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1.
Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.  相似文献   
2.
南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(Ipy)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(Opy)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ34S 平均为-37.8‰,外圈层中 δ34S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   
3.
查岗诺尔铁矿是新疆西天山阿吾拉勒铁矿带内的重要大型铁矿床之一。矿体赋存在下石炭统大哈拉军山组安山质火山岩中,与普遍发育的石榴子石化、阳起石化和绿帘石化时空关系密切。石榴子石和绿帘石分属不同热液成矿阶段,它们均发育丰富的环带结构,具体表现为明显地颜色、干涉色、背散射图像及成分(FeO、Al2O3、SiO2、MnO、TiO2)等差异性。石榴子石具有2个世代、3个类型。早世代石榴子石(Grt1和Grt2)产于块状石榴子石-磁铁矿蚀变岩,呈褐黄色,粒度较细,发育核-边结构,呈非均质性,显示异常干涉色,其核部(Grt1-c)均匀相对富钙铝榴石(Gro51-53And41-43Spr4-8),而边部(Grt1-r)发育振荡成分环带,总体相对富钙铁榴石(Gro18-35And60-77Spr4-6);Grt2核部(Grt2-c)呈均质性,为钙铁榴石(And99-100Spr0-1),边部显异常干涉色,发育振荡成分环带,为钙铝铁榴石(Gro34-54And38-61Spr6-9)。晚世代的石榴子石(Grt3)以细脉状或角砾胶结物形式分布,呈红褐色,自形粗粒结构,显非均质性,发育振荡成分环带,端员组分总体以钙铁榴石为主,次为钙铝榴石(Gro27-43And50-68Spr3-8)。石榴子石结构和元素含量变化表明,早期石榴子石形成于弱氧化-氧化、中性-碱性流体体系,其中向边部生长过程,由于新注入流体以及周期性压力汇聚和释放,体系的氧逸度、pH值呈振荡变化;晚期石榴子石形成于弱氧化、弱碱性、动荡的开放流体环境。绿帘石发育3个世代(Ep1、Ep2和Ep3)。Ep1发育核-边结构,核部(Ep1-c)均匀无环带,XFe值(XFe=Fe3+/(Al+Fe3+),原子比值)为0.19~0.21,w(MnO)为0.05%~0.18%,w(TiO2)为0.10%~0.12%,生长边(Ep1-r)多发育振荡环带,XFe值为0.26~0.29,w(MnO)为0.01%~0.14%,w(TiO2)为0.19%~0.26%。Ep2沿Ep1-r边缘生长,不均匀且经历了溶解-再沉淀过程,XFe值为0.15~0.20,w(MnO)为0.42%~1.19%,w(TiO2)为0.02%~0.07%。Ep3呈柱状或不规则粒状交代Ep2、贴近或穿切Ep1-r生长,较均匀、无环带结构,XFe值为0.28~0.37,w(MnO)为0.12%~0.77%,w(TiO2)为0.02%~0.10%。绿帘石成分变化表明,从Ep1-c到Ep1-r,到Ep2,再到Ep3,流体体系氧逸度经历了先增加,后降低,再升高的变化过程。同时,流体成分也在变化,先从相对贫Ti和Mn向相对富Ti贫Mn演化,而后又变为富Mn贫Ti。因此,在热液磁铁矿矿化阶段,查岗诺尔铁矿的成矿热液的物理-化学环境是不断变化的。研究显示,石榴子石和绿帘石结构和成分研究可以刻画热液成矿系统的流体演化历史。  相似文献   
4.
为真实了解天津市公众地震科普认知与需求情况,以天津市机关单位工作人员、企业员工、事业单位工作人员、大学生、中小学生、社区居民、农民、驻津部队、残障人士等特殊人群为研究对象,开展专项问卷调查与分析。调查结果显示,天津市公众地震科学知识与地震科普工作的认知度与需求度较高,但仍存在地震科学知识掌握不全面、地震科普产品吸引力不足、科普渠道相对单一等问题,地震科普工作在参与性、互动性与趣味性等方面仍有较大提升空间。基于此,提出提高地震科普工作针对性和有效性及地震科普服务个性化和精准化等建议。  相似文献   
5.
Wan  Bo  Wu  Fuyuan  Chen  Ling  Zhao  Liang  Liang  Xiaofeng  Xiao  Wenjiao  Zhu  Rixiang 《中国科学:地球科学(英文版)》2019,62(12):2005-2016
Numerous continents have rifted and drifted away from Gondwana to repeatedly open ocean basins over the past-500 millionyears.These Gondwana-derived continents drifted towards and collided with components of the Eurasian continent to successively close the preexisting oceans between the two.Plate tectonics satisfactorily describes the continental drift from Gondwana to Eurasia but does not define the geodynamic mechanism of continuously rifting to collisions of continents in the Tethy an Realm.After reappraisal of geological records of the rift,collision and subduction initiation from the surface and various geophysical observations from depth,we propose that Eurasia-directed subducting oceanic slabs would have driven Tethyan system in the Phanerozoic.The Eurasia-directed subduction would have dragged the passive Gondwana margin to rift and drift northwards,giving birth to new oceans since the Paleozoic.The closure of preexisting oceans between the Gondwana-derived continents and Eurasia led to continental collisions,which would have induced the initiation of oceanic subduction in the Tethyan Realm.Multiple episodic switches between collision-subduction-rift repeatedly led to the separation of continental fragments from Gondwana and dragged them to drift towards Eurasia.The final disappearance of Neo-Tethy s would have induced collision of the Gondwana-derived continents with the Eurasian continent,giving rise to the Cenozoic Alpine-Zagros-Himalayan collisional system.Therefore,the Eurasia-directed oceanic subduction would have acted as a 'one-way train' that successively transferred the ruptured Gondwana continental fragments in the south,into the terminal in the north.In this regard,the engine of this "Tethyan one-way train" is the negative buoyancy of subducting oceanic slabs.  相似文献   
6.
The extracellular polysaccharide hydrolase-producing strain EP-1 was isolated from seawater and identified as Paenibacillus pabuli. Furthermore, a homogeneous extracellular polysaccharide hydrolase from Paenibacillus pabuli EP-1 was purified by combining ion-exchange chromatography and size exclusion chromatography with a purification fold of 90.69 and recovery of 16.23%. Characterization of the purified polysaccharide hydrolase revealed a molecular mass of 38 k Da and optimum activity at 45℃ and pH 6.0. The polysaccharide hydrolase maintained its stability within a wide range of pH(3.0–12.0) and thermal stability when the temperature was below 50℃. The presence of Hg~(2+), Fe~(2+), Mn~(2+), Co~(2+) and SDS notably decreased hydrolase activity, and organic solvents such as formaldehyde, acetone, DMF and acetonitrile completely inhibited hydrolase activity. The purified hydrolase had no activity on agar, carrageenan, gellan gum, sodium alginate, or starch, but effectively hydrolyzed the polysaccharide from Ulva prolifera. The Km and Vmax values of this hydrolase were 43.84 mg m L~(-1) and 4.33 mg m L~(-1) min~(-1), respectively. The sequence analysis with quantitative time-of-flight mass spectrometry indicated that the hydrolase was an endoglucanase.  相似文献   
7.
In the seismic event classification,determining the seismic features of rockfall is significantly important for the automatic classification of seismic events because of the huge amount of raw data recorded by seismic stations in continuous monitoring. At the same time, the rockfall seismic features are still not completely understood.This study concentrates on the rockfall frequency content, amplitude(ground velocity), seismic waveform and duration analysis, of an artificial rockfall test at Torgiovannetto(a former quarry in Central Italy). A total of 90 blocks were released in the test, and their seismic signals and moving trajectories were recorded by four tri-axial seismic stations and four cameras, respectively. In the analysis processing,all the artificial rockfall signal traces were cut separately and the seismic features were extracted individually and automatically. In this study, the relationships between a) frequency content and impacted materials, b) frequency content and the distance between block releasing position and seismic station(source-receiver distance) were discussed. As a result, we found that the frequency content of rockfall focuses on 10-60 Hz and 80-90 Hz within a source-receiver distance of 200 m, and it is well correlated with impacted material and source-receiver distance. To evaluate the difference between earthquake and rockfall, 23 clear earthquake signals recorded in a seven month-long continuous seismic monitoring, carried out with the four seismic stations, were picked out, according to the Italian national earthquakes database(INGV). On these traces we performed the same analysis as in the artificial rockfall traces, and two parameters were defined to separate rockfall events from earthquake noise. The first one, the amplitude ratio, is related to the amplitude variation of rockfall between two stations and is greater than that of earthquakes, because of the higher attenuation occurring for rockfall events, which consists in high frequencies whereas for earthquakes it consists in low frequencies. The other parameter, the shape of waveform of signal trace, showed a significant difference between rockfall and earthquake and that could be a complementary feature to discriminate between both. This analysis of artificial rockfall is a first step helpful to understand the seismic characteristics of rockfall, and useful for rockfall seismic events classification in seismic monitoring of slope.  相似文献   
8.
采用对角斜撑模拟纵向填充墙的作用,建立考虑填充墙和不考虑填充墙厂房结构模型,采用拉丁超立方抽样技术建立考虑材料不确定性的结构分析样本,基于随机Pushover分析确定结构不同破坏状态下的统计参数。综合考虑结构材料强度及输入地震动不确定性的影响,通过非线性时程分析开展单层钢筋混凝土厂房结构易损性研究,在此基础上比较结构横、纵向易损性的差异,研究填充墙对结构易损性的影响。研究结果表明:钢筋混凝土厂房结构体系横向地震易损性显著大于纵向地震易损性;对纵向结构体系而言,加入填充墙会明显降低结构易损性,但在相同强度的地震动作用下,填充墙破坏程度比主体结构严重,这与厂房结构的实际震害特征相符。  相似文献   
9.
甲玛矿床位于冈底斯成矿带东段,是西藏地区最大的铜多金属矿床之一。磁黄铁矿是甲玛矿床最常见的金属矿物之一,其标型特征不仅反映其自身形成环境,对其形成机制和矿床成因也具有指示意义。文章选取产于不同岩性中的磁黄铁矿矿石样品,利用矿相学、X射线衍射和电子探针分析等手段对磁黄铁矿的形态、成分和结构进行了分析研究。研究表明,甲玛矿床的磁黄铁矿主要分布在距离岩体中心较远的矿区远端矽卡岩和角岩中。磁黄铁矿的晶胞参数和粉晶X射线衍射曲线显示矽卡岩中的磁黄铁矿主要为高温六方磁黄铁矿,角岩中的磁黄铁矿为高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体,但主要以低温单斜磁黄铁矿为主。通过对矽卡岩和角岩中的磁黄铁矿进行电子探针测试,结果显示:矽卡岩中的磁黄铁矿中w(Fe)为60.09%~60.71%,平均为60.38%,w(S)为38.18%~38.69%,平均38.35%,化学分子式为Fe_8S_9~Fe_(10)S_(11);角岩中的磁黄铁矿中w(Fe)为59.05%~59.57%,平均为59.10%,w(S)为39.28%~39.95%,平均39.59%,化学分子式为Fe_5S_6~Fe_7S_8。根据以上矿物学特征,笔者进一步探讨了该矿床磁黄铁矿的沉淀机制:炽热的岩浆热液上涌,与碳酸盐岩地层和碎屑岩地层接触发生相互作用,并有大气水的加入,使得成矿流体在角岩中先快速降温,形成高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体。同时,大量的含矿热液形成,并充填于有利的成矿空间(主要为层间破碎带)沉淀成矿,形成矽卡岩矿体,然后流体在矽卡岩矿段中经历缓慢降温,形成高温六方磁黄铁矿。结合矿床地质特征和相关元素地球化学特征,认为甲玛矿床类型为斑岩-矽卡岩型。  相似文献   
10.
Liu  Ping  Li  Ning  Ma  Hua  Xie  Lili  Zhou  Baofeng 《地震工程与工程振动(英文版)》2020,19(1):1-16
Pulse-like ground motions are capable of inflicting significant damage to structures. Efficient classification of pulse-like ground motion is of great importance when performing the seismic assessment in near-fault regions. In this study, a new method for identifying the velocity pulses is proposed, based on different trends of two parameters: the short-time energy and the short-time zero crossing rate of a ground motion record. A new pulse indicator, the relative energy zero ratio(REZR), is defined to qualitatively identify pulse-like features. The threshold for pulse-like ground motions is derived and compared with two other identification methods through statistical analysis. The proposed procedure not only shows good accuracy and efficiency when identifying pulse-like ground motions but also exhibits good performance for classifying records with high-frequency noise and discontinuous pulses. The REZR method does not require a waveform formula to express and fit the potential velocity pulses; it is a purely signal-based classification method. Finally, the proposed procedure is used to evaluate the contribution of pulse-like motions to the total input energy of a seismic record, which dramatically increases the seismic damage potential.  相似文献   
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