr同位素组成的成矿期的海水混染了具有高Sr同位素的下寒武统石牌组页岩层而致。9件闪锌矿和方铅矿样品的δ~(34)SV-CDT值介于14.78‰~17.21‰,平均值为15.84‰,比同期(早奥陶世)海相硫酸盐硫同位素组成的平均值(29.5‰)低13.66‰,符合该矿床成矿温度(100~200℃)条件下硫同位素的分馏效应(10‰~20‰),表明硫化物中还原硫可能主要来源于赋矿地层中海相硫酸盐的热化学还原作用(TSR)。  相似文献   

华蓥山锶成矿带稳定同位素特征及成矿机理探讨   总被引：6，自引：0，他引：6  

朱创业  武文慧 《地球化学》1999,28(2):197-202

华蓥山Ｓｒ成矿带是我国最重要的Ｓｒ矿带。通过对该成矿带典型矿床的Ｓｒ、Ｈ、Ｏ、Ｓ同位素特征的研究,指出该Ｓｒ成矿带的Ｓｒ主要来自含矿围岩,成矿流体的水源为大气降水和地层建造水的混合流体,Ｓ源为嘉陵江组地层,在矿床稳定同位素特征及成矿物质来源研究的基础上,结合其他的矿床地质特征,指出该Ｓｒ成矿带中分散元素Ｓｒ在沉积－成岩期发生了初步富集,后经热卤水及动力改造富集成矿,属沉积－热卤水脉动力改造成因矿床  相似文献