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In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ18O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ18O = ~15‰) to the rim (δ18O = ~11‰) suggests that the 18O/16O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the 18O/16O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ18O value of the garnet rim, together with the previously reported low δ18O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ18O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.  相似文献   
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We present a general recipe for constructing N -body realizations of galaxies comprising near spherical and disc components. First, an exact spherical distribution function for the spheroids (halo and bulge) is determined, such that it is in equilibrium with the gravitational monopole of the disc components. Second, an N -body realization of this model is adapted to the full disc potential by growing the latter adiabatically from its monopole. Finally, the disc is sampled with particles drawn from an appropriate distribution function, avoiding local-Maxwellian approximations. We performed test simulations and find that the halo and bulge radial density profile very closely match their target model, while they become slightly oblate due to the added disc gravity. Our findings suggest that vertical thickening of the initially thin disc is caused predominantly by spiral and bar instabilities, which also result in a radial re-distribution of matter, rather than scattering off interloping massive halo particles.  相似文献   
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About half of the lunar meteorites in our collections are feldspathic breccias. Acquiring geochronologic information from these breccias is challenging due to their low radioactive-element contents and their often polymict nature. We used high-spatial-resolution (5 μm) NanoSIMS (nanoscale secondary ion mass spectrometry) U-Pb dating technique to date micro-zircons in the lunar feldspathic meteorites Dhofar 1528 and Dhofar 1627. Three NanoSIMS dating spots of two zircon grains from Dhofar 1528 show a discordia with an upper intercept at 4354 ± 76 Ma and a lower intercept at 332 ± 1407 Ma (2σ, MSWD = 0.01, p = 0.91). Three spots of two zircon grains in Dhofar 1627 define a discordia with an upper intercept at 3948 ± 30 Ma and a lower intercept at 691 ± 831 Ma (2σ, MSWD = 0.40, p = 0.53). Both samples likely experienced shock metamorphism caused by impacts. Based on the clastic nature, lack of recrystallization and the consistent U-Pb and Pb-Pb dates of the zircons in Dhofar 1528, the U-Pb date of 4354 Ma is interpreted as the crystallization age of its Mg-suite igneous precursor. Some of the Dhofar 1627 zircons show poikilitic texture, a crystallization from the matrix impact melt, so the U-Pb date of 3948 Ma corresponds to an impact event, likely the Imbrium basin-forming event. These data are the first radiometric ages for these two meteorites and demonstrate that in situ (high spatial resolution) U-Pb dating has potential for extracting geochronological information about igneous activities and impact events from lunar feldspathic and polymict breccias.  相似文献   
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We report on the results of an I -band time-series photometric survey of NGC 2547 using the MPG/ESO 2.2-m telescope with Wide Field Imager, achieving better than 1 per cent photometric precision per data point over  14 ≲ I ≲ 18  . Candidate cluster members were selected from a V versus V − I colour–magnitude diagram over  12.5 < V < 24  (covering masses from  0.9 M  down to below the brown dwarf limit), finding 800 candidates, of which we expect ∼330 to be real cluster members, taking into account contamination from the field (which is most severe at the extremes of our mass range). Searching for periodic variations in these gave 176 detections over the mass range  0.1 ≲ M /M≲ 0.9  . The rotation period distributions were found to show a clear mass-dependent morphology, qualitatively intermediate between the distributions obtained from similar surveys in NGC 2362 and 2516, as would be expected from the age of this cluster. Models of the rotational evolution were investigated, finding that the evolution from NGC 2362 to 2547 was qualitatively reproduced (given the uncertainty in the age of NGC 2547) by solid body and core-envelope decoupled models from our earlier NGC 2516 study without need for significant modification.  相似文献   
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Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ11B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ11B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO2 and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   
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Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ18O value was determined by CO2 laser fluorination (δ18OLF). GRS2 has δ18OLF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ18OLF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ18OLF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.  相似文献   
9.
Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of XMg and XF for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of XMg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.  相似文献   
10.
Land cover dynamics at the African continental scale is of great importance for global change studies. Actually, four satellite-derived land cover maps of Africa now available, e.g. ECOCLIMAP, GLC2000, MODIS and GLOBCOVER, are based on images acquired in the 2000s. This study aims at stressing the compliances and the discrepancies between these four land cover classifications systems. Each of them used different mapping initiatives and relies on different mapping standards, which supports the present investigation. In order to do a relative comparison of the four maps, a preamble was to reconcile their thematic legends into more aggregated categories after a projection into the same spatial resolution. Results show that the agreement between the four land cover products is between 56 and 69%. While all these land cover datasets show a reasonable agreement in terms of surface types and spatial distribution patterns, mapping of heterogeneous landscapes in the four products is not very successful. Land cover products based on remote sensing imagery can indeed significantly be improved by using smarter algorithms, better timing of image acquisition, improved class definitions. Either will help to improve the accuracy of future land cover maps at the African continental scale. Data producers may use the areas of spatial agreement for training area selection while users might need to verify the information in the areas of disagreement using additional data sources.  相似文献   
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