The influence of light intensity,SO2, NOx and C3H6 on sulfate aerosol formation     

Menachem Luria  Geula Sharf 《Journal of Atmospheric Chemistry》1985,2(3):321-329

The photochemical oxidation of SO₂ in the presence of NO and C₃H₆ was studied in a 18.2 liter pyrex reactor. When light intensity, irradiation time and SO₂ concentration were constant, SO₄ ^2- concentration, derived from the total volume of aerosol produced, peaked when [C₃H₆]/[NO] was approximately 6.0. Another increase im SO₄ ^2- formation was reached at very high ratios (>50). The experimental observations are consistent with the two SO₂ oxidation mechanisms. At low [C₃H₆]/[NO] ratios, the processes proceed via the HO–SO₂ reaction, while at high ratios the O₃–C₃H₆ adduct is assumed to oxidize SO₂ to produce SO₄ ^2- aerosols.  相似文献   

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients     

W. Kirchner  F. Welter  A. Bongartz  J. Kames  S. Schweighoefer  U. Schurath 《Journal of Atmospheric Chemistry》1990,10(4):427-449

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.  相似文献   

变刚度钢管混凝土短柱隔震结构弹塑性动力分析     

张玉良  成世峰  张铜生 《震灾防御技术》2006,1(2):129-136

采用HBTA2.5程序,对一变刚度钢管混凝土短柱隔震结构进行了弹塑性时程分析。分析结果表明,其隔震装置的水平变形和耗能能力可以大大减轻地震对结构的影响。提出钢管混凝土短柱隔震结构在工程应用将有很好的发展前景。  相似文献   

伪三维地震勘探法在煤田勘查中的应用     

李金花  李建国 《中国煤田地质》2007,19(1):63-65

勘探区属郭庄煤矿的后备井田，勘探的目的是掌握井田主可采煤层的赋存形态与断层、陷落柱发育特征。根据勘探区的地质条件，地质任务，兼顾质量和成本，勘探设计方案最终确定为3线1炮制线束状观测系统，采用中间放炮，使勘探物理点由常规二维设计的3000个减至700个，勘探成本明显降低。勘探前后的资料对比分析表明，3#煤层的展布特征和断层构造有较大不同，其中3#煤层展布形态由NE向变化均匀，两翼对称的背斜构造修改为等高线变化扭曲相对剧烈，两翼对称的向斜构造；勘探后新解释断层5条，断点3处，另外3条已知断层的形态、位置、落差等相差各异。  相似文献   

活性炭负载磷钨酸催化合成氯乙酸乙二醇双酯     

陈中胜  许文苑  黄国林  梁喜珍 《华东地质学院学报》2007,30(1):67-69

以氯乙酸、乙二醇为原料,活性炭负载磷钨酸为催化剂合成了氯乙酸乙二醇双酯,并根据酸醇摩尔比、催化剂用量、反应时间及带水剂苯加入量等条件对反应的影响,确定了最佳反应条件。测定了产物的熔点,用IR对产物的结构进行了表征。结果表明,活性炭负载磷钨酸是合成氯乙酸乙二醇双酯的良好催化剂,且可重复利用多次。  相似文献   

Na2O对高铝粉煤灰合成莫来石的影响     

魏尊莉  李金洪  邢净 《矿物岩石地球化学通报》2007,26(2):176-180

本文研究了Na2O添加量和烧结温度对粉煤灰合成莫来石材料性能、晶体结构和显微形貌的影响。结果表明,Na2O可较大辐度降低粉煤灰合成莫来石的温度。在1300℃,Na2O添加至2%时,生成的莫来石细小,含量较高,但试样强度不高;Na2O添至4%时,莫来石发育为长柱状,长径比约8～12,并且相互交错成网状,材料的机械强度较高,抗折强度为97.71MPa,莫来石相对含量为76.1%;Na2O添加至8%时,莫来石含量明显减少,晶形变为不规则状。在一定范围内,材料的体积密度、烧成线收缩率和抗折强度均随温度的升高而增大,莫来石含量也相应增多。  相似文献   

Interactions between basalts and oil source rocks in rift basins： CO2 generation     

金强  许丽  万从礼  曾怡 《中国地球化学学报》2007,26(1):58-65

Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China.  相似文献   

北太平洋对人为二氧化碳吸收的数值模拟   总被引：3，自引：0，他引：3       下载免费PDF全文

徐永福  赵亮  李阳春 《地球物理学报》2007,50(2):404-411

采用一个开边界海盆尺度环流模式研究人为CO2在北太平洋的吸收和分布，并与闭边界模式的模拟结果进行了比较.模拟结果表明，西北太平洋和赤道东太平洋是两个重要的人为CO2汇.使用较大的等密度面扩散系数使得西北太平洋人为CO2通量增大，而赤道海区通量减小（RUN2）.与闭边界模式相比，开边界模式中该两个区域的人为CO2通量都增加了.1800～1997年间，北太平洋共吸收人为CO2 2375GtC(1Gt=1×1015 g, RUN1).副极地海区是人为CO2的一个重要输出区，能输出人为CO2吸收量的38％～54％，而20°N～30°N海区是人为CO2的一个重要贮存区，占整个北太平洋的24％.开边界对于10°N以南太平洋吸收和贮存人为CO2有很大影响.与基于观测资料的估计相比，虽然模式低估了西北太平洋的人为CO2的穿透，高估了东北太平洋的人为CO2的穿透，但总的说来，模式比较好地估计了人为CO2在北太平洋的贮存.  相似文献   

DWEPP: a dynamic soil erosion model based on WEPP source terms     

N. S. Bulygina  M. A. Nearing  J. J. Stone  M. H. Nichols 《地球表面变化过程与地形》2007,32(7):998-1012

  相似文献   

MM5对末次盛冰期中国气候的模拟研究Ⅰ:CO2和地球轨道参数的影响     

刘煜何金海  李维亮陈隆勋 《气象学报》2007,65(2):139-150

通过模式结果与实况资料和地质记录对比,表明模式系统可以较好地模拟现代气候状况和末次盛冰期气候的变化,特别是降水的变化与地质记录符合得较好。在末次盛冰期和现代气候状况下地球轨道参数的变化对中国地区年平均温度的影响很小,但对不同季节温度变化的作用不同。冬季气温的变化比较显著,不能忽略。CO2浓度在末次盛冰期最低,其混合比为200×10-6,这使得气温降低。CO2的作用也存在明显的季节和区域特征。冬季其影响最大;但夏季其作用较小,甚至出现CO2浓度减少温度增加的现象。产生增温现象的原因是云量发生了变化,使到达地面的太阳辐射增加。这个结果表明云在气候变化中,可能起着非常重要的作用,甚至可以影响某时段和区域温度等要素变化的方向。青藏高原地区对这两个辐射因子变化的响应与中国其他地区相比偏小,原因是该地区的云量高于其他地区。相对现代气候,末次盛冰期地球轨道参数变化对气候的影响小于CO2的作用。但相对于末次盛冰期气候的变化,这两个因子的贡献都是比较小的。CO2对末次盛冰期年平均温度变化的贡献大约为3%—10%。此外,现代和末次盛冰期气候背景下,CO2的作用相同。  相似文献