Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence   总被引：4，自引：1，他引：4  

Claude Belzile  Laodong Guo   《Marine Chemistry》2006,98(2-4):183-196

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.  相似文献   

Spectrophotometric pH measurement in estuaries using thymol blue and m-cresol purple     

Luke M. Mosley  Shamus L.G. Husheer  Keith A. Hunter   《Marine Chemistry》2004,91(1-4):175-186

The conditional acid dissociation constants (pK_a′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pK_a′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln⁻¹):The estimated accuracy of pH measurements using these calculated pK_a′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities.  相似文献   

Characterization of chromophoric dissolved organic matter (CDOM) in the Baltic Sea by excitation emission matrix fluorescence spectroscopy   总被引：11，自引：0，他引：11  

Piotr Kowalczuk  Joanna Sto&#x;-Egiert  William J. Cooper  Robert F. Whitehead  Michael J. Durako 《Marine Chemistry》2005,96(3-4):273-292

Chromophoric dissolved organic matter (CDOM) is the major light absorber in the Baltic Sea. In this study, excitation emission matrix (EEM) fluorescence spectra and UV–visible absorption spectra of CDOM are reported as a function of salinity. Samples from different locations and over different seasons were collected during four cruises in 2002 and 2003 in the Baltic Sea in both Pomeranian Bay and the Gulf of Gdansk. Absorption by CDOM decreased with increased distance from the riverine source and reached a relatively stable absorption background in the open sea. Regression analysis showed that fluorescence intensity was linearly related to absorption by CDOM at 375 nm and a_CDOM(375) absorption coefficients were inversely related to salinity. Analysis of CDOM-EEM spectra indicated that a change in composition of CDOM occurred along the salinity gradient in the Baltic Sea. Analysis of percent contribution of respective fluorophore groups to the total intensity of EEM spectra indicated that the fluorescence peaks associated with terrestrial humic components of the CDOM and total integrated fluorescence decreased with decreasing CDOM absorption. In contrast, the protein-like fraction of CDOM decreased to a lesser degree than the others. Analysis of the percent contribution of fluorescence peak intensities to the total fluorescence along the salinity gradient showed that the contribution of protein-like fluorophores increased from 2.6% to 5.1% in the high-salinity region of the transect. Fluorescence and absorption changes observed in the Baltic Sea were similar to those observed in similar transects that have been sampled elsewhere, e.g. in European estuaries, Gulf of Mexico, Mid-Atlantic Bight and the Cape Fear River plume in the South Atlantic Bight, although the changes in the Baltic Sea occurred over a much smaller salinity gradient.  相似文献   

Structural monitoring of offshore platforms using impulse and relaxation response     

Lalu Mangal  V. G. Idichandy  C. Ganapathy 《Ocean Engineering》2001,28(6)

Monitoring offshore platforms, long span bridges, high rise buildings, TV towers and other similar structures is essential for ensuring their safety in service. Continuous monitoring assumes even greater significance in the case of offshore platforms, which are highly susceptible to damage due to the corrosive environment and the continuous action of waves. Also, since a major part of the structure is under water and covered by marine growth, even a trained diver cannot easily detect damage in the structure. In the present work, vibration criterion is adopted for structural monitoring of jacket platforms. Artificial excitation of these structures is not always practicable and ambient excitation due to wind and waves may not be sufficient for collecting the required vibration data. Alternate methods can be adopted for the same purpose, for example, the application of an impact or a sudden relaxation of an applied force for exciting the structure. For jacket platforms, impact can be applied by gently pushing the structure at the fender while relaxation can be accomplished by pulling the structure and then suddenly releasing it using a tug or a supply vessel in both cases. The present study is an experimental investigation on a laboratory model of a jacket platform, for exploring the feasibility of adapting vibration responses due to impulse and relaxation, for structural monitoring. Effects of damage in six members of the platform as well as changes in deck masses were studied. A finite element model of the structure was used to analyze all the cases for comparison of the results as well as system identification. A data acquisition and analysis procedure for obtaining the response signatures of the platform due to the impulse and relaxation procedure was also developed for possible adoption in on-line monitoring of offshore platforms. From the study, it has been concluded that both impulse and relaxation responses are useful tools for monitoring offshore jacket platforms. The present work forms the basis for the development of an automated, on-line monitoring system for offshore platforms, using neural networks.  相似文献   

Analysis and classification of hyperspectral data for mapping land degradation: An application in southern Spain     

《International Journal of Applied Earth Observation and Geoinformation》2005,7(2):85-96

Desertification is a severe stage of land degradation, manifested by “desert-like” conditions in dryland areas. Climatic conditions together with geomorphologic processes help to mould desert-like soil surface features in arid zones. The identification of these soil features serves as a useful input for understanding the desertification process and land degradation as a whole. In the present study, imaging spectrometer data were used to detect and map desert-like surface features. Absorption feature parameters in the spectral region between 0.4 and 2.5 μm wavelengths were analysed and correlated with soil properties, such as soil colour, soil salinity, gypsum content, etc. Soil groupings were made based on their similarities and their spectral reflectance curves were studied. Distinct differences in the reflectance curves throughout the spectrum were exhibited between groups. Although the samples belonging to the same group shared common properties, the curves still showed differences within the same group.Characteristic reflectance curves of soil surface features were derived from spectral measurements both in the field and in the laboratory, and mean reflectance values derived from image pixels representing known features. Linear unmixing and spectral angle matching techniques were applied to assess their suitability in mapping surface features for land degradation studies. The study showed that linear unmixing provided more realistic results for mapping “desert-like” surface features than the spectral angle matching technique.  相似文献   

酒钢黑沟矿爆破效应研究     

苏宏伟 《高原地震》2003,15(1):51-54

利用爆破记录的原始资料，计算出地动位移、振动速度，然后确定K、α值。根据不同建筑物的安全振动速度，给出安全爆破的最大Q(炸药量)的参考值。  相似文献   

岩矿石吸收系数的算和测定方法     

刘海滨 《吉林地质》1996,(2)

岩矿石吸收系数是钻孔电磁波法解决地质问题的重要的物性参数。岩矿石有无吸收系数的差异，是开展钻孔电磁波法能否奏效的前提．了解岩矿石的吸收系数可对钻孔电磁波法的透距和分辨力作出估计，并可为钻孔电磁波的反演解释提供重要的依据．本文不但给出了岩矿石吸收系数的计算方法，也给出了室内岩矿石标本吸收系数的测定方法和野外实测岩矿石吸收系数的方法。  相似文献   

黑龙江省及其邻区非构造性地震振动研究     

孟宪森  郑辉  关玉辉  王晓峰  姜锦华 《中国地震》2004,20(2):197-203

应用周期-频度谱方法对黑龙江省数字地震台网资料进行处理，给出了矿震、电缆应力释放、震源车作业、火山地震等振动的周期-频度谱和链波指数，并对构造地震和爆破的链波指数进行了讨论。针对港震公司的数字地震记录格式编写了专门的处理程序，为数字地震台站开展周期-频度谱分析提供了有力的工具。  相似文献   

Assessment of predictions of the response of the Hualien containment model during forced vibration tests     

J. Enrique Luco  Francisco C. P. de Barros 《Soil Dynamics and Earthquake Engineering》2004,24(12):1013-1035

Blind predictions for the response of the 1/4-scale reinforced concrete Hualien (Taiwan) containment model during forced vibration tests are compared with the observed data. The predictions obtained by the CLASSI approach reflect the experimental conditions prior to and after backfill of the soil surrounding the embedded foundation. The experimental data show a strong and unexpected coupling between the response in the NS and EW directions which is not present in the results for the axisymmetric theoretical models. Also, significant differences can be seen between the experimental responses in the two orthogonal horizontal directions which minimize cross-axis coupling. Although these differences are not accounted for in the theoretical models, the discrepancies between predictions and observations are within the uncertainty of the structural and geotechnical data. The obtained differences between predictions and observations give an excellent measure of the prediction error that can be expected in this type of analysis from uncertainty in the data. A detailed assessment of the initial structural and geotechnical data based on extensive comparisons with the results of previous identification studies is also presented. Finally, comparisons between the observed response and calculations based on revised models for the structure and the soil show that current methods of analysis can account accurately for the observed response.  相似文献   

Reduction of ground vibration by means of barriers or soil improvement along a railway track   总被引：3，自引：0，他引：3  

L. Andersen  S.R.K. Nielsen 《Soil Dynamics and Earthquake Engineering》2005,25(7-10):701-716

Trains running in built-up areas are a source to ground-borne noise. A careful design of the track may be one way of minimizing the vibrations in the surroundings. For example, open or infilled trenches may be constructed along the track, or the soil underneath the track may be improved. In this work, the influence of the track design and properties on the level of ground vibration due to a vehicle moving with subsonic speed is examined. A coupled finite element-boundary element model of the track and subsoil is employed, adopting a formulation in the moving frame of reference following the vehicle. The computations are carried out in the frequency domain for various combinations of the vehicle speed and the excitation frequency. The analyses indicate that open trenches are more efficient than infilled trenches or soil stiffening–even at low frequencies. However, the direction of the load is of paramount importance. For example, the response outside a shallow open trench may change dramatically when horizontal load is applied instead of vertical load.  相似文献