Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

鄂尔多斯地块—扬子地块深部电性结构特征及其动力学意义     

吕宏斌  叶高峰  金胜  魏文博  董浩  张乐天  谢成良  尹曜田 《地质论评》2020,66(4):813-828

位于青藏高原东北缘的秦岭造山带在大地构造上南接扬子地块、北接华北地块,是特提斯构造域和古亚洲洋构造域的转换带。本文基于对一条起始于扬子地块,穿过秦岭造山带和鄂尔多斯地块,到达河套地堑的南北向大地电磁测深剖面的研究,探讨秦岭造山带和其北侧的鄂尔多斯地块、南侧的扬子地块之间的接触关系,以及青藏高原物质东北向逃逸等地学问题。对实测数据进行了张量阻抗分解和维性分析等工作,并对剖面进行了二维反演,获得岩石圈电性结构模型。根据电阻率模型认为:在秦岭造山带北部发现大规模"瓶颈状"分布的低阻异常体(C2),可能为华北、华南地块双向俯冲前缘地幔物质的上涌通道,或者是青藏高原中、下地壳物质沿秦岭造山带中构造薄弱位置向东逃逸的通道;在秦岭造山带和大巴山弧形带边界处发现南倾的低阻异常(C1),解释为大巴山弧形带北缘的逆冲断裂在电性上的反映;电性结构模型中,扬子地块高阻异常体(R2、R3和R4)向北倾斜至秦岭造山带下方,而北部鄂尔多斯地块的高阻异常体(R5和R6)向南倾斜至秦岭造山带下方;高阻异常通常被认为是稳定岩石圈的反映,据此推断这两组相向俯冲至秦岭造山带下方的高阻异常是华北地块和扬子地块向秦岭造山带下方汇聚的电性结构探测依据;鄂尔多斯地块南、北电性差异较大,北部中、下地壳大规模分布电阻率值在3～100Ω·m之间的低阻异常体,可能为地幔上涌导致的局部熔融或含盐流体共同作用的结果。  相似文献   

鄂尔多斯地块周缘垂直形变场负位错反演与应变积累研究     

张希  刘立炜  郝明  白卓立 《大地测量与地球动力学》2019,39(6):551-556

利用鄂尔多斯地块及其周缘1970～2014年的垂直形变速率场资料，借助负位错反演研究该区域长期应变积累。结果表明，地块东北缘山西断陷带中北段年均能量积累增量、剪应力强度都较高，西南缘六盘山断裂与渭河断裂西段次之；山西断陷带中南段至晋陕交界处年均剪应力强度较高且显示一定程度的能量积累；西秦岭构造区尤其西秦岭北缘断裂西段、晋冀蒙交界区也反映一定程度的能量积累特性。  相似文献   

地幔上涌对鄂尔多斯西缘岩石圈的改造:来自远震多尺度层析成像的证据   总被引：4，自引：1，他引：3       下载免费PDF全文

高翔  郭飚  陈九辉  刘启元  李顺成  李昱 《地球物理学报》2018,61(7):2736-2749

本文利用喜马拉雅二期科学探测台阵的678个地震台站及26个固定台站记录到的9，641个地震共约160000条远震P波走时数据，采用基于稀疏约束的多尺度层析成像方法，获得了鄂尔多斯西缘及邻区上地幔800 km深度范围内P波速度结构.结果显示，在东经104°附近阿拉善地块与鄂尔多斯盆地间存在岩石圈深度的构造边界，这表明阿拉善地块与鄂尔多斯可能分别从属于不同的大地构造单元.以北纬38°线为界，鄂尔多斯地块西缘在岩石圈范围内南北存在明显的速度差异，鄂尔多斯南部上地幔200~300 km深度范围显示为高速异常，而鄂尔多斯北部上地幔显示大面积的低速异常.这一现象表明，鄂尔多斯地块南北两部分经历了不同的构造演化过程.根据本文的结果可以进一步推断，由于青藏高原、阿拉善地块向东北方向推挤以及岩石圈的拆离引起的上地幔扰动导致了地幔上涌，上涌的热物质改造了鄂尔多斯西北缘地区的岩石圈，并使该区的岩石圈减薄.地幔上涌也可能是东经104°边界带和北纬38°构造带形成的深部动力学因素.  相似文献   

3D P-WAVE VELOCITY STRUCTURE AT THE NORTHEASTERN MARGIN OF ORDOS BLOCK     

HAN Xiao-ming  Liu Fang  ZHANG Fan  CHEN Li-feng  LI Juan  LI Shuan-hu  YANG Hong-ying 《地震地质》2018,40(1):215-231

Using the 7 100 absolute first arrivals of P waves and 91 513 relative P arrival times of 726 events at the northeastern margin of the Ordos block since 2009, the 3D fine structure of P wave velocity within the depth of 15km in the crust was inverted by the double difference seismic tomography method. The results show that there exist obvious high-speed continuous bodies in the northwest of the study area, and their lateral areas increase gradually with depth, while the velocity of east and south is relatively low. The velocity inhomogeneity exists and differs at different depths. The lateral differences of velocity are related to seismicity and faults. The 5~15km depth profile shows that earthquakes tend to occur in the area with relatively high velocity or high speed transition zones, which to some extent reflects the fragility of regional crustal media and the strong differential movement of faults in vertical and horizontal directions where the crust body is easy to absorb and store strain energy and generate major earthquakes. A "Y"-shape low-velocity channel is present in the lower crust around Liangcheng, corresponding to the NW-trending Heilaoyao-Shahukou fault set, which may reveal the migration path of the Late Tertiary-Quaternary basalt eruption. The Helingeer M6.2 earthquake in 1976 was related to the formation of the locking section of the thermal welding in this area. The three-dimensional fine structure of P wave velocity presented in this paper provides intuitive seismological evidence for physical and chemical properties of crustal media and the deep tectonic environment of earthquake preparation.  相似文献   

Current Vertical Motion Analysis of Northwestern Margin of Ordos Based on Precise Leveling     

Guo Baozhen  Ta L  Zhou Haitao  Su Guangli 《中国地震研究》2018,32(1):113-118

Ordos block was squeezed by the Qinghai-Tibetan block and North China block, and the tectonic activity was intense. In the periphery of Ordos block, there was a series of folds zones and compressed faults with complicate structures. This paper used three-phase data of 1980,1990 and 2014 to calculate vertical velocity of Northwestern margin of Ordos and the analytical results indicated that ① the Hetao basin between the rise of Yinshan fault block and Ordos fault block showed relatively subsidence, in which Linhe basin was the most evident and the subsidence rate was about 2-4mm/a. The subsidence rate of Jartai -Yinchuan rift zone on the western margin of Ordos block was about 2mm/a; ② the whole testing zone exhibited the evident inherited movement characterized by mountain rise and basin subsidence; ③the two leveling section through the northern margin fault and Dengkou-Benjing fault showed that the difference between vertical velocities on two sides of the fault was less than 0.5mm/a.  相似文献   

贺兰山—银川地堑及邻区重力异常特征及构造意义   总被引：1，自引：0，他引：1       下载免费PDF全文

吴桂桔  谈洪波  孙凯  王嘉沛  习宇飞  申重阳 《地球物理学报》2020,63(3):1002-1013

贺兰山—银川地堑及邻区地质结构复杂,对该区域深浅结构特征的研究具有重要意义.本文采用重力归一化总梯度成像和二维小波多尺度分解方法对研究区内重力异常进行了垂向和横向构造分析.重力归一化总梯度成像结果显示高低转换带的倾角、倾向与地质上的贺兰山东麓断裂、银川断裂和黄河断裂分布吻合较好,贺兰山西麓断裂与贺兰山东麓断裂汇交深度约18 km,银川断裂与黄河断裂汇交深度约25 km;二维小波多尺度分解成像结果表明正谊关断裂、贺兰山西麓断裂、芦花台断裂和银川断裂为上地壳断裂,贺兰山东麓断裂、青铜峡—固原断裂以及黄河断裂为下地壳断裂,且这三大断裂可能分别是阿拉善地块东南边界和鄂尔多斯地块西南边界;1739年平罗M 8.0古地震震中与银川断裂在重力剖面深度约15 km汇交,其垂向高低梯度为强变形带,同时古地震震中位于重力正负异常转换部位的低值区,据此可推断此次古地震的发震构造是银川断裂.这些结论可提高对贺兰山—银川地堑及邻区地质结构的认识,为该区地壳动力学过程及强震的孕震机理研究提供一定的科学依据.  相似文献   

沿107.6°E南北向剖面鄂尔多斯地块及周缘地区地壳结构          下载免费PDF全文

陈洁  陈永顺  郭震  杨挺 《地球物理学报》2020,63(7):2592-2604

鄂尔多斯地块紧邻青藏高原东北缘,位于华北克拉通的西部,在我国中生代、新生代以来东部地区的构造活动中起到了重要作用.对鄂尔多斯及其周缘地区的研究可以提供有关华北克拉通的形成、演化和破坏过程的重要信息.本文选取了纵贯鄂尔多斯的107.6°E附近南北剖面上的44个流动地震台站进行分析,采用接收函数方法,进行Kirchhoff偏移成像,并且结合在该区域内前人的地震面波频散进行联合反演,获得剖面下方的地壳内部精细结构.研究结果显示:(1)莫霍面在鄂尔多斯北部较平缓,约45km深;在鄂尔多斯南部有所加深,达到50km;其北边的河套盆地的地壳厚度约为50km;南边的渭河盆地到秦岭地区及四川盆地的地壳厚度从约为40km增厚到47～50km.(2)河套盆地下方存在大规模的低速异常,最深可达25km,反映了其显著的拉张构造和沉积历史.(3)秦岭造山带下方的低速异常对应于其主要为长英质的地壳组分,可能是由于中生代的拆沉作用导致的地壳下部基性岩石层的缺失.(4)以38°N为界的鄂尔多斯地块,南北部地壳速度结构存在差异,可能表明了这两部分经历的构造历史不同.  相似文献   

鄂尔多斯块体西南缘地区震源机制解与构造应力场特征分析     

王莹  赵韬  刘春  冯希杰 《地震地磁观测与研究》2020,41(4):18-25

计算了2001年1月至2018年9月鄂尔多斯块体西南缘地区（33°—38°N，103°—109°E）M_L≥3.0地震的震源机制，分析了该区域震源机制解特征，在此基础上，采用平均矩张量技术反演了该区域的构造应力场特征。结果表明，研究区震源机制类型以走滑型和逆冲型为主，其空间分布基本与区域构造动力背景和断裂性质一致，少量不符合区域构造性质的震源机制则反映了局部地质构造的复杂性。区域构造变形主体为NE向压缩，NW向相对扩张，反映了青藏高原块体对鄂尔多斯块体的直接作用。  相似文献   

鄂尔多斯盆地宜川地区二叠纪孢粉化石组合特征          下载免费PDF全文

高存山 《山东国土资源》2018,34(11)

通过对延长油矿延223井晚古生代孢粉组合研究以及古植被的恢复,探讨了该区晚古生代孢粉植物化石组合的地层学和古气候意义。根据孢粉化石主要属种的时代分布及其在各样品中百分含量的规律性变化,自下而上建立了3个孢粉组合:Gulisporites cochlearius-Laevigatosporites minimus组合、Sinulatisporites-Florinites组合和Lueckeisporites permianus-Platysaccus radialis组合。根据对划分孢粉组合的特征分析,通过与邻区及华北地区晚古生代孢粉组合的对比,探讨了孢粉组合的时代意义。通过孢粉组合,推测了相应时期的古植被类型,并与前人在相同地质时期所建立的大植物化石带进行了对比,分析了各地质时期植被的兴起、发展、繁盛以及衰退绝灭的历史过程,研究区二叠纪植物群属于典型的华夏植物群,反映了一种温暖潮湿的热带雨林气候,二叠纪晚期随着松柏类植物所占比例的增加,气候有变干旱的趋势。  相似文献