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During German R/V Meteor M67/2 expedition to Campeche Knolls, southern Gulf of Mexico, a set of 2D high resolution seismic data was acquired to study the near-surface sediment structure and its relationship with hydrocarbon seepages in this salt province. The comprehensive survey covered 20 individual bathymetric highs or ridges and identified three principle structural types: Passive Type, Chaopopte Type, and Asymmetric Flap Type. The first type is the result of passive diapirism, whereas the latter two were initialized by a regional compressional event in the Miocene, but are later differently modified by salt tectonism. Chapopote Type structures appear as symmetrical domes, with uplifted coarse-grained Miocene sediments in their cores and rather thin syn-kinematic sediments covering the crests. Asymmetric Flap Type structures are also first folded as domes or ridges, but one flap later subsided together with salt evacuation, resulting in single uplifted monoclines. With the coarse-grained pre-kinematic sediments as reservoir units, both structural types can focus and accumulate hydrocarbons. The geometries of the structures suggest that hydrocarbons are accumulated in the center of the Chapopote Type structures and in the subsided flaps of the Asymmetric Flap Type structures. Hydrocarbon leakage from these thinly sealed reservoirs is regarded as the principle mechanism for the seepage in the study area, and accordingly the most seepage-prone positions are above these reservoirs. The seep locations suggested by analysis of sea-surface oil slick images of SAR satellite data are also examined in this study. These independently derived seep locations confirm the seepage-prone positions to be above the shallow buried reservoirs. This study suggest that the shallow sediment structures control the distribution of the hydrocarbon seeps of the north-western Campeche Knolls, although the hydrocarbons are sourced from the greater depth.  相似文献   
2.
Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km2), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.  相似文献   
3.
The Northern Humboldt Current Ecosystem is one of the most productive in the world in terms of fish production. Its location near to the equator permits strong upwelling under relatively low winds, thus creating optimal conditions for the development of plankton communities. These communities ultimately support abundant populations of grazing fish such as the Peruvian anchoveta, Engraulis ringens. The ecosystem is also subject to strong inter-annual environmental variability associated with the El Niño Southern Oscillation (ENSO), which has major effects on nutrient structure, primary production, and higher trophic levels. Here our objective is to model the contributions of several external drivers (i.e. reconstructed phytoplankton changes, fish immigration, and fishing rate) and internal control mechanisms (i.e. predator-prey) to ecosystem dynamics over an ENSO cycle. Steady-state models and time-series data from the Instituto del Mar del Perú (IMARPE) from 1995 to 2004 provide the base data for simulations conducted with the program Ecopath with Ecosim. In simulations all three external drivers contribute to ecosystem dynamics. Changes in phytoplankton quantity and composition (i.e. contribution of diatoms and dino- and silicoflagellates), as affected by upwelling intensity, were important in dynamics of the El Niño of 1997–98 and the subsequent 3 years. The expansion and immigration of mesopelagic fish populations during El Niño was important for dynamics in following years. Fishing rate changes were the most important of the three external drivers tested, helping to explain observed dynamics throughout the modeled period, and particularly during the post-El Niño period. Internal control settings show a mix of predator–prey control settings; however a “wasp-waist” control of the ecosystem by small pelagic fish is not supported.  相似文献   
4.
We present near infrared reflectance spectra from 0.8 to 2.5 μm of two asteroids with low Tisserand invariant, 1373 Cincinnati and 2906 Caltech. We compare our spectra with cometary nuclei and other asteroids in their class. Asteroids Cincinnati and Caltech have Tisserand invariant values of 2.72 and 2.97, respectively, values less than 3 are considered suggestive of cometary origin. The observed spectral slopes in the near-infrared are consistent with both the spectra of cometary nuclei and of primitive asteroids. However, both asteroids have features in the near-infrared that are not seen in cometary nuclei, but are present in other X-type asteroids. 1373 Cincinnati has a sharp slope change between 0.75 and 1.0 μm and 2906 Caltech has a broad and shallow absorption between 1.35 and 2.2 μm. Our attempts to model the visible and near-infrared spectrum of these two objects, with the components successfully used by Emery and Brown (2004, Icarus 164, 104–121) to fit Trojan asteroids, did not yield acceptable fits.Visiting Astronomer at the Infrared Telescope Facility, which is operated by the University of Hawaii under contract to the National Aeronautics and Space Administration.  相似文献   
5.
Trans-neptunian objects (TNOs) are a population of small objects orbiting the Sun beyond Neptune. Because of their distance they are difficult to observe spectroscopically, but a large body of photometric observations is available and growing. TNOs are important tracers of the evolution of the outer Solar System and key when testing current dynamical evolution theories. Previous statistical studies of the colors of TNOs have yielded useful but limited results regarding the chemical history and evolution of these bodies.With the aim at obtaining compositional information on the small and distant TNOs we introduce a statistical cluster analysis (labelled albedo) based on colors and published albedos of TNOs. We compare it to a previous taxonomy, to illustrate the significance of including the albedo information when determining the composition of the objects. When the albedo contribution is removed from the data, the new taxonomy (now labelled classical) is in general agreement with the published ones, supporting the applicability of our approach. Making use of modeled reflectance spectra of a variety of plausible mixtures found on the surface of TNOs, we extract the average surface composition of each taxon, for both the classical and the albedo taxonomy, in a statistically consistent fashion.Differently from previous and classical, the albedo taxonomy establishes a direct link between the colors and albedos of the objects and their surface composition, allowing, for the first time, a quick assessment of the chemical history of TNOs. In fact, under closer examination the taxa show trends in composition that might be evolutionary in nature. If a simple ‘snow lines’ model is adopted, we can infer that albedo taxa relate the current objects’ locations to their original ones, prior to the migration of the outer planets. We regard the large population that characterizes the darkest classes spread at a variety of semi-major axis distances as one of the intriguing results of this work.  相似文献   
6.
We present a detailed study of an Iapetus mosaic of VIMS data with high spatial resolution (0.5 × 0.5° or ∼6.4 km/pixel). The spectra were taken in August 2007 and provide the highest VIMS spatial resolution data for this object during Cassini’s primary mission. We analyze this set of data using a statistical clustering approach to reduce the analysis of a large number of data (∼104 spectra from 0.35 to 5.10 μm) to the study of seven representative groups accounting for 99.6% of the surface covered by the original sample. We analyze the spectral absorption bands in the spectra of the different clusters indicative of different composition over the observed surface. We find coherence between the distribution of the clusters and the geographical features on the surface. We give special attention to the study of the water ice and CO2 bands. We find that CO2 is widespread over the entire surface being studied, including the bright and dark areas on Iapetus’ surface, and is probably trapped at the molecular level with other materials. The strength of the CO2 band in the areas where both, H2O- and carbon-bearing materials exist, gives support to the hypothesis that this volatile is formed on the surface of Iapetus as a product of irradiation of these two components. Finally, we also compare the Iapetus CO2 with that on other satellites confirming, that there are evident differences on the center, depth and width of the band on Iapetus and Phoebe, where CO2 has been suggested to be endogenous.  相似文献   
7.
The Bayesian approach to significance testing, that makes use of prior information, has been studied in the last years, particularly to allow the detection of deformations which are small with respect to measurement errors from repeated surveys. Some investigations showed up to now that, under particular conditions concerning both the parameters of the prior distribution and the structure of the control network, Bayesian tests give stronger results than tests based on the frequentist approach, with regard to the detectability of deformations. In the present paper, after illustrating the essential developments and the most relevant results of previous works, new analytical developments and numerical simulations are carried out, to illustrate some critical aspects and advantages of the frequentist and Bayesian methods. It is shown, starting from simple examples involving only Gaussian and truncated Gaussian distributions and from a simplified formulation of the prior deformation model, that the testing procedures based on the frequentist approach, which do not introduce any a priori information, are in many cases of practical interest insensitive to internal consistencies of the displacements (e.g., to the fact that they have a common direction). It is also illustrated that the introduction of prior information, even in a non Bayesian context, more easily allows the detection of little displacements. Besides it is noted that in some cases Bayesian tests detect displacements in the presence of observed non-coherent movements, even if prior probability densities describing coherent movements are introduced.  相似文献   
8.
With changes in climate looming, quantifying often‐overlooked components of the canopy water budget, such as cloud water interception (CWI), is increasingly important. Commonly, CWI quantification requires detailed continuous measurements, which is extremely challenging, especially when throughfall is included. In this study, we propose a simplified approach to estimate CWI using the Rutter‐type interception model, where CWI inputs in the canopy vegetation are proportional to fog interception measured by an artificial fog gauge. The model requires the continuous acquisition of meteorological variables as input and calibration datasets. Throughfall measurements below the forest are used only for calibration and validation of the model; thus, CWI estimates can be provided even after the cessation of throughfall monitoring. This approach provides an indirect and undemanding way to quantify CWI by vegetation and allows the identification of its controlling factors, which could be useful to the comparison of CWI in contrasting land covers. The method is applied on a 2‐year dataset collected in an endemic highland forest of San Cristobal Island (Galapagos). Our results show that CWI reaches 21% ± 6% of the total water input during the first year, and 9% ± 2% during the second one. These values represent 32% ± 10% and 17% ± 5% of water inputs during the cool foggy season of the first and second year, respectively. The difference between seasons is attributed to a lower fog liquid water during the second season.  相似文献   
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10.
Authigenic carbonates from active methane seeps offshore southwest Africa   总被引：2，自引：1，他引：1  
The southwest African continental margin is well known for occurrences of active methane-rich fluid seeps associated with seafloor pockmarks at water depths ranging broadly from the shelf to the deep basins, as well as with high gas flares in the water column, gas hydrate accumulations, diagenetic carbonate crusts and highly diverse benthic faunal communities. During the M76/3a expedition of R/V METEOR in 2008, gravity cores recovered abundant authigenic carbonate concretions from three known pockmark sites—Hydrate Hole, Worm Hole, the Regab pockmark—and two sites newly discovered during that cruise, the so-called Deep Hole and Baboon Cluster. The carbonate concretions were commonly associated with seep-benthic macrofauna and occurred within sediments bearing shallow gas hydrates. This study presents selected results from a comprehensive analysis of the mineralogy and isotope geochemistry of diagenetic carbonates sampled at these five pockmark sites. The oxygen isotope stratigraphy obtained from three cores of 2–5?m length indicates a maximum age of about 60,000–80,000?years for these sediments. The authigenic carbonates comprise mostly magnesian calcite and aragonite, associated occasionally with dolomite. Their very low carbon isotopic compositions (–61.0?<?δ13C ‰ V-PDB?<?–40.1) suggest anaerobic oxidation of methane (AOM) as the main process controlling carbonate precipitation. The oxygen isotopic signatures (+2.4?<?δ18O ‰ V-PDB?<?+6.2) lie within the range in equilibrium under present-day/interglacial to glacial conditions of bottom seawater; alternatively, the most positive δ18O values might reflect the contribution of 18O-rich water from gas hydrate decomposition. The frequent occurrence of diagenetic gypsum crystals suggests that reduced sulphur (hydrogen sulphide, pyrite) from sub-seafloor sediments has been oxidized by oxygenated bottom water. The acidity released during this process can potentially induce the dissolution of carbonate, thereby providing enough Ca2+ ions for pore solutions to reach gypsum saturation; this is thought to be promoted by the bio-irrigation and burrowing activity of benthic fauna. The δ18O–δ13C patterns identified in the authigenic carbonates are interpreted to reflect variations in the rate of AOM during the last glacial–interglacial cycle, in turn controlled by variably strong methane fluxes through the pockmarks. These results complement the conclusions of Kasten et al. in this special issue, based on authigenic barite trends at the Hydrate Hole and Worm Hole pockmarks which were interpreted to reflect spatiotemporal variations in AOM related to subsurface gas hydrate formation–decomposition.  相似文献   
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