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961.
Geological investigations of the Halul and the Shraouh islands, offshore Qatar, indicate that most of their calcareous rocks, which display abundant stromatolitic bedding, belong to the Infra-Cambrian Hormuz Series. Mineralogical, petrological, and geochemical analyses show that these calcareous rocks consist dominantly of dolomite and have formed in a reducing depositional environment. Faint laminations and small streaks of organic matter furnish evidence for the involvement of algal mats in their genesis and indicate their formation in an intertidal to supratidal setting. The Halul and Shraouh dolomites experienced extensive recrystallization and sulfatization during the emplacement of the Halul and Shraouh salt domes that form the cores of the islands. During mobilization and ascent of the salt, the dolomite recrystallized, and its Sr initial ratios were abnormally enhanced by the incorporation of 87Sr from a source, which is more radiogenic than the attendant seawater at the time of the dolomite formation near the Proterozoic–Cambrian boundary. Geochemical analysis show that Si, Al, Ti Zr, and % of insoluble residue are highly correlative, suggesting the presence of detrital minerals such as rutile and zircon. A paleosabkha model may well agree with this chemical signature. However, the Infra-Cambrian age of the Hormuz rocks and the presence of stromatolitic layers containing organic materials in the studied rocks, suggest that organogenic dolomitization could be an alternative dolomitization model.  相似文献   
962.
The Tianshan Carboniferous–Permian rift-related volcanism in northwestern China represents a newly recognized large igneous province extending over at least 1.5 × 106 km2. The volcanic successions comprise thick piles of basaltic lavas and subordinate intermediate and silicic lavas and pyroclastics, and are interpreted to result from a mantle plume head with component of εNd(t) ≈ +5, 87Sr/86Sr(t) ≈ 0.704 and La/Nb ≈ 0.9. On the basis of petrogeochemical data, the Carboniferous basic lavas can be generally incorporated into low-Ti/Y (LT, Ti/Y < 500) magma type that can be further divided into three subtypes: LT1, LT2 and LT3. The chemical evolution of the LT1, LT2 (in central Tianshan) and LT3 (in western Tianshan and Jungar) lavas is controlled by an olivine (ol) + clinopyroxene (cpx) fractionation, but gabbroic fractionation accounts for the chemical variation of the LT3 lavas from eastern Tianshan. Elemental and isotopic data suggest that the chemical variation of Tianshan Carboniferous basic lavas cannot be explained by crystallization from a common parental magma.The Sr–Nd isotopic variation of the crustally contaminated LT3 lavas is related to the nature of lithosphere through which the plume-derived melts have erupted. The involvement of an older (Precambrian) lithosphere led the LT3 lavas in western Tianshan to have lower to negative εNd(t) (−1.2 to +6.1) and variable 87Sr/86Sr(t) (0.7036–0.7061), whereas the LT3 lavas from eastern Tianshan and Jungar are characterized by high εNd(t) (+4.2 to +9.7) and low 87Sr/86Sr(t) (0.7035–0.7044), that are related to the contamination of upper crust containing early Paleozoic and Devonian arc-basin volcanic rocks and/or to a pre-Carboniferous subduction enrichment of the lithospheric mantle source region. The observed geochemical variations in the Tianshan data are consistent with an AFC process.The Tianshan Carboniferous rift-related volcanic rocks display a spatial petrogeochemical variation in which predominantly uncontaminated LT1 and less-contaminated LT2 tholeiitic lavas erupted in central Tianshan rift and predominantly the strongly contaminated LT3 tholeiites erupted in the circumjacent regions of the central Tianshan rift. The LT1 and LT2 lavas were generated by a higher degree (10–30%) of partial melting in the garnet stability field of the mantle plume compared to the LT3 lavas. The lower degree (<10%) of partial melting in the spinel–garnet transition zone of the mantle plume, as is characteristic of the LT3 lavas, may be the result of a relatively lower geotherm.  相似文献   
963.
Geochemical and isotopic data for Cretaceous mafic rocks (basalt, gabbro, and diorite) from the Lower Yangtze region, northern Yangtze block, constrain the evolution of the lithospheric mantle. The mafic rocks, separated into the northeast and southwest groups, are alkaline and evolved, with low Mg# values (44–58) and variable SiO2 contents (47.6–57.4 wt%). Enriched LREEs, LILEs, and Pb, together with depleted Nb, Zr, and Ti, suggest that the mantle sources were metasomatized by slab-derived fluid/melt. All samples show high radiogenic 207Pb/204Pb(t) (15.41–15.65) and 208Pb/204Pb(t) (37.66–38.51) ratios at given 206Pb/204Pb(t) (17.65–19.00) ratios, consistent with the mantle sources having been metasomatized by ancient slab-derived material. Mafic rocks of the southwest group show enriched Sr–Nd isotopic characteristics, with 87Sr/86Sr(t) ranging from 0.7056 to 0.7071 and εNd(t) ranging from −5.3 to −8.3, indicating an origin from enriched lithospheric mantle. Mafic rocks of the northeast group, which record 87Sr/86Sr(t) ratios of between 0.7044 and 0.7050 and εNd(t) of −2.8 to −0.7, possibly formed by the mixing of melts from isotopically enriched lithospheric mantle and isotopically depleted asthenospheric mantle. Taking into consideration the geochemical and isotopic characteristics of Cretaceous mafic rocks, Cenozoic basalts, and basalt-hosted peridotite xenoliths from the Lower Yangtze region, we propose that an isotopically enriched, subduction-modified lithospheric mantle was replaced by or transformed into an isotopically depleted “oceanic-type” mantle. Such a process appears to have occurred in the eastern North China Craton as well as the eastern Yangtze block, probably in response to subduction of the paleo-Pacific plate beneath East Asia.  相似文献   
964.
思茅盆地晚白垩世勐野井组地层是我国唯一的古代固体钾盐发育地层,由于盆地内部断层纵横,地层横向对比困难,急需有效的标志性地层以完善区域对比及后续研究的深入。本次在确认早白垩世扒沙河组地层良好的区域可对比性基础上,通过对比思茅盆地江城地区两个典型地质露头剖面及勐野井钾盐矿床钻孔岩心的元素地球化学特征探讨了江城地区含盐系地层及其下伏扒沙河组地层的化学风化、构造背景及物源属性特征。结果表明,1)思茅盆地江城地区勐野井组与扒沙河组地层在形成过程中,其物源区均经历了中至强的化学风化作用过程;2)尽管这两套地层间呈不整合接触关系,但在物源属性上二者却均具有混和物源的特性(活动大陆边缘或大陆岛弧背景的长英质物源与被动大陆边缘背景的古老沉积物物源的混合),而扒沙河组地层在沉积过程中可能还受到了少量基性岩物源的影响;3)云南江城勐野井组及其下伏扒沙河组地层的主要物源区可能为哀牢山隆起带和扬子古陆块。  相似文献   
965.
The Late Jurassic deposits of the Boulonnais area (N-France) represents the proximal lateral-equivalent of the Kimmeridge Clay Formation; they accumulated on a clastic-dominated ramp subject to synsedimentary faulting in relation with the northward propagation of the Atlantic rifting. Within the terrigenous accumulations, some carbonate objects are visible at various conspicuous levels: oyster patch reefs and fine-grained carbonate beds, either continuous, or more or less nodular. Preliminary studies demonstrated that the carbonate beds of the Bancs Jumeaux Formation as well as the carbonate matrix of the oyster patch reefs are of diagenetic origin. In this paper, we extend the study to many other limestone beds of the Boulonnais with mud- or wackestone texture, examining facies and microfacies through various techniques as well as geochemical data (O, C and S stable isotopes, major and trace elements). We conclude that all examined carbonate bodies are of early diagenetic origin and that they precipitated at, or close to, the sea bed, from seawater mixing with ascending fluids containing isotopically light carbon of organic origin. Fluid circulation was probably induced by the extensional block-faulting segmentation of the northern margin of the Boulonnais Basin in Late Jurassic times. Fluid seepages were either channelized along fault planes or more diffuse, as illustrated by the model we propose.  相似文献   
966.
Geochemical maps can provide us with much information on geology, earth surface processes and anthropogenic pressure and are valuable tools for ore prospecting and land management. Stream sediments represent an integral of the various possible sources of sediments upstream from the sampling point therefore there can be multiple signal sources but generally the prevailing signal source is the one related to bedrock geology. Stream sediments collected from active second-order channels including singular geological units, were selected in order to determine the geochemical characteristics of each unit. The aim of this study was to analyze their potential for using them to integrate geological interpretation and produce a geologically-oriented geochemical map. From the 770 samples collected for a regional geochemical mapping program, we selected 149 samples whose catchment basin included only one of the members recognized within the Marnoso-arenacea formation. This middle–upper Miocene (Langhian–Tortonian) turbiditic unit forms the backbone of the Romagna Apennines and has been subdivided into 14 members according to age and lithostratigraphic criteria. The results indicate that there are marked differences in the composition of the members of the Marnoso arenecea formation which indicate the provenance of the sediment and the palaeogeographic evolution of the units. By means of univariate and multivariate statistical analyses (Factor analyzes) two main types of sediment compositions are identified: Tortonian members are characterized by sialic coarse grain-sediments while the Langhian–Serravallian members are richer in carbonate fraction, slightly enriched in a mafic contribution. This study elaborated the geochemical data from a geological point of view by integrating the information available in literature to spatially extend the interpretation based on limited site observation as for petrographic studies. In general, the geochemical map based on a geological unit could be a useful tool for carrying out the geological reconstruction of a complex area.  相似文献   
967.
西藏雅鲁藏布蛇绿岩带中段日喀则地区的白朗蛇绿混杂岩中,存在作为变质底板的石榴角闪岩。本文对其进行了矿物学、变质温压条件和岩石地球化学研究。根据岩相学和矿物化学研究,日喀则石榴角闪岩经历了四个变质阶段,矿物组合分别为:Am_1+Pl_1+Ep_1+Ttn(M1);Grt-c+Cpx-e+Ep_2+Pl_2+Rt(M2);Grt-r+Ep_3/Czo_3+Cpx-l+Am_3+Pl_3+Ttn(M3)和Prh+Ab+Czo+Chl+Cal(M4)。根据SAFMCNHO体系矿物组合演化的视剖面图,结合传统的地质温压计,估算出峰期前的温压条件为560~620℃/9.1~9.8kbar;峰值为830~870℃/18.0~22.0kbar,退变质阶段保留了640~680℃/10.7~14.9kbar的温压条件,最终止于葡萄石-绿纤石的前绿片岩相变质条件;得出一条逆时针的P-T轨迹。白朗变质底板的岩性可分为三类,即石榴角闪岩、角闪辉石岩和单辉角闪岩。三种岩性具有相似的地球化学性质:主量元素具有低钛(0.92%~1.29%)、低钾(0.26%)、低钠(0.24%~2.46%)的特征。稀土元素和微量元素特征与N-MROB相似,富集大离子亲石元素(Rb、Ba、U),亏损部分高场强元素(Nb、Ti、Zr、Hf),表现出白朗蛇绿混杂岩中的石榴角闪岩等与洋中脊玄武岩有亲缘性,且叠加有俯冲上板片SSZ环境特征。白朗石榴角闪岩的存在表明日喀则蛇绿岩在形成后不久就发生了构造就位,体现了大洋内部俯冲/侵位事件。  相似文献   
968.
The Lakange porphyry Cu–Mo deposit within the Gangdese metallogenic belt of Tibet is located in the southern–central part of the eastern Lhasa block, in the Tibetan Tethyan tectonic domain. This deposit is one of the largest identified by a joint Qinghai–Tibetan Plateau geological survey project undertaken in recent years. Here, we present the results of the systematic logging of drillholes and provide new petrological, zircon U–Pb age, and molybdenite Re–Os age data for the deposit. The ore‐bearing porphyritic granodiorite contains elevated concentrations of silica and alkali elements but low concentrations of MgO and CaO. It is metaluminous to weakly peraluminous and has A/CNK values of 0.90–1.01. The samples contain low total REE concentrations and show light REE/heavy REE (LREE/HREE) ratios of 17.51–19.77 and (La/Yb)N values of 29.65–41.05. The intrusion is enriched in the large‐ion lithophile elements (LILE) and depleted in the HREE and high field‐strength elements (HFSE). The ore‐bearing porphyritic granodiorite yielded a Miocene zircon U–Pb crystallization age of 13.58 ± 0.42 Ma, whereas the mineralization within the Lakange deposit yielded Miocene molybdenite Re–Os ages of 13.20 ± 0.20 and 13.64 ± 0.21, with a weighted mean of 13.38 ± 0.15 Ma and an isochron age of 13.12 ± 0.44 Ma. This indicates that the crystallization and mineralization of the Lakange porphyry were contemporaneous. The ore‐bearing porphyritic granodiorite yielded zircon εHf(t) values between ?3.99 and 4.49 (mean, ?0.14) and two‐stage model ages between 1349 and 808 Myr (mean, 1103 Myr). The molybdenite within the deposit contains 343.6–835.7 ppm Re (mean, 557.8 ppm). These data indicate that the mineralized porphyritic granodiorite within the Lakange deposit is adakitic and formed from parental magmas derived mainly from juvenile crustal material that partly mixed with older continental crust during the evolution of the magmas. The Lakange porphyry Cu–Mo deposit and numerous associated porphyry–skarn deposits in the eastern Gangdese porphyry copper belt (17–13 Ma) formed in an extensional tectonic setting during the India–Asia continental collision.  相似文献   
969.
宜章界牌岭锡多金属矿床地球化学异常模式   总被引:6,自引:0,他引:6  
界牌岭锡多金属矿床是一个与浅源重熔花岗岩有关的热液多金属隐伏矿床。研究表明:矿床自上至下具有F-Be-Pb、Zn-Pb-Sn、Cu-Nb、Ta、TR的矿化分带和细脉状-层状(似层状)-面状的矿体形态分带,成晕具有Hg、B、Ba、Cr、As离心半环状晕-F、Be、Li、Pb、Ag同心环状上偏心晕-Sn、Cu、Zn、同心环状下偏心晕-Nb、Ga离心卫星晕的分布规律。据此,建立了本矿床“三环-帽壳式”地球化学异常模式。经模式识别,总结了不同剥蚀程度矿床(浅,中,深)异常评价的地质-地球化学指标。  相似文献   
970.
系统介绍了近年来地幔同位素地球化学的研究进展,概述了Sr-Nd-Hf-Pb、Os、He-Ar和Ne同位素在的岩石示踪和成因鉴别上所取得的成果,指出同位素在地幔岩石研究的重要作用,简要总结了全球及区域地幔成分的主要研究手段和某些全球均一化比值的意义;并提出了分析技术的落后和基础理论的停滞是影响同位素和微量元素在地幔研究中应用和发展的主要因素。  相似文献   
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