Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques     

Alan M Bond  Julie R Bradbury  Henry A Hudson  John S Garnham  Peter J Hanna  Stanley Strother 《Marine Chemistry》1985,16(1):1-9

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.  相似文献   

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa     

Julie Pronost  Chris Harris  Christian Pin 《Mineralium Deposita》2008,43(8):825-848

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.  相似文献   

Controlling geological and hydrogeological processes in an arsenic contaminated aquifer on the Red River flood plain,Vietnam   总被引：1，自引：0，他引：1  

Flemming Larsen  Nhan Quy Pham  Nhan Duc Dang  Dieke Postma  Søren Jessen  Viet Hung Pham  Thao Bach Nguyen  Huy Duc Trieu  Luu Thi Tran  Hoan Nguyen  Julie Chambon  Hoan Van Nguyen  Dang Hoang Ha  Nguyen Thi Hue  Mai Thanh Duc  Jens Christian Refsgaard 《Applied Geochemistry》2008

  相似文献   

An operational multiscale system for hazards prediction, mapping, and response     

David P. Bacon  Nash’at N. Ahmad  Thomas J. Dunn  Michael C. Monteith  Ananthakrishna Sarma 《Natural Hazards》2008,44(3):317-327

By definition, a crisis is a situation that requires assistance to be managed. Hence, response to a crisis involves the merging of local and non-local emergency response personnel. In this situation, it is critical that each participant: (1) know the roles and responsibilities of each of the other participants; (2) know the capabilities of each of the participants; and (3) have a common basis for action. For many types of natural disasters, this entails having a common operational picture of the unfolding events, including detailed information on the weather, both current and forecasted, that may impact on either the emergency itself or on response activities. The Consequences Assessment Tool Set (CATS) is a comprehensive package of hazard prediction models and casualty and damage assessment tools that provides a linkage between a modeled or observed effect and the attendant consequences for populations, infrastructure, and resources, and, hence, provides the common operational picture for emergency response. The Operational Multiscale Environment model with Grid Adaptivity (OMEGA) is an atmospheric simulation system that links the latest methods in computational fluid dynamics and high-resolution gridding technologies with numerical weather prediction to provide specific weather analysis and forecast capability that can be merged into the geographic information system framework of CATS. This paper documents the problem of emergency response as an end-to-end system and presents the integrated CATS–OMEGA system as a prototype of such a system that has been used successfully in a number of different situations.  相似文献   

A summary of the geology and oil habitat of the Eastern Flank Hydrocarbon Province of South Oman     

Aley Al-Marjeby  David Nash 《Marine and Petroleum Geology》1986,3(4)

The Eastern Flank Hydrocarbon Province borders the southeastern edge of the South Oman Salt Basin in the southern part of Oman. An intensive exploration programme by PDO over the past seven years has led to the discovery of almost 2 × 10⁹ m³ of oil with current production of some 15000 m³/d from six fields.In stark contrast to other oil habitats of the Arabian Peninsula, the main play involves rock units and geological events ranging in age from Late Precambrian to Quaternary Times, while trap development and charging are closely related to syn-tectonic salt dissolution.The principal reservoirs and seals are poorly consolidated, Palaeozoic clastics which drape, due to salt dissolution, over residual ‘cores’ principally composed of either Lower Palaeozoic sandstones (Haima Group), or Late Proterozoic carbonates (Huqf Group), or some combination of these. Oils have been geochemically correlated with algal source rocks of the Huqf Eastern Flank. Structures are considered to have been ‘charged’ from Late Mesozoic times onwards in conjunction with progressive subsurface salt removal and the onset of maturation of local source rocks. The effectiveness of ‘charging’ along the retreating salt edge is indicated by the small percentage of dry wells.Major oil zones are found in both anticlinal and truncation traps which are commonly developed around sandstone (Haima Group) cores. Oils show a wide range of characteristics but are typically heavy, early expulsion crudes, high sulphur with little associated gas. Bacterial transformation is not uncommon.Producing reservoirs mainly occur at relatively shallow depths (600–1200 m). Primary recovery factors of around 7% reflect the high density and viscosity of the Eastern Flank crudes and have initiated interest in Enhanced Oil Recovery (EOR) techniques. Two such pilot projects, involving steam and polymer flooding, are due to commence in 1984 and, if successful, will substantially increase the reserve base of these fields.  相似文献   

Spawning of plaice Pleuronectes platessa L. around the Isle of Man, Irish Sea     

Ellis  Tim; Nash  Richard D. M. 《ICES Journal of Marine Science》1997,54(1):84-92

  相似文献   

A new titanium-bearing calcium aluminosilicate phase: II. Crystallography and crystal chemistry of grains formed in slowly cooled melts with bulk compositions of calcium- aluminum-rich inclusions     

David J. Barber  John R. Beckett  Julie M. Paque  Edward Stolper 《Meteoritics & planetary science》1994,29(5):682-690

Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)_UNK | (001)_mel and <10T0>_UNK | <100>_mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. A Ti-free analog with a formula of Ca₃Al₂Si₄O₁₄ synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is   相似文献   

Spectral reflectance change and luminescence of selected salts during 2–10 KeV proton bombardment: Implications for Io     

Robert M. Nelson  Douglas B. Nash 《Icarus》1979,39(2):277-285

Radiation damage and luminescence, caused by magnetospheric charged particles, have been suggested by several authors as mechanisms for explaining some of the peculiar spectral/albedo features of Io. We have pursued this possibility by measuring the uv-visual spectral reflectance and luminescent efficiency of several proposed Io surface constituents during 2 to 10-keV proton irradiation at room temperature and at low temperature (120 < T < 140°K). The spectral reflectance of NaCl and KCl during proton irradiation exhibits the well-known F-center absorption bands at 4580 and 5560 Å. Na₂SO₄ shows a generalized darkening which increases toward longer wavelengths. NaNO₃ shows a spectral reflectance change indicative of the partial alteration of NaNo₃ to NaNo₂. NaNO₂ shows no change. The luminescent efficiencies of NaCl and KCl are ～10^?4 at 300°K and increase by one-half order of magnitude at ～130°K. The efficiencies of K₂CO₃, Na₂CO₃, Na₂SO₄, and NaNO₃ are 10^?4, 10^?4, 10^?5 and 10^?6, respectively, at 300°K and they all decrease by one-half order of magnitude at ～130°K. These results indicate that magnetospheric proton irradiation of Io could cause spectral features in its observed ultraviolet and visible reflection spectrum if salts such as those studied here are present on its surface. However, because the magnitude of these spectral effects is dependent on competing factors such as surface temperature, incident particle energy flux, solar bleaching effects, and trace element abundance, we are unable at this time to make a quantitative estimate of the strength of these spectral effects on Io. The luminescent efficiencies of pure samples that we have studied in the laboratory suggest that charged-particle induced luminescence from Io's surface might be observable by a spacecraft such as Voyager when viewing Io's dark side.  相似文献   

The place of individuals in the politics of scale   总被引：1，自引：0，他引：1  

Julie Cidell 《Area》2006,38(2):196-203

Conceptualizations and re-conceptualizations of scale have been powerful tools for explaining spatial processes that transcend traditionally-bounded territories. Examining the role of individuals within a politics of scale can do even more to explain multi-scalar conflicts. This paper does so by examining struggles over airport expansion in the US, showing how an understanding of the various roles of individuals in the politics of scale – as sites of multiple scales, as actors constituting other scales, and as scales in and of themselves – better explains multi-scalar conflicts and offers more opportunities for resolving them.  相似文献   

Magmatic processes that generated the rhyolite of Glass Mountain, Medicine Lake volcano, N. California   总被引：13，自引：1，他引：13  

Timothy L. Grove  Julie M. Donnelly-Nolan  Todd Housh 《Contributions to Mineralogy and Petrology》1997,127(3):205-223

Glass Mountain consists of a 1 km³, compositionally zoned rhyolite to dacite glass flow containing magmatic inclusions and xenoliths of underlying shallow crust. Mixing of magmas produced by fractional crystallization of andesite and crustal melting generated the rhyolite of Glass Mountain. Melting experiments were carried out on basaltic andesite and andesite magmatic inclusions at 100, 150 and 200 MPa, H₂O-saturated with oxygen fugacity controlled at the nickel-nickel oxide buffer to provide evidence of the role of fractional crystallization in the origin of the rhyolite of Glass Mountain. Isotopic evidence indicates that the crustal component assimilated at Glass Mountain constitutes at least 55 to 60% of the mass of erupted rhyolite. A large volume of mafic andesite (2 to 2.5 km³) periodically replenished the magma reservoir(s) beneath Glass Mountain, underwent extensive fractional crystallization and provided the heat necessary to melt the crust. The crystalline residues of fractionation as well as residual liquids expelled from the cumulate residues are preserved as magmatic inclusions and indicate that this fractionation process occurred at two distinct depths. The presence and composition of amphibole in magmatic inclusions preserve evidence for crystallization of the andesite at pressures of at least 200 MPa (6 km depth) under near H₂O-saturated conditions. Mineralogical evidence preserved in olivine-plagioclase and olivine-plagioclase-high-Ca clinopyroxene-bearing magmatic inclusions indicates that crystallization under near H₂O-saturated conditions also occurred at pressures of 100 MPa (3 km depth) or less. Petrologic, isotopic and geochemical evidence indicate that the andesite underwent fractional crystallization to form the differentiated melts but had no chemical interaction with the melted crustal component. Heat released by the fractionation process was responsible for heating and melting the crust. Received: 26 March 1996 / Accepted: 14 November 1996  相似文献