EFFECT OF SULPHATE-REDUCING BACTERIA ON ELECTRO-CHEMICAL CORROSION BEHAVIOR OF 16Mn STEEL IN SEA MUD     

张经磊  侯保荣  郭公玉  孙虎元  徐岩 《中国海洋湖沼学报》2001,19(1):87-90

ＩＮＴＲＯＤＵＣＴＩＯＮＩｔｗａｓｇｅｎｅｒａｌｌｙｃｏｎｓｉｄｅｒｅｄｐｒｅｖｉｏｕｓｌｙｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｏｆｓｔｅｅｌｉｎｓｅａｍｕｄｗａｓｎｏｔｓｅｒｉｏｕｓ.Ｈｏｗｅｖｅｒ,ｉｔｗａｓｌａｔｅｒｆｏｕｎｄｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒａｔｅｏｆｓｔｅｅｌｉｎｓｏｍｅｓｅａｍｕｄｗａｓｈｉｇｈｅｒｔｈａｎｔｈａｔｉｎｓｅａｗａｔｅｒ(Ｋｉｎｇ,1980;Ｓｅｈｍｉｄｅ,1982;Ｇｕｏｅｔａｌ.,1997;Ｈｏｕ,1998).Ｔｈｅｒｅａｒｅｓｏｍｅｒｅｐｏｒｔｓｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒ…  相似文献   

An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate   总被引：1，自引：0，他引：1  

Aikaterini I. Vavouraki  Christine V. Putnis  Andrew Putnis  Petros G. Koutsoukos   《Chemical Geology》2008,253(3-4):243-251

In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na₂SO₄ aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.  相似文献   

陕西白河县月儿潭绿松石与次生磷钙铝矾研究     

石振荣  蔡克勤 《岩石矿物学杂志》2008,27(2):164-170

对陕西省白河县月儿潭风化严重的绿松石样品进行了岩石薄片观察、化学成分测试、X射线粉晶衍射和红外吸收光谱分析等研究.结果表明,绿松石风化分解由天蓝色退色成黄绿色,最后变成白色,结构也由致密细腻变得松散多孔,主要原因是发生了硫酸根对磷酸根的交代作用,最终的交代产物主要是磷钙铝矾.  相似文献   

海藻硫酸多糖911对小鼠脾淋巴细胞增殖反应及对细胞产生IL—2作用的影响     

王文涛  张永祥  周金黄  管华诗 《中国海洋大学学报(自然科学版)》1992,(Z1)

本文以~3H—TdR掺入法观察911对小鼠脾淋巴细胞增殖反应的影响并用CTLL细胞检测了其对IL—2的作用。体外实验结果表明,911对小鼠脾淋巴细胞增殖反应有明显的增强作用,以0.5μg/ml的浓度效果最为明显,相对增殖指数RPI可达200％;体内实验则以5mg/kg体重ip,连续7d效果最好,相对增殖指数RPI可达176％;911用药组小鼠IL—2的产生量均高于对照组,以5mg/kg和10mg/kg效果最好。以上实验证明,这一多糖是一种有希望的新免疫调节药物。  相似文献   

Interstitial water chemistry of the inner continental shelf sediments off the gironde estuary     

H. El Ghobary 《Estuarine, Coastal and Shelf Science》1983,16(6)

The interstitial water composition ( , alkalinity, Ca²⁺, Mg²⁺, Sr²⁺, Na⁺, K⁺) and the cation exchange capacity (CEC) were determined for the muddy sediments of the continental shelf off the Gironde Estuary (France), in the area where the sediment represents the deposit of the muddy suspension of the river. In comparison with seawater concentrations, the pore waters below 10 cm depth, show depletions of and Ca²⁺ and below a 30 cm depth show depletions of Mg²⁺. Inversely, the upper 10 cm an enrichment of Ca²⁺ concentration, and an increase of K⁺ concentration to a 40 cm depth. High values of are observed at the top 4 cm. Alkalinity enrichment is observed along the length of the core. Applying the alkalinity models for the sediment below a 10 cm depth demonstrates generally that calculated alkalinities are higher than the measured ones. Ca²⁺ dissolution occurs at the first 10 cm and authigenic carbonate precipitation starts beneath that level. Mg²⁺ depletion is accompanied by bicarbonate loss. This proves that Mg²⁺ depletion is due to a Mg-silicate reaction. The result of the CEC does not confirm the Mg²⁺ uptake by clay minerals in exchangeable site, under reducing conditions. Diffusion and bioturbation play an important role in the pore water concentration at the top of the core.  相似文献   

低硼氢氧化镁的制备及热分解动力学参数     

高荣杰  冯丽娟  杜敏  宁滨  梁丽 《中国海洋大学学报(自然科学版)》2002,32(5):789-794

本文以水合氯化镁、工业氨水为原料制备出了低硼含量的纯度 >99%的氢氧化镁和氧化镁。利用差热 -热重 (DTA- TG)、X-射线衍射 (XRD)、透射电子显微镜 (TEM)等手段 ,对氢氧化镁的热稳定性、相结构、表观状态以及脱水动力学参数进行了分析。结果为 :氢氧化镁以束状纤维和片状粉末共存 ,在 6 2 3K基本完成脱水反应生成氧化镁 ,其脱水反应的表观活化能 E为135 .4 k J· mol-1,指前因子 A为 5 .15× 10 10 ,反应级数 n为 1.10  相似文献   

Growth Aspects and Magnesium Carbonate Concentrations of the Reef Building Octocoral Heliopora coerulea (Pallas) after Transplantation     

B. Velimirov 《Marine Ecology》1980,1(2):155-168

Abstract. An experiment to test C have's hypothesis on temperature dependent MgCO₃ concentrations in marine calcareous skeletons was undertaken by transplanting colonies of Heliopora coerulea. The corals were transferred from a shallow lagoon with high average temperatures to the outer bottom of a fringing reef, 16 m depth, with low average temperatures. Against expectation, a statistically significant increase of average mol % concentrations from 0.48 to 0.54 % for upper growth regions and from 0.49 to 0.62% for lower growth regions was obtained. Temperature records during the experimentation period and the above data indicate that the mol% MgCO₃ concentration in the skeleton of living Heliopora colonies increases when transplanted to an environment with a lower temperature average than that of their original growth site, and with seasonal temperature fluctuations which are smaller in the experimental site than in the control site. Temperature fluctuations at the control site were up to 2.5 times greater than at the experimental site for most of the observation months. This supports the conclusion that the parameters a) minimum temperature and b) temperature stability of the environment are essential for the incorporation of Mg into the carbonate skeleton matrix of marine organisms. Within this study the results of a quantitative chemical analysis of the carbonate skeleton of H. coerulea are presented and growth data of transplanted colonies compared with those from the control site.  相似文献   

硫酸皮肤素寡糖的分离与制备   总被引：2，自引：0，他引：2  

于广利  管华诗  Wang Qun  Hyun OK Yang  Toshihiko Toida 《中国海洋大学学报(自然科学版)》2001,31(6):849-854

利用软骨素酶 ABC (Chondroitinase ABC,EC4 .2 .2 .4 )对硫酸皮肤素 (Dermatan Sul-fate,DS)进行控制降解。对得到的混合寡糖首先采用低压凝胶渗透色谱 (L PGPC)进行分级 ,然后对每一组分再利用强阴离子交换高压液相色谱 (SAX- HPL C)进行分离 ,最终制备出聚合度为 2 ,4 ,6 ,8,10 ,12的寡糖纯品。寡糖纯度采用 SAX- HPL C,毛细管电泳 (CE)以及聚丙烯酰胺凝胶电泳(PAGE)进行检验 ,结构采用电喷雾离子化质谱 (ESI- MS)以及核磁共振波谱 (NMR)技术确定  相似文献   

新疆罗布泊盐湖卤水资源综合开发研究   总被引：10，自引：3，他引：7  

李浩  唐中凡  刘传福  雷光元 《地球学报》2008,29(4):517-524

罗布泊盐湖赋存有丰富的含钾硫酸镁亚型卤水,现已探明仅罗北凹地区段孔隙度储量2.67×109t(折合KCl),属特大型钾盐卤水矿藏,是生产硫酸钾的理想原料;此外,卤水中含有丰富的钠、镁、锂、硼等资源,综合回收利用价值较大。本文针对罗布泊盐湖卤水资源,在有效利用盐湖钾资源同时,加快其他共生资源的综合开发进程,将新疆罗布泊盐湖资源开发建设推向持续、合理、有效、高值的循环经济发展的道路,为国家西部经济开发做出贡献。  相似文献   

Speciation of sulfate components in size-fractionated aerosol particles using sulfur K-edge X-ray absorption near-edge structure （XANES）     

Yoshio Takahashi Yutaka Kanai Hikari Kamioka Atsuyuki Ohta Takuro Miyoshi Hiroshi Shimizu 《中国地球化学学报》2006,25(B08):222-222

Sulfates are a main constituent of aerosols, which sulfate aerosols, it is necessary to determine what can cause various environmental problems sulfate ions are contained in these aerosols In the evaluation of the influence of In this study, sulfur K-edge XANES was used to determine sulfate species present in size-fractionated aerosol particles based on the post-edge structure after the main absorption peak in the XANES region. Aerosol samples were collected as part of the Japan-China joint project, ＂Asian Dust Experiment on Climate Impact＂ using a low-volume Andersen-type air sampler. XANES was measured at Beamline BL-9A at Photon Factory, Japan. A comparison of the XANES spectra of reference sulfate materials and aerosol samples collected in Tsukuba in Japan clearly showed that （NH4）2SO4 was the main sulfur species in particles with a smaller diameter and gypsum was the main sulfur species in particles with a larger diameter. A simulation of the XANES spectra by reference materials allows us to obtain the quantitative mixing ratios of the different sulfate species present in the aerosol samples. The presence of minor sulfur species other than （NH4）2SO4 and gypsum at the surface of mineral aerosols is suggested in our simulations and by a surface-sensitive conversion electron/He-ion yield XANES. In the absence of a contribution from a large dust event, the mole concentration of gypsum in the mineral aerosol fraction determined by XANES is similar to that of Ca which is determined independently using ion chromatography. This shows that the Ca and sulfate in the mineral aerosols are present only as gypsum. Considering that calcite is the main Ca mineral in the original material arising from an arid and semi-arid area in China, it is strongly suggested that gypsum is formed in aerosol during its long-range transportation by a reaction between calcite and sulfate ions.  相似文献