烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

南海北部陆坡西部海域“海马”冷泉甲烷渗漏及其海底表征     

赵静  梁前勇  尉建功  陶军  杨胜雄  梁金强  陆敬安  王建军  方允鑫  龚跃华  何雪宝 《地球化学》2020,(1):108-118

2015年3月"海马"号遥控无人潜水器(ROV)在南海北部陆坡西部海域首次发现活动冷泉,并命名为"海马"冷泉,此后中国地质调查局广州海洋地质调查局先后组织了3个航次,对"海马"冷泉开展进一步勘查和研究。本次研究在综合分析4个航次调查数据的基础上,初步阐述"海马"冷泉的分布范围、地形地貌、生物群落、自生碳酸盐岩和流体活动等特征。总体而言,"海马"冷泉区地势平缓,气体渗漏现象非常发育,是以CH4为主要气体渗漏形成的活动冷泉区,且气体渗漏活动具有时空迁移性。气体碳同位素组成表明,海马冷泉区的CH4为混合成因气,且以微生物成因为主;"海马"冷泉区发育有多种类型的化能自养冷泉生物群落,冷泉区种类丰富,目前已报道了多个冷泉生物新种。这些发现为研究南海北部陆坡西部海域天然气水合物分解及其环境效应、冷泉生物生命起源与演化和南海与印度洋及太平洋物种迁移贯通等科学问题提供重要依据。  相似文献   

Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence     

《China Geology》2020,3(4):602-610

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.  相似文献   

全球主要河流流域碳酸盐岩风化碳汇评估   总被引：7，自引：0，他引：7  

李朝君  王世杰  白晓永  谭秋  李汇文  李琴  邓元红  杨钰杰  田诗琪  胡泽银 《地理学报》2019,74(7):1319-1332

碳酸盐岩风化吸收的大气CO₂主要以HCO₃ ^-形式连续地经由河流从大陆输送到海洋,成为陆地生态系统的重要碳汇。目前主要河流流域的碳酸盐岩风化碳汇估算存在不确定性,分布格局尚不清晰。基于GEMS-GLORI全球河流数据库提供的全球10万km ²以上主要河流流域多年平均监测数据,利用水化学径流法估算出全球主要河流流域碳酸盐岩对CO₂的吸收速率为0.43±0.15 Pg CO₂ yr ^-1,平均CO₂吸收通量为7.93±2.8 t km ^-2 yr ^-1。CO₂吸收通量在不同气候带下差异显著,热带和暖温带CO₂年吸收速率占全球主要河流流域年吸收速率的62.95%。冷温带CO₂年吸收速率占全球主要河流流域的33.05%,仅次于热带地区。本文划分出全球CO₂吸收通量的9个关键带,关键带的交汇处CO₂吸收通量较高。喀斯特出露流域碳酸盐岩对CO₂吸收通量的均值为8.50 t km ^-2 yr ^-1,约为非喀斯特流域的3倍。全球喀斯特出露流域碳酸盐岩风化碳汇在全球碳循环、水循环及碳收支平衡估算研究方面占据重要地位。  相似文献   

Are carbonate barrier islands mobile? Insights from a mid to late-Holocene system,Al Ruwais,northern Qatar     

John Rivers  Max Engel  Robert Dalrymple  Ruqaiya Yousif  Christian J. Strohmenger  Ismail Al-Shaikh 《Sedimentology》2020,67(1):534-558

Barrier islands are important landforms in many coastal systems around the globe. Studies of modern barrier island systems are mostly limited to those of siliciclastic realms, where the islands are recognized as mobile features that form on transgressive coastlines and migrate landward as sea-level rises. Barrier islands of the ‘Great Pearl Bank’ along the United Arab Emirates coast are the best-known carbonate examples. These Holocene islands, however, are interpreted to be anchored by older deposits and immobile. The mid-Holocene to late-Holocene depositional system at Al Ruwais, northern Qatar, provides an example of a mobile carbonate barrier island system, perhaps more similar to siliciclastic equivalents. Sedimentological and petrographic analyses, as well as ¹⁴C-dating of shells and biogenic remains from vibracored sediments and surface deposits, show that after 7000 years ago a barrier system with a narrow back-barrier lagoon formed along what is now an exposed coastal zone, while, contemporaneously, a laterally-extensive coral reef was forming immediately offshore. After 1400 years ago the barrier system was forced to step ca 3 km seaward in response to a sea-level fall of less than 2 m, where it re-established itself directly on the mid-Holocene reef. Since that time, the barrier has retreated landward as much as 1000 m to its current position, exposing previously-deposited back-barrier lagoonal sediment at the open-coast shoreline. In modern neritic warm-water carbonate settings mobile barrier island systems are rare. Their construction and migration may be inhibited by reef formation, early cementation, and the relative inefficiency of sourcing beach sediments from open carbonate shelves. Carbonate barrier island systems likely formed more commonly during geological periods when ramps and unrimmed shelves predominated and in calcite seas, when meteoric cementation was minimized as a result of initial calcitic allochem mineralogy. As with their siliciclastic analogues, however, recognition of the influence of these transient landforms in the rock record is challenging.  相似文献   

青藏高原凯蒙蛇绿混杂岩中碱性火山岩的发现及意义     

潘政  史仁灯  黄启帅  陈生生  龚小晗  吴钪  杨可 《岩石矿物学杂志》2020,39(1):18-34

班公湖-怒江洋的关闭时间直接制约青藏高原早期构造演化的认识。最近,在班公湖-怒江缝合带南侧凯蒙蛇绿混杂岩中发现一碱性火山岩,岩性主要是橄榄粗安岩,具粗面结构,斑晶主要是更长石和少量普通辉石,基质主要由更长石、普通辉石和少量填隙的碱性长石组成,有的具辉绿结构。岩石化学成分较一致,Si O2含量介于51.34%~53.91%之间,Ti O2含量为1.02%~1.55%,具有高Al2O3(17.06%~18.46%)和Na2O(4.90%~6.36%)、低K2O(0.05%~0.88%)含量特点,大多数Mg#大于60,最高68.62,里特曼指数(σ)介于3.65~4.47之间,为碱性系列火山岩;富集Sr、Rb、Ba等大离子亲石元素,亏损Nb、Y、Yb等高场强元素,相对富集Zr、Ti,Nb/U、Zr/Nb、La/Yb等比值稳定,分别为7.45~8.51、15.92~17.26和7.26~8.06;(87Sr/86Sr)i值变化范围较小,介于0.706~0.707之间,(143Nd/144Nd)t值在0.512 368~0.512 548之间,说明源区较为一致,结合Ce/Pb-Si O2图解判断结果,认为凯蒙碱性火山岩具有原始地幔、陆壳和深海沉积物源区混合特征。锆石U-Pb同位素定年结果表明该火山岩年龄为101.8±1.1 Ma,可能形成于洋壳俯冲阶段末期,由大陆边缘陆壳与俯冲洋壳板片断离导致软流圈地幔上涌诱发部分熔融所致,推测班公湖-怒江洋大约在早白垩世晚期关闭。  相似文献   

山东莱芜盆地碳酸盐岩热液溶蚀特征及水文地质意义   总被引：1，自引：0，他引：1  

刘元晴  周乐  李伟  王新峰  马雪梅  吕琳  邓启军  陈晨 《现代地质》2020,34(1):199-206

鲁中山区莱芜盆地在燕山期发生大规模岩浆侵入活动,岩浆岩体外围碳酸盐岩区分布有水源地、富水块段等岩溶发育富水区,且靠近岩体含水层多发生大理岩化。富含CO₂、H₂S等酸性成分的岩浆热液流体,能对碳酸盐岩产生明显的溶蚀作用。基于岩石样品化学组分分析、水文地质调查及数据统计分析、热液溶蚀地质点详细观测,构建热液溶蚀模式,对莱芜盆地及外围热液溶蚀特征及机理进行研究。结果表明:高温高压岩浆侵入使得接触带碳酸盐岩发生热液变质大理岩化;沿渗透性断裂、裂缝以及不整合面等运移的热液流体,对碳酸盐岩地层产生酸性热液溶蚀和混合溶蚀作用,形成不同规模溶蚀孔洞,构成地下水富集空间,为寻找城镇地下水后备水源地提供新方向。  相似文献   

Adding the missing third and fourth dimensions to trajectory analysis in carbonate systems     

Philipp Tesch  Robert S. Reece  James R. Markello  Juan Carlos Laya  Michael C. Pope 《Basin Research》2020,32(2):388-401

We developed a seismic geomorphology-based procedure to enhance traditional trajectory analysis with the ability to visualize and quantify lateral variability along carbonate prograding-margin types (ramps and rimmed shelves) in 3D and 4D. This quantitative approach analysed the shelf break geometric evolution of the Oligo-Miocene carbonate clinoform system in the Browse Basin and delineated the feedback between antecedent topography and carbonate system response as controlling factor on shelf break rugosity. Our geometrical analysis identified a systematic shift in the large-scale average shelf break strike direction over a transect of 10 km from 62° to 55° in the Oligo-Miocene interval of the Browse Basin, which is likely controlled by far-field allogenic forcing from the Timor Trough collision zone. Plotting of 3D shelf break trajectories represents a convenient way to visualize the lateral variability in shelf break evolution. Shelf break trajectories that indicate contemporaneous along-strike progradation and retrogradation correlate with phases of autogenic slope system re-organization and may be a proxy for morphological stability of the shelf break. Shelf break rugosity and shelf break trajectory rugosity are not inherited parameters and antecedent topography does not dictate long-term differential movement of the shelf margin through successive depositional sequences. The autogenic carbonate system response to antecedent topography smooths high-rugosity areas by filling accommodation and maintains a relatively constant shelf break rugosity of ~150 m. Color-coding of the vertical component in the shelf break trajectory captures the creation and filling of accommodation, and highlights areas of the transect that are likely to yield inconsistent 2D sequence stratigraphic interpretations.  相似文献   

Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone,NW Italy)     

Barbara E. Kunz  Richard W. White 《Journal of Metamorphic Geology》2019,37(7):935-950

The development of thermodynamic models for tonalitic melt and the updated clinopyroxene and amphibole models now allow the use of phase equilibrium modelling to estimate P–T conditions and melt production for anatectic mafic and intermediate rock types at high‐T conditions. The Permian mid‐lower crustal section of the Ivrea Zone preserves a metamorphic field gradient from mid amphibolite facies to granulite facies, and thus records the onset of partial melting in metabasic rocks. Interlayered metabasic and metapelitic rocks allows the direct comparison of P–T estimates and partial melting between both rock types with the same metamorphic evolution. Pseudosections for metabasic compositions calculated in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system are presented and compared with those of metapelitic rocks calculated with consistent end‐member data and a–x models. The results presented in this study show that P–T conditions obtained by phase equilibria modelling of both metabasic and metapelitic rocks give consistent results within uncertainties, allowing integration of results obtained for both rock types. In combination, the calculations for both metabasic and metapelitic rocks allows an updated and more precisely constrained metamorphic field gradient for Val Strona di Omegna to be defined. The new field gradient has a slightly lower dP/dT which is in better agreement with the onset of crustal thinning of the Adriatic margin during the Permian inferred in recent studies.  相似文献   

Single subduction zone for the generation of Devonian ophiolites and high‐P metamorphic belts of the Variscan Orogen (NW Iberia)     

Rubn Díez Fernndez  Ricardo Arenas  Sonia Snchez Martínez  Irene Novo‐Fernndez  Richard Albert 《地学学报》2020,32(4):239-245

Within the Variscan Orogen, Early Devonian and Late Devonian high‐P belts separated by mid‐Devonian ophiolites can be interpreted as having formed in a single subduction zone. Early Devonian convergence nucleated a Laurussia‐dipping subduction zone from an inherited lithospheric neck (peri‐Gondwanan Cambrian back‐arc). Slab‐retreat induced upper plate extension, mantle incursion and lower plate thermal softening, favouring slab‐detachment within the lower plate and diapiric exhumation of deep‐seated rocks through the overlying mantle up to relaminate the upper plate. Upper plate extension produced mid‐Devonian suprasubduction ocean floor spreading (Devonian ophiolites), while further convergence resulted in plate coupling and intraoceanic ophiolite imbrication. Accretion of the remaining Cambrian ocean heralded Late Devonian subduction of inner sections of Gondwana across the same subduction zone and the underthrusting of mainland Gondwana (culmination of NW Iberian allochthonous pile). Oblique convergence favoured lateral plate sliding, and explained the different lateral positions along Gondwana of terranes separated by Palaeozoic ophiolites.  相似文献