Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

四川盆地广安地区中二叠统栖霞组岩石特征与沉积环境     

易海永  崔宝琛  王瑶琳  邱玉超  徐胜林  李乾 《吉林大学学报(地球科学版)》2020,50(2):454-464

四川盆地中二叠统栖霞组勘探发现系列油气，资源潜力巨大。但广安地区中二叠统栖霞组的岩石学特征及沉积环境研究薄弱。在野外地质调查的基础上，结合室内岩石学、岩相学等综合分析，对广安地区栖霞组碳酸盐岩岩石特征、沉积相类型及其古地理展布特征进行了系统研究。结果表明：广安地区栖霞组主要发育亮晶颗粒灰岩、亮晶生物碎屑灰岩、微晶生物碎屑灰岩、微晶颗粒灰岩、生物碎屑微晶灰岩、含生物碎屑微晶灰岩和泥晶灰岩7种岩石类型；碳酸盐岩颗粒主要以生物碎屑为主，部分层位发育球粒；古生物化石以三叶虫、腕足和有孔虫为主，同时可见棘皮类和藻类；栖霞组沉积期主要为碳酸盐岩台地沉积环境，其中栖霞组晚期（栖二段）台缘滩和台内滩较为发育，为该区油气成藏提供了有利条件。  相似文献   

中国草畜平衡状态时空演变指示的草地生态保护格局   总被引：2，自引：0，他引：2  

黄麟  翟俊  祝萍  郑瑜晗 《地理学报》2020,75(11):2396-2407

中国草原牧区作为重要生态安全屏障和草地畜牧业生产基地,其草畜平衡状态直接影响草地退化与恢复,进而影响草地生态系统服务能力的强弱。本文分析了2000—2015年主要草原牧区草地植被覆盖、牧草供给、草畜平衡状态的时空变化特征,深入探讨草地退化与恢复及载畜压力下草地生态系统保护与恢复空间格局。结果表明：过去16年主要草原牧区草地面积净减少约163万hm²,6.7%的草地出现植被覆盖退化,而5.4%的草地呈现植被覆盖明显恢复。天然草地牧草供给量以增加为主,年增率约0.3 kg/hm²,然而其载畜压力亦持续增加,不考虑补饲的载畜压力指数高达3.8,除内蒙古东北部、青藏高原中部仍有载畜潜力,其余多处于超载状态;考虑实际冷季补饲的载畜压力指数约3.1,内蒙古中东部有所缓解;假设冷季全额补饲则载畜压力指数减至1.9,内蒙古、青藏高原等区域明显缓解。叠加上述数据,本文针对自然保护地、牧区、半农半牧区和农区等不同区域的草地生态保护格局,提出了平衡草地生态保护与畜牧生产利用的不同发展策略。  相似文献   

喜马拉雅山脉中段土地覆被的垂直分异特征     

张镱锂  吴雪  郑度 《地理学报》2020,75(5):931-948

喜马拉雅山脉中段的珠穆朗玛峰等地,海拔高差巨大、生境复杂多变、土地覆被类型多样且植被垂直带谱完整,是全球范围内研究土地覆被垂直变化的理想场所。本文基于30 m空间分辨率的土地覆被数据（2010年）和DEM数据,在ArcGIS和Matlab平台的支持下,提出并运用脊线法、样带法和扇区法3种山地南北坡划分方法,研究了喜马拉雅山土地覆被垂直分布与结构差异。结果表明：① 山地土地覆被分布具有明确的垂直地带性结构特征,喜马拉雅中部土地覆被垂直带谱为南六北四式,土地覆被垂直带谱中具有人类活动的特点。② 南北坡之间的土地覆被垂直带谱差异明显,南坡土地覆被类型完整多样,北坡相对简单;对同类型土地覆被而言,南坡较北坡分布高程低、幅度宽。③ 依据各类型分布面积比随海拔变化情况,土地覆被类型在南北坡上的垂直分布可分为4种模式：冰川雪被、稀疏植被和草地为单峰分布型,裸地为南单峰北双峰分布型。④ 3种划分方法中,南坡的土地覆被垂直带结构具有相似性,而北坡的土地覆被垂直带结构存在差异,扇区法较好地反映了土地覆被自然分布格局。  相似文献   

帕米尔高原Rushan-Pshart古特提斯洋或中特提斯洋争论的岩石地球化学证据     

徐天德  王世锋  汤文坤  姚鑫 《地质科学》2020,(1):218-233

帕米尔高原上广泛分布的加里东期火山岩,印支期火山岩与燕山期火山岩被认为是块体依次向北俯冲拼贴到欧亚板块上的产物。特别是燕山期火山岩被认为是Rushan-Pshart中特提斯洋闭合的产物。但近年来地层古生物、火山岩证据不断表明Rushan-Pshart洋闭合时间在晚三叠一早侏罗世,由此限定Rushan-Pshart古特提斯洋性质,而帕米尔高原上广泛分布的燕山期火山岩是更南部的Shyok中特提斯洋闭合的产物。目前,中国境内Rushan-Pshart缝合带属性的研究工作展开较晚,研究程度较低。我们对塔什库尔干明铁盖沟一线燕山期火山岩带展开的工作发现零星分布的印支期花岗岩。印支期花岗岩错石U・Pb年龄显示岩体侵位时间在201 Ma左右。全岩主量元素特征表明岩石为I型高钾钙碱性闪长花岗岩;稀土元素在球粒陨石标准化图解中呈轻稀土元素相对富集,重稀土元素相对亏损的右倾海鸥型。明铁盖岩体的微量元素显示大离子亲石元素明显富集,而高场强元素明显亏损。稀土微量元素特征倾向花岗岩属性为岛弧型花岗岩,Sr-Nd-Hf同位素比值特征显示岩体形成于下地壳部分熔融环境。岩体的地化特征表明岩体形成的构造环境为板块汇聚的洋壳俯冲阶段,结合区域地质特征,我们将花岗岩体归为Rushan-Pshart古特提斯洋壳俯冲消减的产物。Rushan-Pshart缝合带传统上认为是中特提斯带,近年的研究进展认为其为古特提斯缝合带,本文的工作支持这种观点。Rushan-Pshart古特提斯缝合带的确立对帕米尔高原与青藏高原主体的块体对比提供了可信的对比方案,并对青藏高原新生代陆内变形方式的争论提供了可靠的证据。  相似文献   

极地环境监测网的设计及其在南极普里兹湾的应用     

程文芳  朱建钢  吴荣荣  詹德川  陆大海  闫可  郑小罗 《海洋科学》2018,42(2):34-45

为了保护南极和北极的生态系统和环境,中国自20世纪90年代初开始推行和实施了极地环境监测计划,部署了各学科监测传感器阵列;采集了多学科数据,包括海洋、大气、冰冻圈、生物圈等主题;架构了"R/V雪龙号破冰船—极地考察站—国内基地"之间的快速数据传输网络;建立了海洋环境监测系统、太阳能地面空间监测系统、生态环境监测系统等系列监测系统。为了实现长期监测,达到预测和预警目标,本文针对国内外现状,在现有基础上设计了一套中国极地环境长期监测网(Polar Environment monitoring network of China,CPEMN)。该监测网集成各监测系统并在监测指标设计上覆盖我国极地所有常规监测/观测任务,且根据国际科研动态和长期监测规划拓展了预期监测范围。最后本文利用南极普里兹湾进行的破冰导航应用示范验证了CPEMN具有可执行性。  相似文献   

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

高精度直升机机载LiDAR在高速公路改扩建勘测中的应用可行性研究          下载免费PDF全文

郑伟安 《山东国土资源》2018,34(8)

机载LiDAR在公路勘测方面的用途日益广泛。该文对直升机机载LiDAR在高速公路改扩建中的应用技术路线可行性进行了研究论证,从地面控制测量、点云数据获取、点云数据处理、成果应用等多个方面进行了阐述,通过分析LiDAR点云数据在5种不同地面控制点布设方案校正下的点云数据精度,论证了利用地面控制点对直升机机载LiDAR点云数据进行平面和高程校正的可行性。  相似文献   

排酸护肾汤治疗尿酸性肾病30例临床观察     

刘劲松  郑燕姣  钟颖 《应用海洋学学报》2018,34(7):7-10

目的：观察排酸护肾汤治疗尿酸性肾病的临床疗效。方法：将60例尿酸性肾病患者随机分为治疗组和对照组各30例，对照组予西医常规治疗，治疗组在对照组治疗的基础上加排酸护肾方超微颗粒治疗，均以2周为1个疗程，治疗3个疗程。观察2组治疗前后的血尿酸（UA）、血肌酐（Scr）、尿素氮（BUN）、尿N-乙酰-β-D-葡萄糖苷酶（UNAG）、尿微量白蛋白（UALB）变化情况，评定综合疗效。结果：总有效率治疗组为90.0%，对照组为70.0%，2组比较，差异有统计学意义（P<0.05）。2组治疗后UA水平均较治疗前降低，差异具有统计学意义（P<0.05），组间比较，差异无统计学意义（P>0.05）；治疗组治疗后BUN、Scr、UNAG、UALB水平均明显下降，且优于对照组治疗后，差异均有统计学意义（P<0.05）。不良反应发生率治疗组及对照组均为3.33%，差异无统计学意义（P>0.05）。结论：排酸护肾汤可有效改善尿酸性肾病患者的临床症状和体征，并可有效降低血UA、Scr、BUN、UNAG、UALB水平，疗效安全确切，值得临床推广应用。  相似文献   

Petrogenesis of Early Cretaceous hornblende gabbro in Khanka Massif: evidence from geochronology and geochemistry     

WEI Chunxia  WEI Xu  ZHU Weigang  XU Wenliang 《世界地质(英文版)》2018,(3)

The authors report zircon U-Pb geochronological,whole-rock geochemical and zircon Lu-Hf isotope data for the hornblende gabbro within the Khanka Massif,with the aim of constraining its formation time and petrogenesis. The zircon U-Pb dating shows that ~(206)Pb/~(238)Pb ages of zircons from the hornblende gabbro range from 120 to 129 Ma,yielding a weighted mean age of 123 ± 2 Ma,i. e.,the Early Cretaceous. The hornblende gabbro has SiO_2 of 44. 77%--46. 58% and belongs to the tholeiitic series on FeO~t/MgO-SiO_2 diagram. It displays a right-inclined REE pattern with( La/Yb)_N ratios of 3. 44 to 4. 42. The trace element spidergram shows that they are enriched in large ion lithophile elements( LILE) such as Rb,Th,U,K and Pb,and depleted in high field strength elements( HFSE) such as Nb,Ta,Ti and P,indicating an affinity to arc igneous rocks.The ε_(Hf)( t) values of zircons vary from -2. 6 to + 3. 9 and Hf model ages( T_(DM1)) range from 622 to 883 Ma.These geochemical characteristics indicate that primary magma of the hornblende gabbro could be derived from partial melting of young mantle material accreted during the Neoproterozoic. Combined with the Early Cretaceous igneous rock assemblages in NE Asia. It is concluded that the hornblende gabbro formed in an active continental margin related to the westward subduction of the Paleo-Pacific Plate beneath the Khanka Massif.  相似文献