菲与纳米银对胶州湾表层沉积物反硝化作用的复合毒性效应评价     

孙鹏飞  白洁  李岿然  白晓岩  田延昭  赵阳国 《中国海洋大学学报(自然科学版)》2020,(1):104-114

多环芳烃(PAHs)与纳米材料污染已对沉积物生态系统和人类生存环境构成严重威胁,其复合污染的毒性效应环境危害可能更大。为了深入探讨PAHs与纳米材料对近岸表层沉积物反硝化作用的复合毒性效应,本文选取位于胶州湾(JZB)的大沽河河口区(DRE)E站和湾内S站,分别以菲和纳米银代表PAHs和纳米材料,通过测定不同剂量单一及复合污染下沉积物反硝化潜势(PDA)的变化,结合浓度相加模型(CA)、独立作用模型(IA)和中效/联合指数等效图法(CI)三种复合毒性评价方法,评价菲和纳米银对沉积物反硝化潜势的复合毒性效应,并对评价方法进行了优选。结果表明,两种污染物浓度越高,对研究区域反硝化潜势的抑制作用越大。菲、纳米银单一及复合作用下对河口区沉积物反硝化潜势的EC50值分别为44.62、112.49和64.86 mg·kg-1,对湾内分别为61.79、147.05和96.18 mg·kg-1。菲单一作用对反硝化潜势的抑制效应强于纳米银,但复合污染的抑制效应更强。两种污染物对河口区的沉积物反硝化潜势抑制效应强于湾内,可能与河口区具有较高Eh和沉积物颗粒度及较低的pH、盐度和有机质含量有关。三种毒性效应评价方法的结果表明,菲和纳米银的复合污染对2个站位反硝化潜势的毒性效应均为协同作用,且对大沽河河口区的协同作用更强。此外,CI法对复合效应的预测结果比CA和IA法更为接近实际观测值,且CI不需要考虑污染物作用模式的限制,因此认为CI法更适用于评价混合污染对沉积物反硝化作用复合影响的效果。本研究结果表明,菲和纳米银会增强彼此对反硝化菌及反硝化功能的毒性效应,由此推断,PAHs和纳米材料在环境中同时存在时比其单独存在对沉积环境的危害更大。  相似文献   

A synthesis of iron deposits in the eastern Tianshan,NW China     

《地学前缘(英文版)》2020,11(4):1271-1287

The northern Xinjiang region is one of the most significant iron metallogenic provinces in China.Iron deposits are found mainly within three regions:the Altay,western Tianshan,and eastern Tianshan orogenic belts.Previous studies have elaborated on the genesis of Fe deposits in the Altay orogenic belt and western Tianshan.However,the geological characteristics and mineralization history of iron deposits in the eastern Tianshan are still poorly understood.In this paper I describe the geological characteristics of iron deposits in the eastern Tianshan,and discuss their genetic types as well as metallogenic-tectonic settings,Iron deposits are preferentially distributed in central and southern parts of the eastern Tianshan.The known iron deposits in the eastern Tianshan show characteristics of magmatic Fe-Ti-V(e.g.,Weiya and Niumaoquan),sedimentary-metamorphic type(e.g.,Tianhu),and iron skarn(e.g.,Hongyuntan).In addition to the abovementioned iron deposits,many iron deposits in the eastern Tianshan are hosted in submarine volcanic rocks with well-developed skarn mineral assemblages.Their geological characteristics and magnetite compositions suggest that they may belong to distal skarns.SIMS zircon U-Pb analyses suggest that the Fe-Ti oxide ores from Niumaoquan and Weiya deposits were formed at 307.7±1.3 Ma and 242.7±1.9 Ma,respectively.Combined with available isotopic age data,the timing of Fe mineralization in the eastern Tianshan can be divided into four broad intervals:Early Ordovician-Early Silurian(476-438 Ma),Carboniferous(335-303 Ma),Early Permian(295-282 Ma),and Triassic(ca.243 Ma).Each of these episodes corresponds to a period of subduction,post-collision,and intraplate tectonics during the Paleozoic and Mesozoic time.  相似文献   

基于FLAC3D数值模拟的清徐地裂缝与交城断裂成因关系研究     

曾金艳  李自红  陈文 《震灾防御技术》2020,15(1):114-122

基于断裂力学理论，应用FLAC3D数值模拟方法对交城断裂活动时附近土体的变形特征进行模拟计算。计算结果表明:断层活动带动上覆土层差异沉降及应力场变化，当断层错动量达到一定程度，断层附近出现拉应力区，土体在拉张应力和自身重力作用下产生垂直差异形变，从而产生地裂缝。将数值模拟结果与方山探槽揭示的地裂缝剖面特征进行对比，二者结果相互印证，说明清徐地裂缝是交城断裂活动的结果，二者具有明显的对应关系，地裂缝为构造成因裂缝。数值模拟结果为研究断裂和地裂缝成因关系提供了佐证。  相似文献   

基于匹配追踪和遗传算法的大地电磁噪声压制   总被引：1，自引：0，他引：1       下载免费PDF全文

李晋  燕欢  汤井田  张贤  李广  朱会杰 《地球物理学报》2018,61(7):3086-3101

针对匹配追踪计算量大、大地电磁数据处理效率低的问题，提出基于匹配追踪和遗传算法的大地电磁噪声压制方法.首先，利用Gabor原子构建过完备原子库，并对过完备原子库集合进行划分.然后，借助遗传算法的自适应性，快速搜寻最优匹配原子及所在位置.最后，运用最优匹配原子对待处理信号进行稀疏分解，重构有用信号.通过对计算机模拟的典型强干扰和矿集区实测大地电磁数据进行分析处理，实验结果表明，相对于匹配追踪和正交匹配追踪，文中所提方法能从过完备原子库中快速、自适应地选取最优匹配原子与不同噪声干扰类型高精度的匹配，极大地提升了计算效率；大地电磁时间域序列中的大尺度强干扰被有效剔除，视电阻率曲线更为光滑、连续，低频段的数据质量得到明显改善.  相似文献   

Assessing model of highway slope stability based on optimized SVM     

《China Geology》2020,3(2):339-344

Considering the geological hazards attributed to the highway slope, using a common simple model cannot accurately assess the stability of the slope. First, principal component analysis (PCA) was conducted to extract the principal components of six factors (namely, bulk density, cohesion, internal friction angle, slope angle, slope height, and pore water pressure ratio) affecting the slope stability. Second, four principal components were adopted as input variables of the support vector machine (SVM) model optimized by genetic algorithm (GA). The output variable was slope stability. Lastly, the assessing model of highway slope stability based on PCA-GA-SVM is established. The maximal absolute error of the model is 0.0921 and the maximal relative error is 9.21% by comparing the assessment value and the practical value of the test sample. The above studies are conducive to enrich the assessing model of highway slope stability and provide some reference for highway slope engineering treatment.  相似文献   

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD     

Li Q.  Bao Z. 《大地构造与成矿学》2018,(4):699-717

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.  相似文献   

Effects of Environmental Cadmium on Cadmium Accumulation,Oxidative Response,and Microelements Regulation in the Liver and Kidney of Hexagrammos otakii     

HU Fawen  SUN Ming  LI Li  GAO Fengxiang  JIAN Yuxia  WANG Xue  WANG Xiaolong  GUO Wen 《中国海洋大学学报(英文版)》2022,21(2):479-485

The effects of cadmium(Cd)on metal accumulation,microelements contents,and antioxidant responses in Hexagram-mos otakii were studied.The fish were exposed to 0.2,2.5,or 10μg L?1 Cd for 12 or 24 days.Then,the concentration of Cd and mi-croelements(Ca,Fe,Zn,and Se)were determined in the liver and kidney.Moreover,the activities of antioxidant enzymes including superoxide dismutase(SOD),catalase(CAT),and glutathione-S-transferase(GST),and the content of malondialdehyde(MDA)in the liver and kidney were also measured.A continuous accumulation of Cd was observed throughout the experimental period.Cd accumulation was higher in liver than that in the kidney,while Ca and Fe contents were lower in liver than those in the kidney.Cd exposure resulted in a decrease of Ca and Fe concentrations in the kidney,while there was no effect on the liver.Zn and Se remained unaffected with exposure to Cd.Cd exposure induced severe oxidative stress in H.otakii,as indicated by significant induction of the activities of SOD,CAT,and GST,and a simultaneous increase of MDA content.These data show that antioxidant enzymes and mi-croelements contents can be used as potential biomarkers to monitor environmental health in fish.  相似文献   

氨氮急性攻毒对水产经济动物棘胸蛙(Paa spinosa)蝌蚪死亡率、排氨率、耗氧率及窒息点的影响     

牛春格  杨程  申屠琰  郑晓静  王志铮 《海洋与湖沼》2019,50(1):188-196

以体长(1.932±0.204)cm、体质量(1.386±0.055)g的棘胸蛙蝌蚪为实验动物,在水温(24±0.2)℃、DO(7.30±0.01)mg/L、pH 7.30±0.01条件下,采用静水停食法开展了氨氮对蝌蚪的急性攻毒实验,并以此为基础,测定了不同氨氮质量浓度胁迫下棘胸蛙蝌蚪的排氨率、耗氧率、氧氮比及窒息点。结果表明:(1)蝌蚪对氨氮急性攻毒具明显的运动避毒行为,濒死个体的背部皮肤和肝脏均具明显的色变症状;(2)氨氮对蝌蚪的急性致死率具明显的剂量—时间效应,24h、48h、72h、96h LC50依次为177.5、151.7、148.6和146.8mg/L,毒性时段蓄积程度系数呈持续下降趋势,24—48h、48—72h、72—96h的时段MAC值分别为84.04%、10.1%和5.86%;(3)蝌蚪夜均、昼均、日均及时段排氨率随氨氮质量浓度增加均呈阶梯式下降趋势,其中时段排氨率与对照组均无显著差异的为9.80mg/L实验组,夜均、昼均、日均及时段排氨率与对照组均无显著差异的仅为2.45mg/L实验组(P0.05);(4)氨氮对蝌蚪呼吸耗氧具低毒兴奋效应,其夜均、昼均和日均耗氧率随氨氮质量浓度增加均呈先升后降趋势,峰值氨氮质量浓度范围均为4.90—7.35mg/L(P0.05),与对照组均无显著差异的仅为14.70mg/L实验组(P0.05),窒息点含氧量随氨氮质量浓度增加呈先降后升趋势,谷底出现于4.90mg/L实验组(P0.05),与对照组无显著差异的仅为9.80mg/L实验组(P0.05);(5)实验期间,蝌蚪氧氮比(O:N)波动于18.87—25.34之间,昼均和日均氧氮比(O:N)随氨氮质量浓度增加均依次呈"上升—稳定—下降—再稳定"之趋势,两者的峰值氨氮质量浓度范围分别为4.90—14.70mg/L和4.90—9.80mg/L,夜均氧氮比(O:N)呈先升后降趋势,峰值出现于7.35mg/L实验组(P0.05)。  相似文献   

苯并（a）芘诱导下岩虫CYP基因的表达特征     

李婉娟  赵欢  Ba Fuyang  李绍娟  孙秀鹏  杨大佐  周一兵 《海洋学报(英文版)》2019,38(6):46-53

Rapid amplification of cDNA ends(RACE) and real-time polymerase chain reaction(RT-PCR) were carried out to analyze the CYP4 gene expression in polychaete Marphysa sanguinea exposed to benzo[a]pyrene(BaP) in this study. The full length of MsCYP4 cDNA was 2 470 bp, and it encoded 512 amino acids. The deduced amino acid sequence showed 47% identity with CYP4 F from frog Xenopus tropicalis and shared high homology with other known CYP4 sequences. To analyse the role of CYP4 in protecting M. sanguinea from BaP exposure, three BaP groups were established: 0.5, 5 and 50 μg/L. Polychaetes were sampled after 3, 7 and 12 d. At 0.5 μg/L, the effect of BaP on MsCYP4 gene expression increased with time prolonged. MsCYP4 gene expression curve showed Ushaped trend with time in 5 and 50 μg/L BaP groups. Therefore, MsCYP4 gene may play an important role in maintaining the balance of cellular metabolism and protecting M. sanguinea from BaP toxicity.  相似文献   

文莱-沙巴盆地深水褶皱冲断带构造变形特征及成因机制          下载免费PDF全文

唐武  赵志刚  张功成  谢晓军  刘世翔  王一博  宋双  王龙  孙瑞  郭佳 《地球物理学报》2018,61(10):4281-4295

为揭示活动陆缘深水褶皱冲断带的特征及成因，本文利用地震和区域地质资料的综合分析，系统阐述了文莱—沙巴盆地深水褶皱冲断带的构造变形特征，并结合盆地演化动力学特点，探讨其构造变形机制及其对深水区油气成藏的影响.研究结果表明，文莱—沙巴盆地深水褶皱冲断带具有"垂向分期、平面分段"的特点，垂向上，以中中新统底界面为界可划分为下部（始新世-早中新世）和上部（中中新世-现今）两套逆冲褶皱冲断体系，其中下部逆冲褶皱冲断带的形成与古南海的俯冲作用密切相关，上部逆冲褶皱冲断带是中中新世以来三角洲前缘重力滑动与苏禄海扩张造成的区域挤压应力远程效应共同作用的结果，且苏禄海扩张造成的远程挤压效应主控平面上南北段褶皱冲断带变形的差异性，导致北段褶皱变形强度大于南段，具有背斜褶皱数量多、褶皱间距离短、逆冲断层倾角陡的特点，南段反之；且晚上新世以来北段深水区地层缩短量大于陆架区伸展量，两者之差为2~6 km，而南段两者相当，仅受三角洲前缘重力滑动影响.整个褶皱冲断带发育断弯、断展、断滑褶皱等3种断层相关褶皱以及叠瓦扇和冲起构造2种逆冲构造组合，是多期NW向挤压应力作用下形成的大型逆冲推覆构造，以前展式向盆地扩展.此外，由于中中新世以来逆冲断层的持续活动，研究区深水褶皱冲断带发育众多构造圈闭，油气成藏条件优越，且南段优于北段，靠近陆坡的近端优于远端，可作为勘探部署重点.  相似文献