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YONGDONG WANG ODD S.BORGEN BRUCE R.KOWALSKI Laboratory for Chemometrics Center for Process Analytical Chemistry Department of Chemistry BG- University of Washington Seattle WA U.S.A. Present address:Perkin-Elmer Corporation Main Avenue Norwalk CT - U.S.A. 《地理学报(英文版)》1993,(5)
Through theoretical analysis and computer simulation,this short communication comments on theresidual bilinearization(RBL)method and compares it with non-bilinear rank annihilation(NBRA)forthe treatment of second-order calibration with non-bilinear data.It is found that these two methods aremathematically equivalent but have different noise propagation properties.The second-order advantage,namely quantitation in the presence of unknown interferences,can be carried over to non-bilinear dataonly if there exists a net analyte rank(NAR)for the analyte of interest. 相似文献
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δ~(18)O record and temperature change over the past 100 years in ice cores on the Tibetan Plateau 总被引：6，自引：0，他引：6
Lonnie Thompson 《中国科学D辑(英文版)》2006,(1)
1 IntroductionMeteorological stations on the Tibetan Plateau are few in number and uneven in distribution, with a majority concentrated in the east and south. No stations exist so far within the large expanse in the middle or west of the Plateau. Moreover… 相似文献
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A Review on the Global Stratotype Section and Point of the Permian-Triassic Boundary 总被引：6，自引：0，他引：6
YIN Hongfu TONG Jinnan ZHANG Kexin Lab of Biological Environmental Geology China University of Geosciences Wuhan Hubei State Key Lab of Geological Process Mineral Resources China University of Geosciences Wuhan Hubei 《《地质学报》英文版》2005,79(6):715-728
1 Introduction The Global Stratotype Section and Point (GSSP) of the Permian-Triassic Boundary (PTB) has been ratified by IUGS in 2001 (Yin et al., 2001). It is defined at the base of the Hindeodus parvus horizon, i.e. the base of Bed 27c of Meishan Section D, Changxing County, Zhejiang Province, South China. The PTB is important because it is not only an erathem boundary but also a great turning point of geological history symbolized by profound global changes and the strongest … 相似文献
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ZHANG Jing CHEN Yanjing QI Jinping GE Jun State Key Laboratory of Geological Process Mineral Resources China University of Geosciences Beijing China Key Laboratory of Metallogenic Dynamics Guangzhou Institute of Geochemistry the Chinese Academy of Sciences Guangzhou China 《《地质学报》英文版》2009,83(2)
The Tongbai-East Qinling Mountains,an important part of the Central orogenic belt,is one of the most important metallogenic belts in China and contains lots of orogenic-type and VMS-type (Volcanogenic Massive Sulfide type)metallogenic systems.The Dahe and Shuidongling VMS-type Cu-Zn deposits,located in the Erlangping Group in Tongbai and East Qinling Mountains,respectively, show similar geological and geochemical features.The Huoshenmiao Formation in the East Qinling region and the Liushanyan Formation i... 相似文献
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地震波传播的褶积微分算子法数值模拟 总被引：2，自引：0，他引：2
为了解决地震波场数值模拟中的速度与精度的匹配及局部信息与全局信息的耦合等问题, 该文借助新推出的基于Forsyte广义正交多项式的褶积微分算子, 将计算数学中的Forsyte多项式褶积微分算子应用到地震波传播的数值模拟中.复杂非均匀介质模型数值模拟结果说明了该方法的可行性和优越性.该方法同时具有广义正交多项式褶积微分算子的高精度和有限差分短算子算法的高速度.通过对算子长度的调节及算子系数的优化, 可同时兼顾波场解的全局信息与局部信息. 相似文献
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中太平洋海山区富钴结壳的钙质超微化石地层学研究 总被引：14，自引：1，他引：13
对“大洋一号”调查船在中太平洋采集的N1-15和N5E-06 2个富钴结壳样品进行了钙质超微化石及其生物地层学的研究与分析.这2个结壳从结构上分为3层: 致密型上层、疏松型中层和致密型下层.在研究中对各结构层和各层中有颜色或细微结构变化的层位都进行了详细的取样和分析.在识别了12个新生代钙质超微化石事件的基础上, 确定了2个结壳致密型上层结壳都为晚更新世以来的沉积, 它们的疏松型中层结壳为上新世到中更新世的沉积.对N5E-06富钴结壳来说, 其致密型下层结壳下部形成于中晚古新世到早渐新世的59.7~ 32.8 Ma期间.N1-15富钴结壳致密型下层的形成时代目前暂时定为中新世.研究注意到在2个结壳中都没有发现可信的晚渐新世到中新世的化石记录, 在个别层位之间存在着沉积间断. 相似文献
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This work evaluates objective functions for multiresponse non-linear modeling using computersimulations.Tests are performed under a variety of signal-to-noise ratios and noise variance-covariancestructures.The standard error of prediction for the model parameters,computed from 50 trials,is usedfor performance comparisons.The full rank and rank-deficient problems are considered.For the fullrank problem one model was investigated,a first-order two-step consecutive reaction model,and twoobjective functions were considered,the total sum of squares and the determinant criterion.Nodistinction could be made between the two objective functions for this model.For the rank-deficient case two models were investigated,a first-order two-step consecutive reactionas in the full rank case,and a pH titration model described by the Henderson-Hasselbalch equation.Three objective functions were investigated for the rank-deficient case,the total sum of squares,aweighted total sum of squares and the determinant criterion.The total sum of squares was found toperform poorly under all conditions tested compared to the weighted total sum of squares and thedeterminant criterion.The determinant criterion was found to perform much better than the other twocriteria when the data have a combination of a low signal-to-noise ratio and high variance-covariancenoise structure. 相似文献
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Hack's law was originally derived from basin statistics for varied spatial scales and regions.The exponent value of the law has been shown to vary between 0.47 and 0.70,causing uncertainty in its application.This paper focuses on the emergence of Hack's law from debris-flow basins in China.Over 5,000 debris-flow basins in different regions of China with drainage areas less than 100km2 are included in this study.Basins in the different regions are found to present similar distributions.Hack's law is derived fi'om maximum probability and conditional distributions,suggesting that the law should describe some critical state of basin evolution.Results suggest the exponent value is approximately 0.5.Further analysis indicates that Hack's law is related to other scaling laws underlying the evolution of a basin and that the exponent is not dependent on basin shape but rather on the evolutionary stage.A case study of a well known debris-flow basin further confirms Hack's law and its implications in basin evolution. 相似文献
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The details of a general multiblock partial least squares(PLS)algorithm based on one originallypresented by Wold et al.have been developed and are completely presented.The algorithm can handlemost types of relationships between the blocks and constitutes a significant advancement in the modelingof complex chemical systems.The algorithm has been programmed in FORTRAN and has been testedon two simulated multiblock problems,a three-block and a five-block problem.The algorithm combinesthe score vectors for all blocks predicting a particular block into a new block.This new block is used topredict the predicted block in a manner analogous to the two-block PLS.In a similar manner if one blockpredicts more than one other block,the score vectors of all predicted blocks are combined to form a newblock,which is then predicted by the predictor block as in the two-block PLS.Blocks that both predictand are predicted are treated in such a way that both of these roles can be taken into account whencalculating interblock relationships.The results of numerical simulations indicate that the computerprogram is operating properly and that the multiblock PLS produces meaningful and consistent results. 相似文献