Ore-bearing fluids of the Eldorado gold deposit (Yenisei Ridge,Russia)     

N.A. Gibsher  A.A. Tomilenko  A.M. Sazonov  T.A. Bul’bak  M.O. Khomenko  M.A. Ryabukha  E.O. Shaparenko  S.A. Sil’yanov  N.A. Nekrasova 《Russian Geology and Geophysics》2018,59(8):983-996

The Eldorado low-sulfide gold-quartz deposit, with gold reserves of more than 60 tons, is located in the damage zone of the Ishimba Fault in the Yenisei Ridge and is hosted by Riphean epidote-amphibolite metamorphic rocks (Sukhoi Pit Group). Orebodies occur in four roughly parallel heavily fractured zones where rocks were subject to metamorphism under stress and heat impacts. They consist of sulfide-bearing schists with veins of gray or milky-white quartz varieties. Gray quartz predominating in gold-bearing orebodies contains graphite and amorphous carbon identified by Raman spectroscopy; the contents of gold and amorphous carbon are in positive correlation. As inferred from thermobarometry, gas chromatography, gas chromatography-mass spectrometry, and Raman spectroscopy of fluid inclusions in sulfides, carbonates, and gray and white quartz, gold mineralization formed under the effect of reduced H₂O-CO₂-HC fluids with temperatures of 180 to 490 °C, salinity of 9 to 22 wt.% NaCl equiv, and pressures of 0.1 to 2.3 kbar. Judging by the presence of 11% mantle helium (³He) in fluid inclusions from quartz and the sulfur isotope composition (7.1-17.4‰ δ³⁴S) of sulfides, ore-bearing fluids ascended from a mantle source along shear zones, where they “boiled”. While the fluids were ascending, the metalliferous S- and N-bearing hydrocarbon (HC) compounds they carried broke down to produce crystalline sulfides, gold, and disseminated graphite and amorphous carbon (the latter imparts the gray color to quartz). Barren veins of milky-white quartz formed from oxidized mainly aqueous fluids with a salinity of < 15 wt.% NaCl equiv at 150-350 °C. Chloride brines (> 30 wt.% NaCl equiv) at 150-260 °C impregnated the gold-bearing quartz veins and produced the lower strata of the hydrothermal-granitoid section. The gold mineralization (795-710 Ma) was roughly coeval to local high-temperature stress metamorphism (836-745 Ma) and intrusion of the Kalama multiphase complex (880-752 Ma).  相似文献   

Changes in dissolved organic matter (DOM) amount and composition along nested headwater stream locations during baseflow and stormflow          下载免费PDF全文

Shatrughan Singh  Shreeram Inamdar  Myron Mitchell 《水文研究》2015,29(6):1505-1520

Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Biodegradation of Isoprenoids,Steranes, Terpanes,and Phenanthrenes During In Situ Bioremediation of Petroleum‐Contaminated Groundwater     

《洁净——土壤、空气、水》2017,45(2)

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Multidimensional Toxicity of Rhamnolipid Extracts Obtained From Creosote‐Contaminated Soil          下载免费PDF全文

Zuzanna Sydow  Piotr Lisiecki  Justyna Staninska‐Pięta  Anna Olejnik  Paweł Cyplik  Agnieszka Zgoła‐Grześkowiak  Roman Marecik  Jacek Nowak  Katarzyna Glazar  Agnieszka Piotrowska‐Cyplik 《洁净——土壤、空气、水》2018,46(5)

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Atmospheric Concentrations and Phase Partitioning of Polycyclic Aromatic Hydrocarbons in Izmir,Turkey   总被引：1，自引：0，他引：1  

Eylem Demircioglu  Aysun Sofuoglu  Mustafa Odabasi 《洁净——土壤、空气、水》2011,39(4):319-327

Ambient air polycyclic aromatic hydrocarbon (PAH) samples were collected at a suburban (n = 63) and at an urban site (n = 14) in Izmir, Turkey. Average gas‐phase total PAH (∑₁₄PAH) concentrations were 23.5 ng m^?3 for suburban and 109.7 ng m^?3 for urban sites while average particle‐phase total PAH concentrations were 12.3 and 34.5 ng m^?3 for suburban and urban sites, respectively. Higher ambient PAH concentrations were measured in the gas‐phase and ∑₁₄PAH concentrations were dominated by lower molecular weight PAHs. Multiple linear regression analysis indicated that the meteorological parameters were effective on ambient PAH concentrations. Emission sources of particle‐phase PAHs were investigated using a diagnostic plot of fluorene (FLN)/(fluorine + pyrene; PY) versus indeno[1,2,3‐cd]PY/(indeno[1,2,3‐cd]PY + benzo[g,h,i]perylene) and several diagnostic ratios. These approaches have indicated that traffic emissions (petroleum combustion) were the dominant PAH sources at both sites for summer and winter seasons. Experimental gas–particle partition coefficients (K_P) were compared to the predictions of octanol–air (K_OA) and soot–air (K_SA) partition coefficient models. The correlations between experimental and modeled K_P values were significant (r² = 0.79 and 0.94 for suburban and urban sites, respectively, p < 0.01). Octanol‐based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. However, overall there was a relatively good agreement between the measured K_P and soot‐based model predictions.  相似文献   

古火灾历史重建的研究进展     

占长林  曹军骥  韩永明  安芷生 《地球科学进展》2011,26(12):1248-1259

火是地球系统的重要组成部分,与气候、植被、生物地球化学循环和人类活动密切相关。火对全球气候和生态系统的影响已成为目前全球变化研究的一个热点。火灾发生后会在周围的环境中留下许多燃烧产物,如黑碳、木炭屑、多环芳烃、左旋葡萄糖等,它们广泛存在于海洋、湖泊、河流、土壤和陆地风成沉积物中;还会留下一些火灾痕迹,如树木火疤、土壤磁...  相似文献   

1株分离自海水中芘降解菌的鉴定及其降解特性研究     

王静  邱金泉  张雨山  杨波  张晓青  苗英霞  张爱君  张辉 《海洋学研究》2011,29(1):49-55

以芘为唯一碳源,对采自于天津港石油污染区的海水和土壤样品进行富集培养,分离到1株芘降解菌,经显微形态观察、生理生化鉴定、16S rRNA基因序列的比对及系统发育进化的分析,确定该菌株为施氏假单孢菌Pseudomonas stutzeri,并采用室内培养方法,对其进行了芘降解性能的测定及降解途径的分析.结果表明,该菌株在...  相似文献   

Permeable Reactive Barrier for Groundwater Pollution Remediation: An Review   总被引：2，自引：0，他引：2  

Liu Fei  Chen Liang  Wang Guangcai  Chen Honghan  Robert W. Gillham 《地球科学进展》2015,30(8):863-877

As an in situ, simple and passive technology, Permeable Reactive Barrier (PRB) is becoming widely used in groundwater remediation. Based on its definition and development process, the development of PRB can be divided into two stages: The traditional zero-valent iron PRB before 2000 and the PRB composed of novel mixed media after 2000. With the rapid worsening of groundwater pollution, the increasing application of PRB and the rapid development of materials science, the development of PRB technology in future will be mainly focused on the investigation of mixed and novel media, the design of mixed PRBs, the combination of PRB technology with other remediation technology, and the long term monitoring and management of PRB projects.  相似文献   

Structural Evolution and Hydrocarbon Potential of the Upper Paleozoic Northern Ordos Basin, North China     

YANG Minghui  LI Liang  ZHOU Jin  JIA Huichong  SUN Xiao  GONG Ting  DING Chao 《《地质学报》英文版》2015,89(5):1636-1648

The hydrocarbon potential of the Hangjinqi area in the northern Ordos Basin is not well known, compared to the other areas of the basin, despite its substantial petroleum system.Restoration of a depth-converted seismic profile across the Hangjinqi Fault Zone(HFZ) in the eastern Hangjinqi area shows one compression that created anticlinal structures in the Late Triassic, and two extensions in ~Middle Jurassic and Late Early Cretaceous, which were interrupted by inversions in the Late Jurassic–Early Early Cretaceous and Late Cretaceous, respectively.Hydrocarbon generation at the well locations in the Central Ordos Basin(COB) began in the Late Triassic.Basin modeling of Well Zhao-4 suggests that hydrocarbon generation from the Late Carboniferous–Early Permian coal measures of the northern Shanbei Slope peaked in the Early Cretaceous, predating the inversion in the Late Cretaceous.Most source rocks in the Shanbei Slope passed the main gas-migration phase except for the Hangjinqi area source rocks(Well Jin-48).Hydrocarbons generated from the COB are likely to have migrated northward toward the anticlinal structures and traps along the HFZ because the basin-fill strata are dipping south.Faulting that continued during the extensional phase(Late Early Cretaceous) of the Hangjinqi area probably acted as conduits for the migration of hydrocarbons.Thus, the anticlinal structures and associated traps to the north of the HFZ might have trapped hydrocarbons that were charged from the Late Carboniferous–Early Permian coal measures in the COB since the Middle Jurassic.  相似文献   

AHDEB油田白垩系油藏油气充注期次的流体包裹体证据          下载免费PDF全文

伏美燕  刘榧  邓虎成  黄婷婷  王浩 《地球科学》2015,40(7):1187-1196

伊拉克AHDEB油田油藏成藏规律对油田后期开发具有重要意义, 与埋藏史相结合的流体包裹体研究是揭示油藏油气成藏期次和时间的有效手段.利用伊拉克AHDEB油田白垩系油藏储层样品对流体包裹体特征进行了分析, 并且通过流体包裹体的显微观察、荧光颜色、单一包裹体的红外光谱和均一温度测定, 结合地质背景对该油田的油充注期次进行了研究.研究表明, 油包裹体以发绿色和黄绿色荧光为主, 少数发浅黄色和黄褐色荧光.油包裹体的显微傅立叶红外光谱测定结果计算的CH_2a/CH_3a、X_inc、X_std可划分油的成熟度, 表明存在两种成熟度的油.最后, 根据均一温度测定结果, 结合埋藏史和热史, 认为该油田可能存在4期油充注成藏相关的流体活动: 第1成藏期发生在95.0~96.5Ma, 相当于晚白垩世早期; 第2成藏期为71.0~78.5Ma, 相当于晚白垩世晚期, 第1期和第2期烃源岩排烃规模小, 产生中-重质油, 后期遭受氧化而形成沥青; 第3成藏期发生在14.0~15.0Ma, 相当于中中新世, 处于生排烃高峰期, 为主要成藏期; 第4期发生在10.0Ma左右, 与第3期为多幕连续充注.   相似文献