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1IntroductionThecarbonisotopiccompositionofnaturalgasesisregardedasacontanttracerusedinthegeochemicalresearchofnaturalgases .Basedonthecarbonisotopiccomposition ,thegenetictypesofnaturalgasesarebasicallydividedtodeterminethematurationofnaturalgasesandmakegas sourcecorrelations (Stahl,1 973;StahlandCarey ,1 975;Stahletal.,1 977;James ,1 983;Schoell,1 983,1 988;DaiJinxingetal.,1 992 ;FuJiamoetal.,1 992 ;XuYongchang ,1 994 ) .Theformationofnaturalgasescouldbededucedintermsofcarbonisotopicvar… 相似文献
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火山活动与海侵影响下的典型湖相页岩有机质保存差异分析 总被引：1，自引：0，他引：1
黑色富有机质页岩是页岩油气生成和赋存的主要母体,是强还原环境水体的沉积产物,在其形成过程中,细菌硫酸盐还原作用(BSR)对水体环境影响明显,但BSR强度如何影响有机质的保存尚未得到关注。我国陆相湖盆富有机质泥页岩广泛发育,形成过程中常常伴随有火山活动或者海侵等事件,大量硫酸盐进入湖盆,改变水体的沉积环境,不同环境下BSR对黑色页岩有机质保存的影响明显不同。本次研究选取鄂尔多斯盆地延长组长7段页岩、松辽盆地青山口组和嫩江组页岩作为对象,同时与现代沉积物进行对比。研究表明,TOC与TS之间关系复杂,但细菌硫酸盐还原强度指数(SRI)与TOC呈现幂指数变化,且表现出两阶段变化的特征。当SRI大于1.375时,TOC整体偏低,指示了强硫酸盐还原作用消耗大量有机质;当SRI小于1.375时,TOC明显较高,指示了弱硫酸盐还原作用对有机质消耗相对较少,更有利于有机质保存。火山活动和海侵作用均向水体提供了大量硫酸盐,但对陆相湖盆页岩中有机质的保存影响不同。火山活动影响的长7段页岩SRI普遍小于1.375,BSR对有机质消耗相对弱,页岩TOC高。而受海侵影响的青山口组一段底部和嫩江组一段底部页岩SRI大于1.375,BSR过度消耗了大量有机质,使得页岩TOC偏低。嫩江组一段下部SRI指数更高,海侵强度更大,BSR反应更强,更不利于有机质保存。 相似文献
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深入探究页岩气富集机理是保障勘探开发高效推进的基础。本研究通过对四川盆地五峰组—龙马溪组页岩气勘探开发实践的系统分析,梳理总结前人研究成果,从生成机理、运移机理、赋存机理和保存机理四个方面对海相页岩气富集机理进行了深入分析,并讨论了深层和常压页岩气的勘探开发潜力。结果表明：在生成机理方面,埋藏史和热演化史控制了页岩生排烃史、生排烃量和现今含气量;页岩气运移机理涉及运移动力、运移相态、运移方式和运移通道四方面内容,页岩气运移主要是烃源岩内的初次运移,同时讨论了初次运移的影响因素;在赋存机理方面,甲烷—页岩间表现出单/多分子层吸附和微孔充填等多种赋存机制,组分润湿性和孔隙有效性是决定甲烷吸附赋存和解吸运移的关键;在保存机理方面,盖层和物性自封闭是主要的保存机理,构造运动引起的裂缝—流体活动是页岩气保存条件遭到破坏的主要原因,流体活动时间和期次研究是页岩气保存条件和含气量定量评价的重要内容。页岩气富集机理的系统分析和创新认识为页岩气勘探开发评价提供了重要依据,建议加强页岩气演化历史全过程的动态评价。结合深层和常压页岩气勘探实践,分析了深层和常压页岩气的成因机制及主要特征,指出了下一步攻关内容及勘探方向。 相似文献
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Peng Weilong Liu Quanyou Zhang Ying Jia Huichong Zhu Dongya Meng Qingqiang Wu Xiaoqi Deng Shang Ma Yongsheng 《中国科学:地球科学(英文版)》2022,65(5):874-881
Science China Earth Sciences - Helium gas is a scarce but important strategic resource, which is usually associated with natural gas. Presently, only one extra-large helium-rich gas field has been... 相似文献
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何文渊 崔宝文 王凤兰 王永卓 蒙启安 张金友 邵红梅 王瑞 白云风 林旭东 赵莹 孙宝刚 付秀丽 徐庆霞 崔坤宁 钟建华 高剑波 孙宁亮 毛毳 邵珠福 倪良田 宋全友 薛纯琦 郝兵 圣朋朋 张继震 王宇航 张文鑫 《地质论评》2022,68(2):693-741
松辽盆地古龙凹陷有丰富的页岩油气资源.但是目前对古龙凹陷页岩油储层的岩石学特征和页岩油的状态,尤其是储集空间的类型及其组合关联性认识不清.通过对古龙凹陷白垩系青山口组岩芯的精细描述及其薄片分析和电子显微镜观察及三维CT深入研究,发现古龙青山口组页岩油的储集空间具有多样性和多尺度性.除了纳米孔缝外,还有页理缝.根据页理缝... 相似文献
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Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons. 相似文献
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XU Huiyuan LIU Quanyou JIN Zhijun ZHU Dongy MENG Qingqiang LI Pengpeng ZHU Biqing 《《地质学报》英文版》2023,97(1):327-336
Continental epithermal ore deposits are commonly associated with sedimentary organic matter, oils or solid bitumen. These organics embedded in mineral deposits can convey valuable information of the ore genesis. However, the extent to which the formation of ore minerals was recorded by organic compounds remains largely unknown, as also is how metal-rich ores interfere with the molecular proxies in the temperature regime envisaged for hydrothermal activity. The molecular compositional changes of ... 相似文献
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以4-硝基苯并-15-冠醚-5(4-NO_2-B15C5)做萃取剂,苯甲醚和1-丁基-3-甲基咪唑双(三氟甲烷磺酰)亚胺盐([C_4mim][NTf_2])作稀释剂和协萃剂,以1 mol/L LiCl溶液作萃取溶剂,构建高效的冠醚—离子液体/锂盐溶液的溶剂萃取体系。重点考察了有机相组成、冠醚浓度和锂盐阴离子等对锂同位素分离的影响。结果表明,4-硝基苯并-15-冠醚-5具有良好的锂同位素分离效果,在萃取CF_3COOLi时最大单级分离系数(α)可达1.043±0.01。 相似文献
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LI Peng JIA Chengzao JIN Zhijun LIU Quanyou BI He ZHENG Min WU Songtao HUANG Zhenkai 《《地质学报》英文版》2020,94(2):219-232
Pore distribution and micro pore-throat structure characteristics are significant for tight oil reservoir evaluation, but their relationship remains unclear. This paper selects the tight sandstone reservoir of the Chang 7 member of the Xin’anbian Block in the Ordos Basin as the research object and analyzes the pore size distribution and micro pore-throat structure using field emission scanning electron microscopy(FE-SEM), high-pressure mercury injection(HPMI), highpressure mercury injection, and nuclear magnetic resonance(NMR) analyses. The study finds that:(1) Based on the pore size distribution, the tight sandstone reservoir is characterized by three main patterns with different peak amplitudes. The former peak corresponds to the nanopore scale, and the latter peak corresponds to the micropore scale. Then, the tight sandstone reservoir is categorized into three types: type 1 reservoir contains more nanopores with a nanopore-to-micropore volume ratio of 82:18;type 2 reservoir has a nanopore-to-micropore volume ratio of 47:53;and type 3 reservoir contains more micropores with a nanopore-to-micropore volume ratio of 35:65.(2) Affected by the pore size distribution, the throat radius distributions of different reservoir types are notably offset. The type 1 reservoir throat radius distribution curve is weakly unimodal, with a relatively dispersed distribution and peak ranging from 0.01 μm to 0.025 μm. The type 2 reservoir’s throat radius distribution curve is single-peaked with a wide distribution range and peak from 0.1 μm to 0.25 μm. The type 3 reservoir’s throat radius distribution curve is single-peaked with a relatively narrow distribution and peak from 0.1 μm to 0.25 μm. With increasing micropore volume, pore-throat structure characteristics gradually improve.(3) The correlation between micropore permeability and porosity exceeds that of nanopores, indicating that the development of micropores notably influences the seepage capacity. In the type 1 reservoir, only the mean radius and effective porosity have suitable correlations with the nanopore and micropore porosities. The pore-throat structure parameters of the type 2 and 3 reservoirs have reasonable correlations with the nanopore and micropore porosities, indicating that the development of these types of reservoirs is affected by the pore size distribution. This study is of great significance for evaluating lacustrine tight sandstone reservoirs in China. The research results can provide guidance for evaluating tight sandstone reservoirs in other regions based on pore size distribution. 相似文献