基于多源数据的主体功能区划分方法——以广州市为例     

罗伟玲  王艳阳  张恒 《热带地理》2020,40(1):110-118

以广州市为例,基于城市感知数据、遥感影像等多源数据,采用卷积神经网络对遥感影像进行了语义提取,将提取结果与兴趣点（Points of Interest）样方密度的功能用地识别结果进行补充校验,根据政策和规划文件建立功能用地与主体功能区之间的关联,利用信息熵分析广州市功能用地混合程度,以辅助判别主体功能区,最终得到广州市主体功能区划分结果。将划分结果与《广州市主体功能区规划（2008—2020年）》和《广州市城市总体规划（2017—2035年）》草案对比验证,结果表明文章所提出的方法精准度较高,并能体现广州市空间格局形态,反映主体功能区实际分布情况。  相似文献   

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence     

《China Geology》2020,3(4):602-610

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.  相似文献   

广盐性鱼类渗透压适应性与生理可塑性机制研究     

马爱军  崔文晓  刘志峰  张金生  黄智慧  杨双双  刘晓菲  杨凯  张薇 《海洋与湖沼》2018,49(6):1308-1317

拥有强大的渗透压调节能力对广盐性鱼类的生存至关重要。目前,关于鱼类渗透压调节机制已有不少研究,但均存在较大的局限性。本文从广盐性鱼类渗透压信号转导机制、渗透胁迫的细胞调控机制、渗透调控的内分泌调节机制和无机离子通道和转运蛋白介导的渗透调控等方面对广盐性鱼类的渗透压适应性和生理可塑性机制进行分析,以期从分子、细胞、通路和生理等层次初步探索广盐性鱼类盐度胁迫后的可塑性表型变化和不同盐度条件下的应答机制,为广盐性鱼类的渗透压调节机制的深入研究奠定基础。对广盐性鱼类渗透压适应性与生理可塑性机制研究,有助于研究其环境适应机理,促进野生鱼种的人工化养殖以及新品种的育种从而提高经济效益、社会效益和生态效益,对促进水产养殖学进步以及养殖业的发展具有重要意义,同时,为研究广盐性鱼类的渗透压调节机制开辟新的研究方向。  相似文献   

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI     

Janaína N. vila  Trevor R. Ireland  Peter Holden  Peter Lanc  Andrew Latimore  Norm Schram  John Foster  Ian S. Williams  Liane Loiselle  Bin Fu 《Geostandards and Geoanalytical Research》2020,44(1):85-102

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.  相似文献   

STUDY FOR ABNORMAL VARIATIONS OF UNDERGROUND FLUID IN LIJIANG AREA,YUNNAN PROVINCE BEFORE LUDIAN M_S6.5 EARTHQUAKE IN 2014     

YANG Zhu-zhuan  DENG Zhi-hui  YANG Yue-wen  DENG Sheng-chang  LI Qing 《地震地质》2018,40(2):480-498

The study is based on the underground fluid observation data in Lijiang area, northwest Yunnan Province. The data include the water level and temperature in Dangxiao well and Jinjia well, and the ion measurements in Ganze spring. Combining with the data of regional hydrogeology, rainfall, well structures, and the geothermal gradient, we analyzed the variations of each measurement item before the Ludian M_S6.5 earthquake on August 3, 2014 and discussed the possible mechanism for the abnormal variations. The water levels of both Dangxiao well and Jinjia well are influenced by local rainfall, but the former shows hysteresis according to rainy seasons and is the long trend influence; while the latter shows synchronization between high water level and rainy season, indicating good connection between well water and shallow aquifer. The recharge water for Dangxiao well is in relatively low temperature, and the temperature sensor is located at the major connecting section between the well water and the aquifer; the water temperature variation is mainly affected by the discharge status and variation of water level. The Jinjia well is always in static level, and the temperature sensor is below the major connecting section between the well water and aquifer, so the water temperature is affected little by water level variations and in smooth fluctuation. The recharge source for Ganze spring can generally increase the contents of calcium and magnesium ions, so does the conductivity. The water level data of Dangxiao well since 2012 are decomposed with wavelet technique. The results, excluding such high-frequency components as the noise and the semidiurnal and daily wave components influenced by earth tide, are further processed with difference method in order to eliminate the trend effect. The results show that the relative change of water level is enhanced and in relatively rapid increase before the Ludian M_S6.5 earthquake; the corresponding water temperature values are high. The tendency of water level in Jinjia well displays descending, while the corresponding water temperature shows ascending. The content of calcium ion, magnesium ion, bicarbonate ion, and conductivity of Ganze spring are descending, while the content of fluoride ion is ascending. The abnormal variations of underground fluid in Lijiang area appeared in turns and were accompanied with minor earthquakes before Ludian M_S6.5 earthquake, which indicates enhancing of regional stress and increasing of fluid activity.  相似文献   

离子色谱法测定海水中氯离子和硫酸根离子     

王丕波  曾艳敏  闫晶  殷丽娜  任登龙 《海洋科学》2020,44(11):52-56

氯离子和硫酸根离子是海水中重要的无机阴离子，在研究海洋生态变化、海洋循环作用过程与海洋全球气候变化等领域具有重要的指示意义。其测定方法较多，但缺少相应的测试方法。本文对测定海水中Cl^-，SO₄^2-的离子色谱方法进行了优化，选用IonPacAS14碳酸盐选择性离子色谱柱，以3.5 mmol/L Na₂CO₃+1 mmol/L NaHCO₃为流动相，可消除海水样品中碳酸盐及其他阴离子的干扰。该方法对Cl^-检出限为0.29 mg/L，线性相关系数r²=0.999 2，对SO₄^2-检出限为0.42 mg/L，线性相关系数r²=0.997 9。样品的加标回收率在95%~102%，Cl^-和SO₄^2-的相对标准偏差分别为1.92%和4.18%。该方法简便、迅速、灵敏、准确度高，可满足批量海水样品中Cl^-与SO₄^2-的准确测试。  相似文献   

2012—2016年象山近岸海域水质评价与模拟研究          下载免费PDF全文

叶林安  欧阳萱  陈杲  袁国坚  茆洪卫 《海洋开发与管理》2020,37(3):31-35

为了解象山近岸海域水质污染状况，文章根据2012—2016年象山县近岸海域的水质监测结果，分析象山近岸海域水质现状及年际变化。应用灰色预测的模型来对象山近岸海域水质主要污染物的相关数据进行处理，得出主要污染物的预测结果。分析结果表明：象山近岸海域主要污染物为无机氮。用预测结果和实际数值通过残差验证，最后模拟出今后几年的监测值，为象山县近岸海域生态环境相关管理部门提供数据支撑和决策依据。  相似文献   

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet     

Alice Vho  Daniela Rubatto  Benita Putlitz  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):459-471

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.  相似文献   

Petrogenesis of the microcrystalline-dioritic enclaves from Jiuling granitoids in the eastern segment of Jiangnan Orogen and constraints on magma source materials     

《China Geology》2018,1(3):374-391

Numerous dark enclaves with different shapes are found in Jiuling Neoproterozoic granitoids. Precise LA-ICP-MS U-Pb dating was conducted on zircons extracted from two microcrystalline enclave samples, yielding crystallization ages of 822.6±5.8 Ma and 822.2±6.2 Ma, respectively. The consistent ages within analytical errors with the host granitoids suggested that they were the products of the same magmatism. The microcrystalline-dioritic enclaves commonly show plastic forms and contain similar plagioclase megacrysts to the host rocks, and both of the enclaves and host granitoids showed a complex composition and structural imbalance in plagioclases. Furthermore, the apatites with a euhedral acicular shape occurred widely in the microcrystalline-dioritic enclaves. All of these petrographic features above imply magma mixing is involved in their diagenesis. The enclaves and host granitoids show a marked zircon trace element difference and Hf isotopic signatures without correlation in zircon trace element pairs but form their own system between enclaves and host granitoids. Additionally, most of the zircons show extremely high ε_Hf (t) with ε_Hf (t) =3.54–11.94 from the southern samples, and ε_Hf (t) =1.0–9.09 from the central region. Some zircons with the higher ε_Hf (t) are similar to the zircons from the juvenile island arc in the eastern segment of Jiangnan Orogen. Integrated geological and Hf isotopic characteristics suggest microcrystalline-dioritic enclaves were derived from the partial melting process of the Mesoproterozoic crust which enriched juvenile island arc materials and mixed with the granitic magma that remelted from the Mesoproterozoic continental crust which relatively enriched ancient sediments and mixed with the host granitoid in diagenesis.  相似文献