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81.
82.
采用马弗炉将样品与NaOH混合进行熔融煅烧,热去离子水提取、离心、稀释后过OnGuard Ⅱ H柱和过滤膜进行前处理,抑制型电导离子色谱法检测,测定了Ta2O5和Nb2O5的氟离子、氯离子和硫酸根离子。该方法对三种被测阴离子的检测限(s/N=3)在0.15~0.70μg/g(以固体样品实际浓度计)或0.136~0.623μg/L(以溶液浓度计),标准曲线线性范围均在两个数量级以上,方法的精密度(RSD,n=7)小于5.46%,回收率为88%~106%,具有灵敏度高、选择性好、重现性佳、对环境友好等特点,用于实际样品的检测,结果令人满意。 相似文献
83.
Hairong LI Qinbin LIU Wuyi WANG Xuehui LIU Hailong LI Shuhai LI Xiaoyu ZHAO Lizhen WANG 《中国地球化学学报》2006,25(B08):73-74
Tea bush is one of the plants cultivated in acidic soil, and is a typical hyper-accumulator of F and Al. Brick tea is a kind of brick-formed tea compressed using the older and coarse leaves and branches of tea trees. Brick tea mixed with milk is drunk as a daily indispensable beverage for Mongols, Ewenki, and other minority nationalities in the pastoral and semi-pastoral areas of Northwest China. It is reported that drinking brick tea can result in dental and skeletal fluorosis due to the high F content in it. Because Alzheimer's disease (AD) is related with Al in human brain, and Al has potential toxicities for skeletal and neural systems, 相似文献
84.
85.
Lakshmi Narasimharao Kodali Jagadiswararao Ramayanam 《中国地球化学学报》2006,25(B08):65-65
Endemic fluorosis, caused by excess fluoride in water, is widespread in the arid and semiarid tracts of India. This disorder is of recent origin and developed due to certain faulty water management practices. After Eager reported ‘dental mottling' among emigrants from Pozzuli in Italy in 1901, several such reports came from all over the world. From 3 works published independently from Pennsylvania, Arizona and South Africa in 1931, it was known that this disorder is caused by drinking water containing over 1 mg/L fluoride during formation of permanent teeth among children.‘Skeletal fluorosis/Osteofluorosis', affecting bones and joints among adults was reported by Moeller and Gudjonsson in 1932 due to accumulation of fluoride in hard tissues by drinking water with over 7 mg/L fluoride for several years. In course of time fluorosis has been reported in over 22 countries from all over the world. Fluorosis spreads now among 67 million people in the entire arid and semiarid tracts of India. The work of National Institute of Nutrition of India at Hyderabad in 1977 revealed the spread of endemic ‘genu valgum' (knock-knee) crippling lower limbs right from childhood in association with fluorosis in most parts of India. Although preliminary work revealed that genu valgum is caused by drinking waters poor in calcium and rich in molybdenum, efforts these disorders by supplying low-fluoride water should be taken up to know its exact cause to the communities could not so eradicate The governmental efforts to eradicate the problem. 相似文献
86.
In this study, the relationship between fluorine in drinking water and that in urine of urban residents in China is assessed. Fluorine concentrations in tap water and those in urine show a good correlation with a linear regression coefficient of 0. 9798, indicating that the fluorine concentrations in big cities under investigation are extremely low, and the main source of fluorine is tap water. The weather effect on the intake amount of fluorine is also discussed. When air temperature is above 15℃, people would intake more fluorine through drinking water with the rise of air temperature. When temperature is below 15℃, no remarkable relationship is observed between air temperature and the intake amount of fluorine. This phenomenon indicates that the main source of fluorine in China is tap water instead of foodstuff. 相似文献
87.
氟铁云母——“姑苏城外”发现的新矿物 总被引:2,自引:0,他引:2
氟铁云母是三八面体云母类矿物新种 ,属铁云母的富氟类似物。新矿物产于“姑苏城外”近郊苏州A型花岗岩上部氟铁云母分异岩中。矿物呈自形 -半自形板片状 ;铁黑色 ,半透明。密度 3.18g/cm3(实测 )和 3.2 3g/cm3(计算 )。二轴负晶 ;钠光下测得折光率 :Ng =Nm =1.648,Np =1.596;2V(实测 )≈ 0° ,2V(计算 ) =0° ;Y =b =Nm。矿物多色性强 :Ng棕褐色 ,Nm暗绿色 ,Np浅棕色。由电子探针、湿法和原子吸收分析等手段提供的氟铁云母化学成分均值(wB% ) :SiO2 34 .12 ,Al2 O313.89,FeO 2 6.19,Fe2 O37.86,MgO 1.4 9,MnO 0 .68,Li2 O 0 .4 7,TiO21.2 9,ZnO 0 .2 7,NiO 0 .0 1,K2 O 8.73,Na2 O 0 .19,Rb2 O 0 .4 2 ,CaO 0 .0 2 ,BaO 0 .4 4 ,SrO 0 .0 1,H2 O 0 .91,F 3.91,Cl痕量 ,S 0 .0 0 ,O =F 1.65,总量 99.2 5。按O OH F Cl S =12及四面体阳离子数之和为 4计算的氟铁云母经验化学式为 :(K0 .92 Na0 .0 3 Rb0 .0 2 Ba0 .0 1) 0 .98(Fe2 1.82 Fe3 0 .4 9Al0 .19Mg0 .18Li0 .16Ti0 .0 8Mn0 .0 5Zn0 .0 2 ) 2 .99(Al1.17Si2 .83) 4 .0 0 O10 (F1.0 3OH0 .50 O0 .4 7) 2 .0 0 。其理想化学式为 :KFe2 3 AlSi3O10 F2 。氟铁云母属单斜晶系 1M型 ,空间群C2 /m。晶胞参数 :a =0 .5369( 8)nm、b =0 .92 89( 3)nm、 相似文献
88.
吉林省通榆、乾安县承压地下水氟污染的原因及其防治对策 总被引:3,自引:0,他引:3
本文针对吉林省通榆、乾安县潜水高区下部第四系承压地下水氟含量升高,引起氟地主病重新抬头的环境水千文地质问题,分析了氟升高的原因,主要是研发第四系承压地下水的过程中含水层顶板的大规模破坏,使高氟潜水下窜,污染了深层压水所致。对防治对策进行了探讨,提示人们在水资源开发过程中应保护开采层的地球化学环境,从违背自然的主观意识所造成的恶果中肖取教训。 相似文献
89.
90.
新疆轮台5.1级地震前地下流体前兆异常的分析 总被引:5,自引:0,他引:5
1999年9月23日在新疆轮台东北发生了Ms≥5.1级地震。震前,北天山地区地下流体相继监测到了大量的前兆异常。据此,我们对该地震做出了较好的短期预测。 相似文献