琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素     

刘杰  杨睿  邬黛黛  金光荣  张辉 《海洋学报》2019,41(8):13-25

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律，定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上，分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后，综合各因素的历史演化过程，初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大；水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件；超过600 m水深的海域水合物稳定带厚度大部分超过 100 m，其中西北部稳定带的最大厚度超过300 m，是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果，推测其形成与天然气水合物的分解释放有关。  相似文献   

南海北部陆坡西部海域“海马”冷泉甲烷渗漏及其海底表征     

赵静  梁前勇  尉建功  陶军  杨胜雄  梁金强  陆敬安  王建军  方允鑫  龚跃华  何雪宝 《地球化学》2020,(1):108-118

2015年3月"海马"号遥控无人潜水器(ROV)在南海北部陆坡西部海域首次发现活动冷泉,并命名为"海马"冷泉,此后中国地质调查局广州海洋地质调查局先后组织了3个航次,对"海马"冷泉开展进一步勘查和研究。本次研究在综合分析4个航次调查数据的基础上,初步阐述"海马"冷泉的分布范围、地形地貌、生物群落、自生碳酸盐岩和流体活动等特征。总体而言,"海马"冷泉区地势平缓,气体渗漏现象非常发育,是以CH4为主要气体渗漏形成的活动冷泉区,且气体渗漏活动具有时空迁移性。气体碳同位素组成表明,海马冷泉区的CH4为混合成因气,且以微生物成因为主;"海马"冷泉区发育有多种类型的化能自养冷泉生物群落,冷泉区种类丰富,目前已报道了多个冷泉生物新种。这些发现为研究南海北部陆坡西部海域天然气水合物分解及其环境效应、冷泉生物生命起源与演化和南海与印度洋及太平洋物种迁移贯通等科学问题提供重要依据。  相似文献   

黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系   总被引：1，自引：0，他引：1  

夏鹏  付勇  杨镇  郭川  黄金强  黄明勇 《地质学报》2020,94(3):947-956

通过矿物组分、主量元素、微量元素、碳氧同位素等特征，分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明，牛蹄塘组下段以硅质页岩为主，TOC含量4. 96%~10. 10%；上段以富泥硅质页岩为主，TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境，沉积古水体为贫氧的还原状态；上段富泥硅质页岩沉积时期，仍为贫氧的还原环境，但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素，热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。  相似文献   

钻井局域网实时监控设备研发          下载免费PDF全文

韩晓玲  闫思江  韩文峰  张圣杰  韩红玲 《探矿工程》2020,47(12):30-35

为实现钻井指挥部对各钻井站点钻采工艺的远程监控，在前期钻井工艺参数自动实时监测的单机研发基础上,本文应用TIA portal软件进行主站从站组网监控研究，实验设备用Siemens1200PLC做主控机，用Siemens200PLC做从站控制机监控钻采现场工艺参数，通过主控机与各从站点组态，实现主控机对从站主从控制。装机后在钻采现场进行了无线网传输实验，实验结果表明:应用互联网通信技术解决无线网断点续传问题，能够实现了钻采实时监控数据短距离传输。  相似文献   

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

Exploration prospects of oil and gas in the Northwestern part of the Offshore Indus Basin,Pakistan     

《China Geology》2020,3(4):633-642

Oil and gas resources are short in Pakistan and no commercially viable oil and gas sources have been yet discovered in its offshore areas up to now. In this study, the onshore-offshore stratigraphic correlation and seismic data interpretation were conducted to determine the oil and gas resource potential in the Offshore Indus Basin, Pakistan. Based on the comprehensive analysis of the results and previous data, it is considered that the Cretaceous may widely exist and three sets of source rocks may be developed in the Offshore Indus Basin. The presence of Miocene mudstones has been proven by drilling to be high-quality source rocks, while the Cretaceous and Paleocene–Eocene mudstones are potential source rocks. Tectonic-lithologic traps are developed in the northwestern part of the basin affected by the strike-slip faults along Murray Ridge. Furthermore, the Cretaceous and Paleocene–Eocene source rocks are thick and are slightly affected by volcanic activities. Therefore, it can be inferred that the northwestern part of Offshore Indus Basin enjoys good prospects of oil and gas resources.  相似文献   

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药     

时磊  孙艳艳  沈小明  吕爱娟  蔡小虎  刘娇  沈加林 《岩矿测试》2020,39(6):856-865

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。  相似文献   

微生物勘探技术在潮汕坳陷油气勘探中的应用初探     

赵忠泉  孙鸣  万晓明  陈胜红  赵静  宋立军  李辉  强昆生  梁永兴 《中国地质》2020,47(3):645-654

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。  相似文献   

滇西南钾盐调查MK-3大口径超深井绳索取心钻进工艺          下载免费PDF全文

吕利强 《探矿工程》2020,47(3):53-58

滇西南中生代盐盆地钾盐资源调查评价项目MK-3井，设计井深2700 m，全孔取心，岩心直径≮80 mm，一般井段岩心采取率达到80%以上，盐岩段岩心采取率＞95%。工程技术要求高，施工难度大。施工中遇到了地层坍塌、涌水、掉块、盐岩溶蚀等问题，通过采用氯化镁饱和盐水冲洗液，HXY-9B型钻机取心钻进、TSJ-2000型水源钻机扩孔钻进，分级下管隔离等措施，圆满完成了钻探任务。完钻井深2701 m，岩心采取率90%，盐岩段岩心采取率达98.65%，终孔口径127 mm，岩心直径81 mm。经地球物理测井，各项指标都达到了设计要求。刷新了国内CHD127标准绳索取心钻杆P口径钻探深度的记录。  相似文献   

Relationship Between Electrical Properties and Sedimentary Environment of the Longmaxi Formation Shale, Southern Sichuan     

YANG Kai  ZHANG Bing  WANG Xuben  HE Lanfang  YANG Hongyu  WANG Pengwan  TANG Jialin  DENG Jixin  ZHANG Cong 《《地质学报》英文版》2020,94(5):1531-1546

The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献