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1.
吉林敦化—密山断裂带北段琵河口—黄泥河镇之间新发现有多处的霓辉粗面岩,岩石以普遍富含碱性矿物霓辉石为特点,均呈整合接触覆盖于船底山期碱性玄武岩之上,具高位喷发、低位充填特点,全岩K--Ar年龄测定结果 (25. 64±0. 53 Ma、27. 36±0. 45 Ma、28. 45±0. 56 Ma、28. 55±0. 43Ma、28. 63±0. 45 Ma、28. 65±0. 61 Ma)属渐新世。地球化学数据显示,霓辉粗面岩SiO_2质量分数均值为59. 05%,富碱、高钾,亏损大离子亲石元素(Sr、Ba、V、Cr),富集高场强元素(Nb、Ta、Hf、Zr)和轻稀土元素(LREE),∑REE含量很高,具有右倾型稀土分配型式,显示明显Eu负异常。研究表明,霓辉粗面岩是由碱性玄武质岩浆经强烈分离结晶作用形成的,揭示该区渐新世处于一种强烈的拉张环境,幔源岩浆经历了由碱性玄武岩-碱性粗面岩的演化过程。 相似文献
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The igneous rocks of the Katzenbuckel, Southwest Germany, represent a unique and unusual alkaline to peralkaline association within the European Volcanic Province. The magmatic activity can be subdivided into two main phases. Phase I comprises the main rock bodies of phonolite and nepheline syenite, which were later intruded by different peralkaline dyke rocks (tinguaites and alkali feldspar syenite dykes) of phase II. The dyke assemblage was accompanied by magnetite and apatite veins and was followed by a late-stage pneumatolytic activity causing autometasomatic alterations.
As is typical for alkaline to peralkaline igneous rocks, early mafic minerals of phase I rocks comprise olivine, augite and Fe–Ti oxides, which are substituted in the course of fractionation by Na-amphibole and Na-pyroxene. For the early magmatic stage, calculated temperatures range between 880 and 780 °C with low silica activities (0.4 to 0.6) but high relative oxygen fugacities between 0.5 and 1.9 log units above the FMQ buffer. Even higher oxygen fugacities (above the HM buffer) are indicated for the autometasomatic alteration, which occurred at temperatures between 585 and 780 °C and resulted in the formation of pseudobrookite and hematite.
The unusually high oxygen fugacities (even during the early magmatic stage) are recorded by the major element compositions of the mafic minerals (forsterite content in olivine between 68 and 78 mol%, up to 6.2 wt.% ZrO2 and 8.5 wt.% TiO2 in clinopyroxene), the unusual mineral assemblages (pseudobrookite, freudenbergite) and by the enrichment of Fe3+ in the felsic minerals (up to 2.8 wt.% Fe2O3 in alkali feldspar and up to 2.6 wt.% Fe2O3 in nepheline). These observations point to a metasomatically enriched and highly oxidized lithospheric mantle as a major source for the Katzenbuckel melts. 相似文献
3.
Michael A.W. Marks Roberta L. Rudnick Thomas Ludwig Horst Marschall Thomas Zack Ralf Halama William F. McDonough Detlef Rost Thomas Wenzel Edward P. Vicenzi Ivan P. Savov Rainer Altherr Gregor Markl 《Geostandards and Geoanalytical Research》2008,32(3):295-310
Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ7Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ7Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request. 相似文献
4.
The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km2 area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which
are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite
and quartz veins.
The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock,
alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite,
volcanic tuff, phosphatic rock and chert breccia.
The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow
level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly
alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic
than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits
with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other
as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate
and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction
with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ18O and δ13C) on carbonatites of Samchampi have indicated that the δ13C of the source magma is related to contamination from recycled carbon. 相似文献
5.
四川冕宁霓石碱长花岗岩中的贝塔石 总被引：2，自引：0，他引：2
本文研究的贝塔石(betafite)产于川西南冕宁地区某霓石碱长花岗岩体及其霓石-重晶石-碳酸盐脉中,与氟碳铈矿为主的稀土矿物,方铅矿等共生。矿物全部为变生态。 相似文献
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霓石是白云鄂博矿床主要含铁硅酸盐矿物。本文采用俄歇能谱、穆斯堡尔谱、X射线衍射、红外光谱及电子探针等现代测试手段研究了该矿床中两种霓石样品(AW-1、AW-2)的特征及差异。研究表明,它们均呈长柱状晶体,AW-1端部较尖锐,AW-2端部较粗钝。晶体化学式及晶胞参数分别为:AW-1:(Na_(1.269)Ca_(0.001))_(1.270)(Fe_(0.755)Mg_(0.045)Al_(0.063)Ti_(0.003))_(0.666)Si_(2.043)O_6,a=0.9635nm,b=0.8782nm,c=0.5290nm;AW-2:(Na_(1.64)Ca_(0.016))_(1.18)(Fe_(0.902)Mg_(0.002)Al_(0.089) Ti_(0.007) Ce_(0.002) Mn_(0.002))_(1.004) Si_(1.947)O_6,a=0.9636nm b=0.8772nm c=0.5307nm。AW-1较AW-2晶形完整,晶体破裂主要是沿着垂直于Fe—O方向断裂,断裂面存在大量Fe~(3+)和少量Si~(4+),无明显Na~+存在,且讨论了其选矿意义。 相似文献
8.
The Tenda crystalline massif (northern Corsica) is a fragment of the western Corsica basement involved in the Alpine orogeny. Rhyolite dykes crosscutting the gabbroic complex of Bocca di Tenda (southern sector of the Tenda crystalline massif) show an unusual metamorphic mineral assemblage, defined by jadeite‐bearing (up to 46 mol percentage) aegirine, riebeckite, celadonite‐rich phengite (Si=3.50–3.65 apfu), quartz, albite and K‐feldspar. Jadeite‐bearing aegirine and riebeckite mostly occur as coronas around jadeite‐free aegirine and arfvedsonite, respectively, which both are relics of igneous origin. This metamorphic assemblage reflects the peralkaline compositions, which are characterised by anomalously high contents of SiO2 and Na2O, and negligible CaO and MgO. The evolved rocks of the gabbroic sequence (quartz‐diorites to tonalites) and the surrounding granitoids are characterised by the development of riebeckite/ferroglaucophane, epidote, celadonite‐rich phengite and albite, thus pointing to a metamorphic crystallization in the epidote‐blueschist facies. In all the studied rocks, metamorphic reactions were controlled by fluid‐assisted mass‐transfer through grain boundaries and microfractures. The different mineral assemblages allow the peak P–T metamorphic conditions to be constrained to between 0.8 GPa/300 °C and 1.1 GPa/500 °C. These estimates attest to a geothermal gradient (dT/dP) of 10–13 °C km?1 and indicate that the Tenda crystalline massif was buried to a minimum depth of 27 km during the Alpine orogeny. The blueschist facies recrystallization in the Tenda crystalline massif has been related to the cessation of an eastward‐dipping subduction event. 相似文献
9.
大别山超高压变质带是华北与扬子板块俯冲碰撞作用的产物。迄今为止，报导的超高压变质岩除镁铁、超镁铁质岩石外，主要为火山－沉积岩，然而除上述岩石外，大别山南部出露大量花岗质片麻岩。作者在近期对大别山东南部变质花岗岩岩石学研究中发现：变质花岗岩中含有Ｇｔ＋Ｒｕ＋Ｐｈｅ±Ａｃｇ＋Ａｕｇ±Ｄｉ＋Ｐｌ＋Ｎａ－Ａｍｐ＋Ｏｒ＋Ｑ组合，与钠长石共生的霓石或透辉石可能是早期矿物硬玉或富硬玉质绿辉石退变的，而岩石中石榴石分带特征，即内带以铁铝榴石（４３．０６％）和钙铝榴石（４６．２８％）为主，外带则以锰铝榴石（３０．４０％）和钙铝榴石（３５．６７％）为主，这些都表明它们是由高压向低压退化变质之产物。因此，变质花岗岩可能早期存在着这样的榴辉岩相峰期矿物组合Ｊｄ／ｏｍｐ＋Ｑ／ＣＳ＋Ｐｈｅ＋Ｒｕ＋Ｇｔ＋Ｏｒ，这个组合由于后期的压力降低而退变为中低压的矿物组合。 相似文献
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