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1.
滇东南马关都龙是一个以锡锌为主,共-伴生铟、铜、铅、钨、铁、银等多种元素的锡锌多金属超大型矿床。虽然前人从矿物学、矿床地球化学、年代学等不同角度开展了较多的研究,该矿床锡锌多金属矿化为燕山晚期岩浆热液活动的产物已是不争的事实,但关于该矿床是否存在热水沉积作用及其与锡锌多金属成矿作用的关系依然存在较大争议。本文选取都龙矿区广泛存在的黄铁矿作为主要研究对象,在矿相学基础上利用LA-ICPMS对不同阶段黄铁矿的微量元素组成开展了系统的研究。野外及显微鉴定结果表明,矿区存在四种类型(期次)的黄铁矿,即:鲕状黄铁矿Py1;穿切或交代Py1的细脉状黄铁矿Py2;与闪锌矿等硫化物共生的自形黄铁矿Py3;包裹早期黄铁矿或闪锌矿等硫化物的他形黄铁矿Py4。LA-ICPMS分析结果表明,该矿床黄铁矿中富集多种微量元素,其中Co、Ni、As、Ge等元素以类质同象的形式存在黄铁矿晶格中,而其余元素多以显微矿物包体形式赋存于黄铁矿中。上述四期黄铁矿微量元素组成存在较大差别,Py1相对富集Zn和As,而其余微量元素含量较低,Co与Ni含量较低,Co/Ni比值远低于1.00,其微量元素组成与典型沉积作用形成黄铁矿基本一致; Py2与Py1具有相似的微量元素组成特征,其Co/Ni比值接近Py1变化范围; Py3和Py4除富集Zn、As外,Mn、Co、Ni、Cu、Sb、Pb、Bi元素含量也相对较高,其Co/Ni比值相对较高,多大于1,与典型岩浆热液型黄铁矿微量元素组成相似,而与沉积型黄铁矿差异明显。结合各阶段黄铁矿产出地质特征,对比不同类型黄铁矿微量元素组成,本研究认为:Py1鲕状黄铁矿为热水沉积作用形成; Py2为Py1变质改造形成的细脉状黄铁矿,其微量元素继承了Py1; Py3为岩浆热液活动形成的自形黄铁矿; Py4为岩浆热液活动晚期形成的他形黄铁矿,Ag和Bi组成作为区分不同成因类型黄铁矿的化学指标的潜力。矿区早期沉积作用形成鲕状黄铁矿过程可能为后期成矿作用提供了部分硫源及少量Zn等成矿物质,海西-印支期区域变质改造作用对矿区成矿作用影响不大,而燕山晚期岩浆热液活动才是矿区锡多金属大规模成矿作用的主导因素。 相似文献
2.
《Chemie der Erde / Geochemistry》2021,81(2):125765
A large, euhedral crystal of fluorapatite (ca. 19.5 × 20.0 mm) from the Panasqueira tin-tungsten deposit (Portugal) was investigated in terms of the distribution of trace elements by using several microanalytical techniques. The studied material represents almost pure fluorapatite with minor amounts of other cations (mainly Sr, Mn, REE and Fe), OH and Cl. Particular interest was given to the distribution of rare earth elements with respect to the crystallographic orientation. A broad range of analytical techniques were used, including optical microscopy coupled with cathodoluminescence imaging, electron probe microanalysis (EPMA), laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS), Raman microspectroscopy, and simultaneous thermal analysis coupled with mass spectrometry. The investigated crystal consists of the main crystal with a distinct core and rim (Ap2core and Ap2rim, respectively), which grew on a previous, euhedral crystal (Ap1). The fluorapatite demonstrates various types of zoning: regular oscillatory, irregular, and internal sectoring, which is also reflected in trace elements concentrations. The rim Ap2rim has lower concentrations of Mn, Sr and Fe, and significantly higher concentrations of REE compared to the core Ap2core and older crystal Ap1. Furthermore, the rim Ap2rim is strongly depleted in Th, U and Pb. The entire crystal shows elevated Eu contents, expressed as a strong positive anomaly in chondrite-normalized REE patterns. With regards to the volatiles, F concentrations are constant in Ap1, Ap2core and Ap2rim, whereas Cl is below the EPMA detection limit. The Ap2rim was the only part of the investigated material containing OH and CO3, which were observed in the Raman spectra. Furthermore, part of the crystal Ap2core is extensively altered, likely due to fluid-induced metasomatic processes. LA-ICPMS U-Pb dating yielded highly discordant dates due to common Pb content. A lower intercept age of 297 ± 13 Ma (MSWD = 0.13) indicates the age of the fluorapatite crystallization. The overall analytical data constrain growth and post-growth processes, including crystallization of Ap1 and Ap2core, which both have typical hydrothermal Sn-W deposit characteristics, whereas Ap2rim is related to a carbonate stage of the mineralization in the Panasqueira deposit. 相似文献
3.
新疆西准噶尔苏云河钼矿床含矿岩体地球化学和年代学 总被引：4，自引：0，他引：4
苏云河钼矿床位于新疆西准噶尔巴尔鲁克山西段,容矿岩石为二长花岗岩和二长花岗斑岩。这些花岗岩具有类似的地球化学特征:富集Rb、Th、U和LREE,相对亏损Ba、P、Ti,属于高钾钙碱性I型花岗岩系列,局部经历过强烈的分离结晶作用。LA-ICPMS锆石U-Pb定年结果显示苏云河钼矿区的成岩年龄为309.3~310.2 Ma,这表明与成矿有关的岩浆活动发生于晚石炭世。黑云母的Ti温度计表明Ⅰ号和Ⅲ号岩体的结晶温度相近,为695~728℃;而Ⅱ号岩体的结晶温度较低,为642~668℃。同时根据角闪石-斜长石压力计获得Ⅰ号和Ⅲ号岩体的结晶压力为(3.0~3.9)×108Pa。综合地球化学研究表明,苏云河钼矿区3个岩体均形成于岛弧环境。此外,以苏云河钼矿床为代表的巴尔鲁克山成矿带与哈萨克斯坦境内的巴尔喀什成矿带在岩石地球化学、成岩成矿时代等方面具有许多类似的特点,表明巴尔鲁克山成矿带可能是巴尔喀什成矿带在中国境内的延伸。 相似文献
4.
The Darongshan granitic suite (~ 10,000 km2) consists of five major units (Taima, Nadong and Jiuzhou plutons, and Pubei and Darongshan batholiths) typical of peraluminous S-type granitoids containing abundant granulite inclusions in the Cathaysia block, South China. Six samples from these plutons and batholiths have been investigated using both LA-ICPMS U–Pb age dating on zircon cores and EMP U–Th–Pb chemical age dating on monazite cores and rims. LA-ICPMS zircon results give similar major age populations ranging between 260 ± 3 and 250 ± 3 Ma for all units, with apparent older age peaks concentrated at 1020, 800, 430 and 330 Ma. On the other hand, EMP monazite results yield younger ages of 231–229 Ma for Nadong, Taima, Pubei and Darongshan and 224 Ma for Jiuzhou samples, with older age groups of 264 Ma for Taima and 256–250 Ma for Pubei units. Since the older monazite ages are similar to the majority of zircon ages, the latter are considered as inherited ages. Further because such zircon ages are similar with the emplacement time of the Emeishan large igneous province in western South China, they likely reflect the timing of metamorphism for the included fragments of granulitic crusts that had been formed by invasion of the Emeishan plume. The younger monazite ages, as present for all plutons and batholiths in the entire Darongshan area, are taken as the formation age of the host granites. Combining U–Pb zircon and EMP monazite ages known for Permo-Triassic high temperature and high pressure metamorphic rocks and granites in the Indochina block (e.g., the Kannack Complex of the Kontum massif), it is suggested that the Indosinian thermal activity had set records over both the Indochina (plus Simao) and South China blocks in two main episodes, one is 260–250 Ma and the other is 231–229 Ma. One plausible explanation is that these two blocks were one united continent before the Emeishan plume activity and an opening was triggered by this plume at ~ 260 Ma. Due to forces of the approaching Sibumasu block, both the South China and Indochina blocks were amalgamated again at ~ 230 Ma. We, therefore, advocate that double subduction of the plume-triggered oceanic crusts in opposite directions is responsible for the generation of the Darongshan granitic suite in the South China block and its counterpart in the Indochina block. 相似文献
5.
Yukio Isozaki Shinji Yamamoto Shuhei Sakata Hideyuki Obayashi Takafumi Hirata Ken-ichi Obori Toshinori Maebayashi Satoshi Takeshima Toshikazu Ebisuzaki Shigenori Maruyama 《地学前缘(英文版)》2018,9(4):1073-1083
Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons. 相似文献
6.
辽宁五龙金矿是辽东地区大型岩浆热液型矿床之一,成矿作用主要与中生代火成岩有关,为了进一步理清五龙地区中生代火成岩成因,本文对五龙金矿区大量花岗斑岩脉、闪长岩脉、三股流岩体和其中的各类脉岩进行了单颗粒锆石LA-ICPMS U-Pb测年和岩石主、微量元素地球化学研究。结果表明,五龙地区岩浆岩形成时代主要有晚侏罗世和早白垩世,矿区内近南北向展布的花岗斑岩脉形成于晚侏罗世（154.3±0.9~155.6±1.1 Ma）,指示矿区在晚侏罗世受到区域最大主应力方向为近南北向;三股流岩体成岩最新年龄（116.8±0.8~117.3±0.7 Ma）基本位于前人报道的年龄范围（111~129 Ma）;地球化学数据表明各类岩浆岩属于高钾钙碱性—钾玄岩系列,具有相同源区特征,形成于活动大陆边缘俯冲伸展环境下的弧岩浆,并且具有壳幔混合及进一步演化特征;结合不同深度标高成矿元素丰度特征,指示闪长岩与成矿作用密切相关,并且越往深部成矿潜力越大,对该地区找矿预测具有重要指导意义。 相似文献
7.
柴达木盆地西部基底分布有大量的有花岗岩类岩石。通过对柴达木盆地西部昆北断阶带钻遇的基底花岗岩样品开展详细的岩石学、锆石激光探针等离子体质谱U-Pb同位素年代学及岩石地球化学研究表明,锆石U-Pb同位素年龄为467~450Ma,显示基底花岗岩的结晶年龄为中-晚奥陶世,属于加里东期岩浆侵入旋回。详细的岩石地球化学分析表明,昆北断阶带基底花岗岩属过铝高钾钙碱性系列,其稀土元素配分模式为具有Eu负异常的轻稀土元素富集型,昆北断阶带中南部基底花岗岩属上地壳物质熔融,同碰撞环境下形成的花岗岩。综合区域上的研究成果,昆北断阶带及其以西地区存在中奥陶世-早志留世的加里东期构造-岩浆事件,这对探讨柴达木盆地西部基底花岗岩成因类型及岩浆演化具有重要的意义。 相似文献
8.
The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope. 相似文献
9.
新疆西准噶尔北部广泛发育中酸性侵入岩,其形成时代为晚石炭世—早二叠世,岩石类型为辉石闪长岩、石英闪长岩和花岗闪长岩。阔依塔斯杂岩体的形成年龄为(297±2)Ma,Si O2为52.40%~67.53%;高Al2O3,14.92%~17.85%;里特曼指数(δ)小于3.3,介于1.47~1.98;富钠贫钾,K2O/Na2O为0.15~0.49;铁高而镁低,Fe OT/Mg O为1.01~1.69。其稀土配分模式右倾,轻重稀土分馏明显,具有微弱铕正异常。地球化学和年代学特征表明:岩体形成于后碰撞演化的晚期阶段,这一时间早于东准噶尔后碰撞的时间(二叠纪末)。该杂岩体主体可能为幔源岩浆底侵镁铁质下地壳,导致发生部分熔融的产物。 相似文献
10.