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1.
Weathering of Hitura (W Finland) nickel sulphide mine tailings and release of heavy metals into pore water was studied with mineralogical (optical and electron microscopy, X-ray diffraction) and geochemical methods (selective extractions). Tailings were composed largely of serpentine, micas and amphiboles with only minor carbonates and sulphides. Sulphides, especially pyrrhotite, have oxidized intensively in the shallow tailings in 10–15 years, but a majority of the tailings have remained unchanged. Oxidation has resulted in depletion of carbonates, slightly decreased pH, and heavy metal (Ni, Zn) release in pore water as well as in the precipitation of secondary Fe precipitates. Nevertheless, in the middle of the tailings area, where the oxidation front moves primarily downward, released heavy metals have been adsorbed and immobilized with these precipitates deeper in the oxidation zone. In contrast to what was seen in pore water pH, but in accordance with static tests of the previous studies, the neutralisation potential ratio (NPR) calculated based on the mineralogical composition and the total sulphur content suggested that tailings are ‘not potentially acid mine drainage (AMD) generating’. However, the calculated buffering capacity of the tailings resulted largely from the abundant serpentine because of the low carbonate content. Despite its slow weathering rate, serpentine may buffer the acidity to some extent through ion exchange processes in fine ground tailings. Nevertheless, in practice, acid production capacity of the tailings depends primarily on the balance between Ca–Mg carbonates and iron sulphides. NPR calculation based on carbonate and sulphur contents suggested, that the Hitura tailings are ‘likely AMD generating’. The study shows that sulphide oxidation can be significant in mobilisation of heavy metals even in apparently non-acid producing, low sulphide tailings. Therefore, prevention of oxygen diffusion into tailings is also essential in this type of sulphide tailings. 相似文献
2.
Kaisa Korhonen-Kurki Maria Brockhaus Jenniver Sehring Monica Di Gregorio Samuel Assembe-Mvondo Andrea Babon 《Climate Policy》2019,19(3):315-328
Reducing Emissions from Deforestation and forest Degradation (REDD+) has emerged as a promising climate change mitigation mechanism in developing countries. In order to identify the enabling conditions for achieving progress in the implementation of an effective, efficient and equitable REDD+, this paper examines national policy settings in a comparative analysis across 13 countries with a focus on both institutional context and the actual setting of the policy arena. The evaluation of REDD+ revealed that countries across Africa, Asia and Latin America are showing some progress, but some face backlashes in realizing the necessary transformational change to tackle deforestation and forest degradation. A Qualitative Comparative Analysis (QCA) undertaken as part of the research project showed two enabling institutional configurations facilitating progress: (1) the presence of already initiated policy change; and (2) scarcity of forest resources combined with an absence of any effective forestry framework and policies. When these were analysed alongside policy arena conditions, the paper finds that the presence of powerful transformational coalitions combined with strong ownership and leadership, and performance-based funding, can both work as a strong incentive for achieving REDD+ goals.
Key policy insights
The positive push of already existing policy change, or the negative stress of resource scarcity together with lack of effective policies, represents institutional conditions that can support REDD+ progress.
Progress also requires the presence of powerful transformational coalitions and strong ownership and leadership. In the absence of these internal drivers, performance-based funding can work as a strong incentive.
When comparing three assessments (2012, 2014, 2016) of REDD+ enabling conditions, some progress in establishing processes of change can be observed over time; however, the overall fluctuation in progress of most countries reveals the difficulty in changing the deforestation trajectory away from business as usual.
3.
Markku Heikkinen 《Journal of Geodesy》1979,53(3):239-245
The Honkasalo term is discussed and the author arrives at the conclusion that its application to gravimetric observations
is harmful and should be avoided. 相似文献
4.
Jussi Heikkinen 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(3):267-274
This paper deals with a novel imaging arrangement for special modeling purpose. The method introduced here will take care of the geometrical consistence of photography. It is based on image ray bundles and is meant for conditions where imaging is accomplished inside the object space (e.g. in case of interior model reconstruction). Imaging is designed to be constrained in terms of camera position and orientation and to consist of two image sequences. The image orientations will be resolved by use of LSQ-estimation in heavily overdetermined conditions. The benefits of overdetermination are discussed and the accuracy assessment in a real experiment is published. The accuracy assessment is accomplished with help of exterior reference and stochastic error propagation. 相似文献
5.
Hannu Marttila Annalea Lohila Pertti Ala-Aho Kashif Noor Jeffrey M. Welker Danny Croghan Kaisa Mustonen Leo-Juhani Meriö Anna Autio Filip Muhic Hannah Bailey Mika Aurela Jussi Vuorenmaa Timo Penttilä Valtteri Hyöky Eric Klein Anton Kuzmin Pasi Korpelainen Timo Kumpula Anssi Rauhala Bjørn Kløve 《水文研究》2021,35(9):e14350
Subarctic ecohydrological processes are changing rapidly, but detailed and integrated ecohydrological investigations are not as widespread as necessary. We introduce an integrated research catchment site (Pallas) for atmosphere, ecosystems, and ecohydrology studies in subarctic conditions in Finland that can be used for a new set of comparative catchment investigations. The Pallas site provides unique observational data and high-intensity field measurement datasets over long periods. The infrastructure for atmosphere- to landscape-scale research in ecosystem processes in a subarctic landscape has recently been complemented with detailed ecohydrological measurements. We identify three dominant processes in subarctic ecohydrology: (a) strong seasonality drives ecohydrological regimes, (b) limited dynamic storage causes rapid stream response to water inputs (snowmelt and intensive storms), and (c) hydrological state of the system regulates catchment-scale dissolved carbon dynamics and greenhouse (GHG) fluxes. Surface water and groundwater interactions play an important role in regulating catchment-scale carbon balances and ecosystem respiration within subarctic peatlands, particularly their spatial variability in the landscape. Based on our observations from Pallas, we highlight key research gaps in subarctic ecohydrology and propose several ways forward. We also demonstrate that the Pallas catchment meets the need for sustaining and pushing the boundaries of critical long-term integrated ecohydrological research in high-latitude environments. 相似文献
6.
An enzyme assay was developed for studies on peroxidase activities in humic lake water. 3,4-Dimethoxybenzyl alcohol (veratryl alcohol, VeraOH) was used as tracer substrate, and peroxidase (EC 1.11.1.7) activity was measured by high-performance liquid chromatography. The chemical stability of VeraOH and its application as peroxidase substrate was tested under light and dark conditions, different hydrogen peroxide (H2O2) concentrations and humic matter contents. VeraOH was stable under low UV radiation at in situ conditions in lake water (<0.010...0.25 kJ m–2 d–1), laboratory conditions (<0.05...0.30 kJ m–2 d–1), and low (1...100 μM) H2O2 concentrations. However, peroxides oxidized VeraOH above 1...10 mM H2O2 concentration in sterile Millipore-Q and humic lake water. Dark incubations showed little VeraOH oxidation products. The developed peroxidase assay was tested in the growth medium of Phanerochaete chrysosporium and a bacteria isolate (P.M.D. 20.4.3.1) from mesohumic lake Pääjärvi. Peroxidase activities were also measured in natural microbial communities under standard laboratory and under in situ conditions in humic lake water. Incubation times of about 5 to 12 days were usually needed to record significant (P < 0.05) peroxidase activities, in lake waters. In situ peroxidase activities varied in pelagial surface water (0...0.5 m) on a seasonal scale between 74 nmol L–1 h–1 and 273 nmol L–1 (mean: 176 nmol L–1 h–1) and within the water column between 110 nmol L–1 h–1 and 800 nmol L–1 h–1 (mean: 500 nmol L–1 h–1) in polyhumic lake Mekkojärvi. 相似文献
7.
Redistribution of potentially harmful metals and As was studied based on selective extractions in two active sulphide mine tailings impoundments in Finland. The Hitura tailings area contains residue from Ni ore processing, while the Luikonlahti site includes tailings from the processing of Cu–Co–Zn–Ni and talc ores. To characterize the element solid-phase speciation with respect to sulphide oxidation intensity and the water saturation level of the tailings, drill cores were collected from border zones and mid-impoundment locations. The mobility and solid-phase fractionation of Ni, Cu, Co, Zn, Cr, Fe, Ca, Al, As, and S were analysed using a 5-step non-sequential (parallel) selective extraction procedure. The results indicated that metal redistribution and sulphide oxidation intensity were largely controlled by the disposal history and strategy of the tailings (sorting, exposure of sulphides due to delayed burial), impoundment structure and water table, and reactivity of the tailings. Metal redistribution suggested sulphide weathering in the tailings surface, but also in unsaturated proximal areas beside the earthen dams, and in water-saturated bottom layers, where O2-rich infiltration is possible. Sulphide oxidation released trace metals from sulphide minerals at both locations. In the Hitura tailings, with sufficient buffering capacity, pH remained neutral and the mobilized metals were retained by secondary Fe precipitates deeper in the oxidized zone. In contrast, sulphide oxidation-induced acidity and rise in the water table after oxidation apparently remobilized the previously retained metals in Luikonlahti. In general, continuous disposal of tailings decreased the sulphide oxidation intensity in active tailings, unless there was a delay in burial and the reactive tailings were unsaturated after deposition. 相似文献
8.
Heather Schijns Suvi Heinonen Douglas R. Schmitt Pekka Heikkinen Ilmo T. Kukkonen 《Geophysical Prospecting》2009,57(6):997-1008
A traveltime inversion technique is applied to model the upper ∼40 m of the subsurface of a glaciated shield rock area in order to calculate static corrections for a multi-azimuth multi-depth walk-away vertical seismic profile and a surface seismic reflection profile. First break information from a seismic refraction survey is used in conjunction with a ray-tracing program and an iterative damped least-squares inversion algorithm to create a two-dimensional model of the subsurface. The layout of the seismic survey required crooked seismic lines and substantial gaps in the source and receiver coverage to be accounted for. Additionally, there is substantial topographical variation and a complex geology consisting of glaciofluvial sediment and glacial till overlying a crystalline bedrock. The resolution and reliability of the models is measured through a parameter perturbation technique, normalized χ2 values, root means square traveltime residuals and comparison to known geology. 相似文献
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10.
Velocities of upper-mantle P waves (Pn) generated by large shallow earthquakes in the Japan area have been studied by the time-term method in three areas of the Japanese islands. Data reported from routinely recording seismic stations, grouped to act as elongated arrays, were used. The velocities observed correspond to the P-wave velocity in the top layer of the mantle. For a region in southwestern Japan not spanned by active volcanoes the value obtained was 8.0 km/s, while for central Japan and on northern Honshu Island the corresponding values were as low as 7.6–7.7 km/s. After allowance for the influence of systematic earthquake mislocation, the probable error of the measurements is estimated not to exceed 0.1 km/s. The differences in P-wave velocity are attributable to the regional variation of subcrustal temperature in Japan reported by Uyeda and Horai, with high temperatures and low velocities in the volcanic zone.The time terms tend to be larger on the Japan Sea side than on the Pacific side of the Japanese islands. We suggest that this is due to an increase in P velocity in the mantle towards the Pacific, perpendicular to our profiles of measurement. 相似文献