Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts     

Jonathan F. Stebbins  Emily V. Dubinsky  Koji Kanehashi  Kimberly E. Kelsey 《Geochimica et cosmochimica acta》2008,72(3):910-925

Configurational changes with temperature are important for the thermodynamic and transport properties of most aluminosilicate melts, but in general are not well understood. Here, we present high-resolution ²⁷Al and ¹⁷O NMR data on several calcium aluminosilicate glasses prepared with varying quench rates and thus with fictive temperatures that span ranges up to about 200 K. In all compositions the content of five-coordinated aluminum increases with fictive temperature, in agreement with recent high temperature NMR data on melts. In a glass of CaAl₂Si₂O₈ (“anorthite”) composition, the content of non-bridging oxygens also increases with temperature; however this effect was not observed in a sample with a much higher CaO/Al₂O₃ ratio. We present a consistent notation for reactions among structural species in these systems that clarify why in some cases, high-coordinated network cations may appear on the same side of the reaction, while in others they occur on the opposite sides: the key difference is in accounting for all coordination changes for oxygens. Mixing of non-bridging oxygens and of high-coordinated aluminum make significant contributions to the overall configurational entropy and heat capacity of the melts, as does the mixing of various bridging oxygens and of tetrahedral network cations. Other, less well known, types of increase in disorder with temperature may be important as well.  相似文献   

Shoreface translation and the Holocene stratigraphic record: Examples from Nova Scotia, the Mississippi Delta and eastern Australia     

Ron Boyd  Shea Penland 《Marine Geology》1984,60(1-4):391-412

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Cumulative impacts of aggregate extraction on seabed macro-invertebrate communities in an area off the east coast of the United Kingdom     

Keith Cooper  Sin Boyd  John Aldridge  Hubert Rees 《Journal of Sea Research》2007,57(4):288-302

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Effect of fluid-sediment reaction on hydrothermal fluxes of major elements, eastern flank of the Juan de Fuca Ridge     

Emily R. Giambalvo  Carl I. SteefelAndrew T. Fisher  Nina D. RosenbergC.Geoffrey Wheat 《Geochimica et cosmochimica acta》2002,66(10):1739-1757

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Mechanisms of expansion for an introduced species of cordgrass, Spartina densiflora, in Humboldt Bay, California     

Pamela M. Kittelson  Milton J. Boyd 《Estuaries and Coasts》1997,20(4):770-778

The dominant plant in Humboldt Bay salt marshes in Spartina densiflora, a species of cordgrass apparently introduced from South America. At several salt marshes and restoration sites around Humboldt Bay, distribution of this plant has increased significantly. We investigated the relative contributions of vegetative tiller production and seed germination to the establishment and expansion of S. densiflora. Lateral spread of plants surrounded by competitors were compared to areas without competing plant species. Plants growing in areas without competitors had significantly higher rates of vegetative expansion (p<0.0001). Viable seed production, germination rates, seedling survivorship, and growth of adult plants were measured in six salinity treatments. Approximately 1,977±80 viable seeds are produced per plant (0.25–0.5 m²). The number of germinating seeds was inversely related to increases in salinity. Salinity treatments between 19‰ and 35‰ produced significantly lower germination rates than salinities of 0–18‰ (p<0.0001). Seedling survivorship was 50% at ≤4‰ and 8–14% at ≥11‰. Lateral expansion of adult, greenhouse-grown plants occurred in all salinity treatments, with modest decreases in the highest salinity treatments (p<0.05). Our findings indicate that S. densiflora expands primarily by vegetative expansion, and lateral tillers are produced by throughout the year. Spartina densiflora produces prolific amounts of seed, but recruitment in mature salt marshes may be limited by competitors and higher salinities. At restoration sites, planting of native species such as Salicornia virginica, Distichlis spicata, or Jaumea carnosa may prevent monospecific stands of S. densiflora from developing.  相似文献   

How a wet tropical rainforest copes with repeated volcanic destruction     

Leigh C.F. Jago  William E. Boyd 《Quaternary Research》2005,64(3):399-406

The Holocene Period for the province of West New Britain, Papua New Guinea, is characterised by periodic catastrophic volcanism. The region is mantled in dense wet tropical rainforest, and has been occupied by people since the Pleistocene. Analyses of peat from two nearby sites within a lowland rainforest environment provide us with a macro-level landscape account of the periodic destruction and recovery of the coastal forests during seven periods of volcanic activity in the latter part (2900 yr ago to present) of the Holocene. Radiocarbon dating shows the very close correlation of the peat and tephra layers at both sites, yet the pollen analysis reveals different vegetation communities. These initial results allow us to begin identifying the processes of recovery, and to recognise different ecological pressures placed on vegetation at these neighbouring sites. Evidence of hydrological changes are observed beginning with a marine incursion recorded at Garu Site 3 1360 ¹⁴C yr B.P. The distinct differences in the vegetation re-establishment and community regeneration rates suggest the greater level of disturbance at Garu Site 1 could be related to the depth of the ashfall, although the proximity of a known human settlement may also be a contributing factor. Of note, palynologically, we found that the fern spore flora is particularly rich and believe it will be useful for ecological interpretation.  相似文献   

Characterizing and classifying urban watersheds with compositional and structural attributes     

Joseph M. Delesantro  Jonathan M. Duncan  Diego Riveros-Iregui  Joanna R. Blaszczak  Emily S. Bernhardt  Dean L. Urban  Lawrence E. Band 《水文研究》2021,35(9):e14339

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.  相似文献   

New Modes of Environmental Governance in Greater Sage-Grouse Conservation in Oregon     

Katherine Wollstein  Emily Jane Davis 《社会与自然资源》2020,33(5):555-573

Abstract

Natural resource challenges often span administrative jurisdictions and include actors and processes operating at different spatial and political scales. We applied concepts of new environmental governance to analyze Oregon’s approach to greater sage-grouse conservation. Through one in-depth case study in Lake County, we traced features of new environmental governance (cross-scale interactions, decentralization, and capacities of actors) through different governance levels. Interviews and qualitative analysis revealed that decentralization of administrative functions facilitated cross-scale interactions and relied on intermediaries, gap-filling, and perceptions of legitimacy at lower levels. State and agency guidelines steered the effort and were accompanied by financial and technical resources from multiple arenas, which increased local capacity. This study adds to the understandings of environmental governance for implementing multi-actor, multi-level conservation arrangements in resource-dependent communities. Further exploration of connections between higher levels and local contexts will reveal important, new ways to link policies with on-the-ground outcomes.  相似文献   

Engagement in the Third U.S. National Climate Assessment: commitment,capacity, and communication for impact     

Emily Cloyd  Susanne C. Moser  Edward Maibach  Julie Maldonado  Tinqiao Chen 《Climatic change》2016,136(1):39-55

This paper examines the dynamics of energy investments and clean energy Research and Development (R&D) using a scenario-based modeling approach. Starting from the global scenarios proposed in the RoSE model ensemble experiment, we analyze the dynamics of investments under different assumptions regarding economic and population growth as well as availability of fossil fuel resources, in the absence of a climate policy. Our analysis indicates that economic growth and the speed of income convergence across countries matters for improvements in energy efficiency, both via dedicated R&D investments but mostly through capital-energy substitution. In contrast, fossil fuel prices, by changing the relative competitiveness of energy sources, create an economic opportunity for radical innovation in the energy sector. Indeed, our results suggest that fossil fuel availability is the key driver of investments in low carbon energy innovation. However, this innovation, by itself, is not sufficient to induce emission reductions compatible with climate stabilization objectives.  相似文献   

On the relation of vegetation and southwest monsoon rainfall over Western Ghats,India     

T. V. Lakshmi Kumar  Koteswara Rao  R. Uma  Humberto Barbosa  K. V. K. R. K. Patnaik  Emily Prabha Jothi 《Natural Hazards》2016,80(1):425-444

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