湿法冶锰废渣中锰的形态分析与应用   总被引：1，自引：0，他引：1  

雷忠平  李金岩  田宗平 《矿产与地质》2008,22(1):83-86

将湿法冶锰废渣经过烘干、研细等预处理,按其所使用的原材料进行形态研究,通过筛选和实验,确定了废渣中的锰可用形态分析方法。在弄清废渣中锰的各种形态及含量的基础上,将其成果进行转化,用于指导工业生产、环境评价和废渣处理,具有很好的经济效益和社会效益。  相似文献   

氧化锰矿物的生物成因及其性质的研究进展   总被引：5，自引：0，他引：5  

刘凡  冯雄汉  陈秀华  邱国红  谭文峰  贺纪正 《地学前缘》2008,15(6):66

土壤中的氧化锰矿物是原生矿物风化和成土过程的产物,是最具反应活性的一类矿物,决定着环境中许多物质的形态、迁移和转化,在元素生物地球化学循环中起着重要的作用,其形成机制和环境效应备受关注。已有的研究表明,环境中氧化锰的形成与微生物作用紧密相关,微生物作用可使自然环境中的Mn(Ⅱ)氧化速率提高105倍。参与Mn(Ⅱ)氧化的微生物在环境中广泛存在,已知的典型锰氧化细菌分布在变形菌门、放线菌门或厚壁菌门,它们均通过胞外聚合物中的多铜氧化酶来催化氧化Mn(Ⅱ)。细菌氧化Mn(II)成Mn(Ⅳ)是酶催化的两个连续的快速单电子传递过程,Mn(Ⅲ)在溶液中以与酶结合的瞬时中间态出现。生物形成氧化锰的最初形态为层状锰矿物,与δ-MnO2或酸性水钠锰矿很类似,且结晶弱,粒径小,锰氧化度高,结构中的八面体空穴多,因而比化学形成的氧化锰具有更强的吸附、氧化等表面活性。环境中Mn(Ⅱ)微生物氧化及形成的Mn(Ⅲ)中间体与碳、氮、硫等生命元素的地球化学循环的关系令人关注。  相似文献   

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China     

Bo PENG Shurong XIE Meilian XIAO Fucheng WU Zhi SONG 《中国地球化学学报》2006,25(B08):23-24

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.  相似文献   

Oxidation of AsⅢ by Several Manganese Oxide Minerals in Absence and Presence of Goethite     

FENG Xionghan  TAN Wenfeng  LIU Fan  Huada Daniel RUAN  HE Jizheng 《《地质学报》英文版》2006,(2)

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Cathodoluminescence of authigenic albite     

Detlev K. Richter  Thomas G  tte  Dirk Habermann 《Sedimentary Geology》2002,150(3-4):367-374

Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn²⁺- and Fe³⁺-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE).  相似文献   

吉林省土壤中有效锰、铜、钼和锌含量的时空变化   总被引：5，自引：0，他引：5  

杨娟  王冬艳 《世界地质》2003,22(4):392-395

选择吉林省的五个大豆种植区(敦化、桦甸、榆树、农安、白城)、四个水稻种植区(白城、九台、延吉、梅河口)及3个草场分布区(镇赉、洮南、大安)，对其土壤中有效锰、铜、钼和锌的含量在过去20年的变化作了比较和分析。经研究表明：吉林省土壤中有效锰和有效铜含量较20年前有所增高，有效钼含量总体呈降低趋势，中部部分地区和东部地区土壤有效锌含量降低，其余地区含量增高。空间分布东部高于中西部。  相似文献   

Comparison of Cu and Zn cycling in eutrophic lakes with oxic and anoxic hypolimnion     

HanBin Xue  René Gächter  Laura Sigg 《Aquatic Sciences - Research Across Boundaries》1997,59(2):176-189

Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation 1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by freshly formed Mn- and Fe-oxides.  相似文献   

重庆城口高燕锰矿床矿物解离度与工艺粒度研究     

张燕  宋志娇  陈翠华  张自贤 《地质论评》2016,62(S1):285-286

随着当前矿产资源日趋贫、细、杂,合理利用低品位和复杂多金属矿石是目前选矿工作的重要问题（吴荣庆, 2008）,只有通过对矿物原料或产物中元素或矿物的状态和性质的系统研究,阐明其行为规律,指导和配合矿物加工研究和生产,才能有针对性地选择选矿方法和工艺流程（贾木欣, 2007）,实现对矿物资源的综合利用（吕宪俊,2001）。而矿物工艺粒度、解离度对选矿发挥着不可缺少的重要作用。矿物解离是选矿的必要条件之一,矿物工艺粒度、磨矿粒度等因素对矿物解离度都有影响,这些因素致使解离度和工艺粒度之间关系复杂化（洪秉信,傅文章., 2012）。本文通过对重庆城口高燕锰矿床矿物解离度与工艺粒度的研究,从而探讨解离度与工艺粒度对选矿加工的影响。  相似文献   

Stability,transformations and stabilizing potential of an amorphous manganese oxide and its surface-modified form in contaminated soils     

《Applied Geochemistry》2016

A surface-modified amorphous manganese oxide (SM-AMO) was prepared to increase the stability of a previously studied promising stabilizing agent and to compare its immobilizing efficiency with respect to contaminating metals with the original material. To synthesize the SM-AMO, the AMO surface was synthetically covered with a coating of MnCO₃ because newly formed rhodochrosite precipitates were previously found to increase the stability of AMO particles in soils. A preliminary experiment evaluating the long-term stability of both materials in pure water suggested higher stability for the SM-AMO particles, showing a smaller release of Mn compared to the original AMO. An adsorption kinetics study focused on As, Cd, Pb and Zn showed lower adsorption rates and adsorption capacity for Zn, probably as a result of partial surface passivation. In comparison to these results for simple controlled systems, different effects were recorded when the two materials were applied to contaminated soils. When incubated in soil, a constantly lower mass loss was recorded in the case of SM-AMO. There were no significant differences in the release of Mn and DOC into the soil solution or in the stabilizing efficiency with regard to contaminating metal(loid)s between the original and surface-modified materials. Concerning the potential solid phase transformations in soil conditions, we observed a gradual equilibration between the surface composition of both materials. While the newly formed rhodochrosite precipitated on the AMO surface, the MnCO₃ coatings on SM-AMO gradually dissolved. Both amendments also effectively supported microbial activity, especially in the more contaminated soil sample. Thus, despite the smaller mass loss, the effectiveness of both materials is comparable in the long term.  相似文献   

湘西北烂泥田锰矿区地质特征与成矿地质条件及成因   总被引：1，自引：0，他引：1       下载免费PDF全文

陈明辉  杨长明  潘君庆  梁惠敏  鲍振襄 《地质找矿论丛》2016,31(4):515-521

湘西北锰矿资源丰富,主要为赋存于南华系大唐坡组下段黑色页岩中。通过对烂泥田锰矿床研究表明,成矿物质来源为深源富锰热液及古陆等多种来源,锰以氧化物或氢氧化物的形式沉淀,菱锰矿的生成与藻类活动密切相关,属于化学-生物化学沉积成因矿床。湘西北地区南华系内自下而上构成钼钒矿→磷矿→锰矿→铅锌矿组成的矿床组合成矿系列,可进行综合找矿、综合评价、扩大矿床经济效益。  相似文献