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1.
Daniel H. Doctor E. Calvin Alexander Jr Metka Petrič Janja Kogovšek Janko Urbanc Sonja Lojen Willibald Stichler 《Hydrogeology Journal》2006,14(7):1171-1191
Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ18O, δ2H) and of dissolved inorganic carbon (δ13CDIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions. 相似文献
2.
Size segregated sampling of aerosol particles at the coal-fired power station Šoštanj, Slovenia was performed by a newly developed
system. In addition, simultaneous sampling of particles was performed at two locations, Velenje and Veliki vrh, chosen on
the basis of long term monitoring of SO2 in the influential area of power plant. The signature of the power plant (e.g. characteristic size distributions of some
typical trace elements) was identified. For elements, like As, Mo, Cd and Ga, which are typical for coal combustion, the highest
concentrations were observed in the size range between 1 and 4 μm. For Se and sometimes for Ga two modes were identified,
first between 0.1 and 0.5 μm and second between 1 and 4 μm. Ratios between the average concentrations of selected elements
in fine and coarse particles collected at Veliki vrh (the most influenced location) and Velenje (usually not influenced by
the thermo power station) were significantly higher than 1 in the case of Mo and Se for coarse and fine size range, while
for As the ratio was higher than 1 for the coarse fraction. Consequently, Mo, Se and As were found as the most important tracers
for the emissions from the investigated source. On the basis of the ratios between the concentrations of elements measured
in particles at low and high SO2 concentrations at Veliki vrh, Cd was shown to be a typical tracer as well. Our results definitely showed that size segregated
measurements of particles at the source and in the influenced area give more precise information on the influence of source
to the surrounding region. It was found that patterns of size distributions for typical trace elements observed at the source
are found also in the influenced area, i.e. Veliki vrh. 相似文献
3.
Gregor Muri Branko Čermelj Radojko Jaćimović Tina Ravnikar Andrej Šmuc Janja Turšič Polona Vreča 《Journal of Paleolimnology》2018,59(4):411-426
Increased eutrophication was recently observed in the 5th (5J) and 6th (6J) Triglav Lakes, two remote Slovenian mountain lakes. Sediment phosphorus (P) pools were analysed and potential external P sources affecting the lakes (atmospheric deposition, terrestrial export and nearby hut) evaluated, to assess the effects of internal and external changes on the lakes. A sequential extraction procedure was used to quantify five P fractions from the sediments: adsorbed (NH4Cl–P), redox-sensitive (BD–P), aluminium- (NaOH–P) and calcium- (HCl–P) bound, and refractory organic (Res–P) P. Total phosphorus (TP) contents in surface sediment of 5J and 6J were 1430 and 641 µg P g?1 dry weight sediment (dw), respectively. TP varied with depth in 5J sediments, but displayed no discernible pattern, whereas it decreased steadily downcore in 6J. Contents of all P forms were distinctly higher in 5J than 6J, but their rank order and relative abundances were similar in the two lakes. Res–P was the most abundant P fraction, followed by HCl–P. Together, the two P forms accounted for nearly 80 and 90% of TP in 5J and 6J sediments, respectively. BD–P and NaOH–P were less abundant, with each fraction accounting for 3 to 9% of TP, whereas NH4Cl–P was least abundant. Atmospheric deposition and terrestrial export were substantial sources of P for the lakes. Delivery of the former was estimated to be at least 7.5 mg P m?2 yr?1 and the latter around 20 mg P m?2 yr?1. We concluded that P was not retained in the catchment effectively, likely because of only slightly acidic soil pH (5.9), relatively low aluminium content and high organic matter content (53%) in soils, resulting in higher vulnerability of the studied lakes to eutrophication. The mountain hut could also be a significant source of P for the lakes. Each year, it could potentially contribute ~12 kg of soluble P to the environment, but the true impact of the hut on lake trophic status remains unclear. 相似文献
4.
Nataša Ravbar Juan Antonio Barberá Metka Petrič Janja Kogovšek Bartolomé Andreo 《Environmental Earth Sciences》2012,65(8):2259-2272
In this study a multi-tracer test with fluorescent tracers was combined with time series analyses of natural tracers to characterize
the dynamics of the solute transport through different recharge pathways and to study hydraulic behaviour of a binary karst
system under low-flow conditions. Fluorescent tracer testing included the introduction of uranine, amidorhodamine G, or naphthionate
at three injection points. Sampling and monitoring took place at two karst springs (Malenščica, Unica) and at two underground
rivers (Pivka, Rak) recharging the Unica River at the Polje of Planina, SW Slovenia. Other monitored parameters included precipitation,
spring or underground river discharge, water temperature, and electrical conductivity. Water samples were collected and analyzed
for total organic carbon, Mg2+, SO4
2−, and NO3
− in the laboratory. In the study area, results of the tracer test suggest that contaminant transport in karst may be retarded
for several weeks during low-flow conditions followed by increases in contaminant concentrations after subsequent rainfall
events. Based on interpretation of tracer concentration breakthrough curves, low apparent dominant flow velocities (i.e.,
between 5.8 and 22.8 m/h through the well developed karst conduits, and 3.6 m/h through the prevailing vadose zone with a
dominant influence of a diffuse recharge) were obtained. Together with analyses of hydro-chemographs the artificial tracing
identified different origins of water recharging the studied aquifer. During prolonged low-water conditions the Malenščica
spring is mainly recharged from the karst aquifer and the Unica spring by the sinking Pivka River. After more intensive rainfall
events allogenic recharge from Cerknica prevails in the Malenščica spring, while the Unica spring drains mainly the allogenic
water from the Pivka Valley. These findings of alternating hydraulic connections and drainage areas due to respective hydrological
conditions are important and should be considered when monitoring water quality, implementing groundwater protection measures,
and optimizing future water exploitation. 相似文献
5.
Ryoko Fujiyoshi Hikaru Amano Yousuke Sakuta Kazumasa Okamoto Takashi Sumiyoshi Ivan Kobal Janja Vaupoti? 《Environmental Earth Sciences》2012,67(1):133-140
Carbon sources were estimated by measuring carbon isotope ratios (??13C and ??14C) with accelerator mass spectrometry (AMS) in forest soils of different lithology. Six locations were selected in temperate deciduous and coniferous stands in Slovenia (?irovski vrh, Idrija, Ko?evski Rog, Pohorje, Gori?nica, and Rakitna), where carbonate rocks consisting of limestone and dolomite are abundant as underlying bedrock. Carbon isotope fractionation would not have occurred in two carbonaceous soils, since the values of both ??13C and ??14C changed consistently in these soils after thermal (550°C, 2?h) or chemical (1?M HCl, 24?h) treatments. Organic components were found to be predominant carbon sources (70?C100%) in the uppermost portions (0?C2?cm in depth). In deeper portions at a depth of about 30?C35?cm, soil carbon may be derived completely from underlying carbonate minerals in Idria, western part of Slovenia. The Combination of heat and chemical treatments with AMS provides practical information on soil carbon sources in carbonaceous soils. 相似文献
6.
Daqing Yang Barry E. Goodison John R. Metcalfe Valentin S. Golubev Esko Elomaa Thilo Gunther Roy Bates Timothy Pangburn Clayton L. Hanson Douglas Emerson Voilete Copaciu Janja Milkovic 《水文研究》1995,9(8):877-895
The Tretyakov non-recording precipitation gauge has been used historically as the official precipitation measurement instrument in the Russian (formerly the USSR) climatic and hydrological station network and in a number of other European countries. From 1986 to 1993, the accuracy and performance of this gauge were evaluated during the WMO Solid Precipitation Measurement Intercomparison at 11 stations in Canada, the USA, Russia, Germany, Finland, Romania and Croatia. The double fence intercomparison reference (DFIR) was the reference standard used at all the Intercomparison stations in the Intercomparison. The Intercomparison data collected at the different sites are compatible with respect to the catch ratio (measured/DFIR) for the same gauge, when compared using mean wind speed at the height of the gauge orifice during the observation period. The Intercomparison data for the Tretyakov gauge were compiled from measurements made at these WMO intercomparison sites. These data represent a variety of climates, terrains and exposures. The effects of environmental factors, such as wind speed, wind direction, type of precipitation and temperature, on gauge catch ratios were investigated. Wind speed was found to be the most important factor determining the gauge catch and air temperature had a secondary effect when precipitation was classified into snow, mixed and rain. The results of the analysis of gauge catch ratio versus wind speed and temperature on a daily time step are presented for various types of precipitation. Independent checks of the correction equations against the DFIR have been conducted at those Intercomparison stations and a good agreement (difference less than 10%) has been obtained. The use of such adjustment procedures should significantly improve the accuracy and homogeneity of gauge-measured precipitation data over large regions of the former USSR and central Europe. 相似文献
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9.
Patricija Mozetič Cosimo Solidoro Gianpiero Cossarini Giorgio Socal Robert Precali Janja Francé Franco Bianchi Cinzia De Vittor Nenad Smodlaka Serena Fonda Umani 《Estuaries and Coasts》2010,33(2):362-375
The results of the updated and quality-checked data base of field observations on chlorophyll a (Chl a) collected in the period 1970–2007 in the Northern Adriatic Sea are presented. From the last decade, SeaWiFS satellite information
was also considered. Results demonstrate a global tendency towards Chl a reduction in the period of investigation, which is more marked in the eutrophic area under the influence of the Po River.
In the rest of the basin, which presents meso- or oligotrophic characteristics, long-term changes are more difficult to detect.
The long-term field dataset can be divided into two periods: the last decade characterized by the strong decrease observed
in the whole northern Adriatic and the earlier period with no or slight increase. The recent substantial reduction of Chl
a concentrations is confirmed all over the basin (−0.11 mg m−3 year−1) from satellite-derived information. Results are consistent with recently evidenced decrease in concentrations of phosphate
and ammonia and point to the existence of oligotrophication in the Northern Adriatic. Results indicate forcefully that the
still common perception of the Adriatic Sea as a very eutrophic basin is no longer appropriate, at least for its northern
part and in recent years. 相似文献
10.
Ryoko Fujiyoshi Takayuki Yamaguchi Naoki Takekoshi Kazumasa Okamoto Takashi Sumiyoshi Ivan Kobal Janja Vaupotič 《Central European Journal of Geosciences》2011,3(3):291-301
Depth distribution profiles of environmental radionuclides (137Cs and 210Pb) have been investigated in soil to elucidate the underlying environment of semi-natural temperate deciduous and/or coniferous forest soils in Slovenia (?irovski vrh, Idrija, Ko?evski Rog, Pohorie, Gori?nica and Rakitna). Surface enrichment of both nuclides was observed at all the sites investigated in this study, suggesting that the soils had undergone little natural or anthropogenic disturbance for at least the last several decades. Apparent annual burial rates of 137Cs (0.1–0.2 cm y??1) were estimated to be about 1.3 times higher than those of 210Pb at individual sites of different lithology, which suggests strong affinity of 210Pb to soil organic matter. Variability of the vertical distribution profiles of these nuclides depends not only on “in situ” pedology but also on geographical and meteorological conditions, especially precipitation and wind direction. 相似文献